catalКатализ в промышленностиKataliz v promyshlennosti1816-03872413-6476LLC "KALVIS"10.18412/1816-0387-2024-2-43-50catal-1005Research ArticleКАТАЛИЗ В ХИМИЧЕСКОЙ И НЕФТЕХИМИЧЕСКОЙ ПРОМЫШЛЕННОСТИCATALYSIS IN CHEMICAL AND PETROCHEMICAL INDUSTRYЭкспериментальные исследования и математическое моделирование каталитической конверсии биодизельного топлива в синтез-газExperimental studies and mathematical modeling of the catalytic conversion of biodiesel fuel into synthesis gasШиловВ. А.ShilovV. A.ctls@kalvis.ruЗажигаловС. В.ZazhigalovS. V.ctls@kalvis.ruБурматоваМ. А.BurmatovaM. A.ctls@kalvis.ruЗагоруйкоА. Н.ZagoruikoA. N.ctls@kalvis.ruСнытниковП. В.SnytnikovP. V.ctls@kalvis.ruИнститут катализа им. Г.К. Борескова СО РАН (ИК СО РАН), Новосибирск; Новосибирский государственный университет (НГУ), НовосибирскРоссияBoreskov Institute of Catalysis, Novosibirsk; Novosibisk State UniversityRussian FederationИнститут катализа им. Г.К. Борескова СО РАН (ИК СО РАН), НовосибирскРоссияBoreskov Institute of Catalysis, NovosibirskRussian Federation2024200320242424350Copyright © LLC "KALVIS", 20242024LLC "KALVIS"LLC "KALVIS"https://www.catalysis-kalvis.ru/jour/about/submissions#copyrightNoticehttps://www.catalysis-kalvis.ru/jour/article/view/1005

Исследованы паровая конверсия и автотермический риформинг метилолеата (модельное соединение биодизельного топлива) в синтез-газ на структурированном Rh-содержащем катализаторе. Показано, что превращение метилолеата протекает через стадию термического крекинга с последующей конверсией образованных органических соединений с более коротким углеродным скелетом. На основе экспериментальных результатов была разработана математическая модель, учитывающая радиальный градиент температуры и представляющая собой эффективный инструмент для количественного описания и оптимизации процесса конверсии биодизельного топлива.

In this work, steam reforming and autothermal reforming of methyl oleate (a model compound of biodiesel fuel) into synthesis gas on a structured Rh-containing catalyst were investigated. It has been shown that the conversion of methyl oleate proceeds through the stage of thermal cracking followed by the conversion of the resulting organic compounds with a shorter carbon skeleton. Based on the experimental results, a mathematical model was developed that takes into account the radial temperature gradient and represents an effective tool for quantitatively describing and optimizing the biodiesel conversion process.

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The authors declare that there are no conflicts of interest present.