catalКатализ в промышленностиKataliz v promyshlennosti1816-03872413-6476LLC "KALVIS"10.18412/1816-0387-2026-2-65-84catal-1256Research ArticleКАТАЛИЗ В ХИМИЧЕСКОЙ И НЕФТЕХИМИЧЕСКОЙ ПРОМЫШЛЕННОСТИCATALYSIS IN CHEMICAL AND PETROCHEMICAL INDUSTRYКаталитические способы получения диметоксиметана, диметилоксалата и диметилкарбоната из метанолаCatalytic obtaining of dimetoxymethane, dimethyl oxalate and dimethyl carbonate from methanolУсковС. И.UskovS. I.ctls@kalvis.ruПеченкинА. А.PechenkinA. A.ctls@kalvis.ruКузнецоваА. Д.KuznetsovaA. D.ctls@kalvis.ruБадмаевС. Д.BadmaevS. D.ctls@kalvis.ruИнститут катализа им. Г.К. Борескова СО РАН, НовосибирскРоссияBoreskov Institute of Catalysis SB RAS , NovosibirskRussian Federation2026300320262626584Copyright © LLC "KALVIS", 20262026LLC "KALVIS"LLC "KALVIS"https://www.catalysis-kalvis.ru/jour/about/submissions#copyrightNoticehttps://www.catalysis-kalvis.ru/jour/article/view/1256

В работе представлены перспективные пути использования метанола как сырья для получения востребованных продуктов химической промышленности. Обсуждаются катализаторы и технологии производства диметоксиметана, диметилоксалата и диметилкарбоната. Данный обзор может представлять интерес в условиях сокращенного экспорта метанола из РФ с целью создания отечественных технологий утилизации метанола для получения ценных химических соединений.

This paper presents promising approaches to using methanol as a feedstock for producing valuable chemical products. Catalysts and technologies to produce dimethoxymethane, dimethyl oxalate, and dimethyl carbonate are discussed. This review may be of interest given the reduced methanol exports from Russia, with the aim of developing domestic methanol utilization technologies for producing valuable chemical compounds.

метанолдиметоксиметандиметилоксалатдиметилкарбонаткатализаторыmethanoldimethoxymethanedimethyl oxalatedimethyl carbonatecatalystsReferenceshttps://rupec.ru/news/53403/ - дата обращения 18.09.2025https://rupec.ru/news/53403/ - дата обращения 18.09.2025Cheremisinoff N. P. Industrial solvents handbook, revised and expanded. CRC Press, 2003, 344 с.Cheremisinoff N. P. Industrial solvents handbook, revised and expanded. CRC Press, 2003, 344 с.Zhu R., Wang X., Miao H., Yang X., Huang Z. // Fuel. 2011. V. 90. P. 1731-1737. https://doi.org/10.1016/j.fuel.2011.01.035Zhu R., Wang X., Miao H., Yang X., Huang Z. // Fuel. 2011. V. 90. P. 1731-1737. https://doi.org/10.1016/j.fuel.2011.01.035Zhu R., Miao H., Wang X., Huang Z. // Proceedings of the combustion institute. 2013. V. 34. P. 3013-3020. https://doi.org/10.1016/j.proci.2012.06.174Zhu R., Miao H., Wang X., Huang Z. // Proceedings of the combustion institute. 2013. V. 34. P. 3013-3020. https://doi.org/10.1016/j.proci.2012.06.174Sun Q., Auroux A., Shen J. // Journal of Catalysis. 2006. V. 244. P. 1-9 . https://doi.org/10.1016/j.jcat.2006.07.027Sun Q., Auroux A., Shen J. // Journal of Catalysis. 2006. V. 244. P. 1-9 . https://doi.org/10.1016/j.jcat.2006.07.027Fu Y., Shen J. // Journal of Catalysis. 2007. V. 248. P. 101-110. https://doi.org/10.1016/j.jcat.2007.03.013Fu Y., Shen J. // Journal of Catalysis. 2007. V. 248. P. 101-110. https://doi.org/10.1016/j.jcat.2007.03.013Shen H., Fu Y., Sun Q., Zuo S., Auroux A., Shen J. // Catalysis Communications. 2008. V. 9. P. 801- 806. https://doi.org/10.1016/j.catcom.2007.09.003Shen H., Fu Y., Sun Q., Zuo S., Auroux A., Shen J. // Catalysis Communications. 2008. V. 9. P. 801- 806. https://doi.org/10.1016/j.catcom.2007.09.003https://www.undp.org/sites/g/files/zskgke326/files/publications/Methylal_WEB.pdf - дата обращения 18.09.2025https://www.undp.org/sites/g/files/zskgke326/files/publications/Methylal_WEB.pdf - дата обращения 18.09.2025Wang C., Li X., Yuan S., Sun L., Bai P., Ling L., Guo H., Mintova S. // Catalysis Reviews. 2024. V. 67(2). P. 323–370. https://doi.org/10.1080/01614940.2024.2320165Wang C., Li X., Yuan S., Sun L., Bai P., Ling L., Guo H., Mintova S. // Catalysis Reviews. 2024. V. 67(2). P. 323–370. https://doi.org/10.1080/01614940.2024.2320165Thavornprasert K., Capron M., Jalowiecki-Duhamel L., Dumeignil F. // Catalysis Science & Technology. 2016. V. 6. P. 958-970. https://doi.org/10.1039/C5CY01858GThavornprasert K., Capron M., Jalowiecki-Duhamel L., Dumeignil F. // Catalysis Science & Technology. 2016. V. 6. P. 958-970. https://doi.org/10.1039/C5CY01858GMühler M. Handbook of Heterogeneous Catalysis, ed. G. Ertl, H. Knözinger and J. Weitkamp. VCH, Germany, 1997. Vol. 5. P. 2274.Mühler M. Handbook of Heterogeneous Catalysis, ed. G. Ertl, H. Knözinger and J. Weitkamp. VCH, Germany, 1997. Vol. 5. P. 2274.Fair J. R., Kmetz R. C. Formaldehyde, in Encyclopedia of Chemical Processing and Design, ed. J. J. McKetta and W. A. Cunningham. Marcel Dekker, Inc., USA, 1985. Vol. 23. P. 350.Fair J. R., Kmetz R. C. Formaldehyde, in Encyclopedia of Chemical Processing and Design, ed. J. J. McKetta and W. A. Cunningham. Marcel Dekker, Inc., USA, 1985. Vol. 23. P. 350.Патент RU 2439048С1, опубл. 10.01.2012.Патент RU 2439048С1, опубл. 10.01.2012.Tatibouët J. M., Lauron-Pernot H. // Journal of Molecular Catalysis A: Chemical. 2001. V. 171. P. 205-216. https://doi.org/10.1016/S1381-1169(01)00104-2Tatibouët J. M., Lauron-Pernot H. // Journal of Molecular Catalysis A: Chemical. 2001. V. 171. P. 205-216. https://doi.org/10.1016/S1381-1169(01)00104-2Rocchiccioli-Deltcheff C., Aouissi A., Bettahar M. M., Launay S., Fournier M. // Journal of Catalysis. 1996. V. 164. P. 16-27. https://doi.org/10.1006/jcat.1996.0358Rocchiccioli-Deltcheff C., Aouissi A., Bettahar M. M., Launay S., Fournier M. // Journal of Catalysis. 1996. V. 164. P. 16-27. https://doi.org/10.1006/jcat.1996.0358Liu H., Iglesia E. // J. Phys. Chem. B. 2003. V. 107. P. 10840-10847. https://doi.org/10.1021/jp0301554Liu H., Iglesia E. // J. Phys. Chem. B. 2003. V. 107. P. 10840-10847. https://doi.org/10.1021/jp0301554Wang W., Gao X., Xiong P., Zhang J., Song F., Zhang Q., Han Y., Tan Y. // Journal of Fuel Chemistry and Technology. 2021. V. 49. P. 1487-1494. https://doi.org/10.1016/S1872-5813(21)60094-4Wang W., Gao X., Xiong P., Zhang J., Song F., Zhang Q., Han Y., Tan Y. // Journal of Fuel Chemistry and Technology. 2021. V. 49. P. 1487-1494. https://doi.org/10.1016/S1872-5813(21)60094-4Fu Y., Shen J. // Chem. Commun. 2007. P. 2172-2174. https://doi.org/10.1039/B618898BFu Y., Shen J. // Chem. Commun. 2007. P. 2172-2174. https://doi.org/10.1039/B618898BLiu J., Fu Y., Sun Q., Shen J. // Microporous Mesoporous Mater. 2008. V. 116. P. 614-621. https://doi.org/10.1016/j.micromeso.2008.05.032Liu J., Fu Y., Sun Q., Shen J. // Microporous Mesoporous Mater. 2008. V. 116. P. 614-621. https://doi.org/10.1016/j.micromeso.2008.05.032Baraket L., Ghorbel A., Grange P. // Applied Catalysis B: Environmental. 2007. V. 72. P. 37-43. https://doi.org/10.1016/j.apcatb.2006.10.001Baraket L., Ghorbel A., Grange P. // Applied Catalysis B: Environmental. 2007. V. 72. P. 37-43. https://doi.org/10.1016/j.apcatb.2006.10.001Cai J., Fu Y., Sun Q., Jia M., Shen J. // Chinese Journal of Catalysis. 2013. V. 34. P. 2110–2117. https://doi.org/10.1016/S1872-2067(12)60690-1Cai J., Fu Y., Sun Q., Jia M., Shen J. // Chinese Journal of Catalysis. 2013. V. 34. P. 2110–2117. https://doi.org/10.1016/S1872-2067(12)60690-1Lu X., Qin Z., Dong M., Zhu H., Wang G., Zhao Y., Fan W., Wang J.. // Fuel. 2011. V. 90. P. 1335-1339. https://doi.org/10.1016/j.fuel.2011.01.007Lu X., Qin Z., Dong M., Zhu H., Wang G., Zhao Y., Fan W., Wang J.. // Fuel. 2011. V. 90. P. 1335-1339. https://doi.org/10.1016/j.fuel.2011.01.007Zhao H., Bennici S., Cai J., Shen J., Auroux A. // Catal. Today. 2010. V. 152. P. 70-77. https://doi.org/10.1016/j.cattod.2009.08.005Zhao H., Bennici S., Cai J., Shen J., Auroux A. // Catal. Today. 2010. V. 152. P. 70-77. https://doi.org/10.1016/j.cattod.2009.08.005Zhao H., Bennici S., Shen J., Auroux A. // Mol. Catal. A: Chem. 2009. V. 309. P. 28-34. https://doi.org/10.1016/j.molcata.2009.04.011Zhao H., Bennici S., Shen J., Auroux A. // Mol. Catal. A: Chem. 2009. V. 309. P. 28-34. https://doi.org/10.1016/j.molcata.2009.04.011Guo H., Li D., Jiang D., Li W., Sun Y. // Catalysis Communications. 2010. V. 11. P. 396–400. https://doi.org/10.1016/j.catcom.2009.11.009Guo H., Li D., Jiang D., Li W., Sun Y. // Catalysis Communications. 2010. V. 11. P. 396–400. https://doi.org/10.1016/j.catcom.2009.11.009Kaichev V.V., Popova G.Ya., Chesalov Yu.A., Saraev A.A., Zemlyanov D.Y., Beloshapkin S.A., Knop-Gericke A., Schlögl R., Andrushkevich T.V., Bukhtiyarov V.I. // Journal of Catalysis. 2014. V. 311. P. 59–70. https://doi.org/10.1016/j.jcat.2013.10.026Kaichev V.V., Popova G.Ya., Chesalov Yu.A., Saraev A.A., Zemlyanov D.Y., Beloshapkin S.A., Knop-Gericke A., Schlögl R., Andrushkevich T.V., Bukhtiyarov V.I. // Journal of Catalysis. 2014. V. 311. P. 59–70. https://doi.org/10.1016/j.jcat.2013.10.026Sima R., Liu G., Wang Q., Wu P., Qin T., Zeng G., Chen X., Liu Z., Sun Y. // ChemCatChem. 2017. V. 9. P. 1776–1781. https://doi.org/10.1002/cctc.201700074Sima R., Liu G., Wang Q., Wu P., Qin T., Zeng G., Chen X., Liu Z., Sun Y. // ChemCatChem. 2017. V. 9. P. 1776–1781. https://doi.org/10.1002/cctc.201700074Tao M., Wang H., Lu B., Zhao J., Cai Q. // New J. Chem. 2017. V. 41. P. 8370. https://doi.org/10.1039/C7NJ01295KTao M., Wang H., Lu B., Zhao J., Cai Q. // New J. Chem. 2017. V. 41. P. 8370. https://doi.org/10.1039/C7NJ01295KYin T., Wang H., Li S., Lu B., Zhao J., Cai Q. // Applied Surface Science. 2021. V. 548. P. 149180. https://doi.org/10.1016/j.apsusc.2021.149180Yin T., Wang H., Li S., Lu B., Zhao J., Cai Q. // Applied Surface Science. 2021. V. 548. P. 149180. https://doi.org/10.1016/j.apsusc.2021.149180Royer S., Sécordel X., Brandhorst M., Dumeignil F., Cristol S., Dujardin C., Capron M., Payen E., Dubois J.-L. // Chem. Commun. 2008. P. 865-867. https://doi.org/10.1039/B714260ARoyer S., Sécordel X., Brandhorst M., Dumeignil F., Cristol S., Dujardin C., Capron M., Payen E., Dubois J.-L. // Chem. Commun. 2008. P. 865-867. https://doi.org/10.1039/B714260AChen S., Meng Y., Zhao Y., Ma X., Gong J. // American Institute of Chemical Engineers Journal. 2013. V. 59. P. 2587–2593. https://doi.org/10.1002/aic.14033Chen S., Meng Y., Zhao Y., Ma X., Gong J. // American Institute of Chemical Engineers Journal. 2013. V. 59. P. 2587–2593. https://doi.org/10.1002/aic.14033Fu Y., Hong T. Chen J., Auroux A., Shen J. // Thermochimica Acta. 2005. V. 434. P. 22-26. https://doi.org/10.1016/j.tca.2004.12.023Fu Y., Hong T. Chen J., Auroux A., Shen J. // Thermochimica Acta. 2005. V. 434. P. 22-26. https://doi.org/10.1016/j.tca.2004.12.023Gornay J., Secordel X., Tesquet G., de Menorval B., Cristol S., Fongarland P., Capron M., Duhamel L., Payen E., Dubois J.-L., Dumeignil F. // Green Chem. 2010. V. 12. P. 1722-1725. https://doi.org/10.1039/C0GC00194EGornay J., Secordel X., Tesquet G., de Menorval B., Cristol S., Fongarland P., Capron M., Duhamel L., Payen E., Dubois J.-L., Dumeignil F. // Green Chem. 2010. V. 12. P. 1722-1725. https://doi.org/10.1039/C0GC00194EMeng Y., Wang T., Chen S., Zhao Y., Ma X., Gong J. // Applied Catalysis B: Environmental. 2014. V. 160–161. P. 161-172. https://doi.org/10.1016/j.apcatb.2014.05.008Meng Y., Wang T., Chen S., Zhao Y., Ma X., Gong J. // Applied Catalysis B: Environmental. 2014. V. 160–161. P. 161-172. https://doi.org/10.1016/j.apcatb.2014.05.008Zou S., Wang H., Li S., Lu B., Zhao J., Cai Q. // Applied Surface Science. 2022. V. 574. P. 151516. https://doi.org/10.1016/j.apsusc.2021.151516Zou S., Wang H., Li S., Lu B., Zhao J., Cai Q. // Applied Surface Science. 2022. V. 574. P. 151516. https://doi.org/10.1016/j.apsusc.2021.151516Yuan Y., Shido T., Iwasawa Y. // Chem. Commun. 2000. P. 1421-1422. https://doi.org/10.1039/B003870IYuan Y., Shido T., Iwasawa Y. // Chem. Commun. 2000. P. 1421-1422. https://doi.org/10.1039/B003870IYuan Y., Liu H., Imoto H., Shido T., Iwasawa Y. // J. Catal. 2000. V. 195. P. 51-61. https://doi.org/10.1006/jcat.2000.2990Yuan Y., Liu H., Imoto H., Shido T., Iwasawa Y. // J. Catal. 2000. V. 195. P. 51-61. https://doi.org/10.1006/jcat.2000.2990Sécordel X., Yoboué A., Cristol S., Lancelot C., Capron M., Paul J.-F., Berrier E. // J. Solid State Chem. 2011. V. 184. P. 2806-2811. https://doi.org/10.1016/j.jssc.2011.08.002Sécordel X., Yoboué A., Cristol S., Lancelot C., Capron M., Paul J.-F., Berrier E. // J. Solid State Chem. 2011. V. 184. P. 2806-2811. https://doi.org/10.1016/j.jssc.2011.08.002Liu H., Iglesia E. // J. Phys. Chem. B. 2005. V. 109. P. 2155-2163. https://doi.org/10.1021/jp0401980Liu H., Iglesia E. // J. Phys. Chem. B. 2005. V. 109. P. 2155-2163. https://doi.org/10.1021/jp0401980Li M., Long Y., Deng Z., Zhang H., Yang X., Wang G. // Catalysis Communications. 2015. V. 68. P. 46-48. https://doi.org/10.1016/j.catcom.2015.04.031Li M., Long Y., Deng Z., Zhang H., Yang X., Wang G. // Catalysis Communications. 2015. V. 68. P. 46-48. https://doi.org/10.1016/j.catcom.2015.04.031Yuan M., Dong M., Tian Z., Che Y., Tian Y., Qiao Y., Zhang J., Li D. // Journal of the Energy Institute. 2022. V. 103. P. 47-53. https://doi.org/10.1016/j.joei.2022.05.006Yuan M., Dong M., Tian Z., Che Y., Tian Y., Qiao Y., Zhang J., Li D. // Journal of the Energy Institute. 2022. V. 103. P. 47-53. https://doi.org/10.1016/j.joei.2022.05.006Yu B., Chung C., Chien I. // Comput. Chem. Eng. 2018. V. 119. P. 85-100. https://doi.org/10.1016/j.compchemeng.2018.08.025Yu B., Chung C., Chien I. // Comput. Chem. Eng. 2018. V. 119. P. 85-100. https://doi.org/10.1016/j.compchemeng.2018.08.025Peng S., Xu Z., Chen Q., Chen Y., Sun J., Wang Z., Wang M., Guo G. // Chem. Commun. 2013. V. 49(51). P. 5707-5806. https://doi.org/10.1039/C3CC00219EPeng S., Xu Z., Chen Q., Chen Y., Sun J., Wang Z., Wang M., Guo G. // Chem. Commun. 2013. V. 49(51). P. 5707-5806. https://doi.org/10.1039/C3CC00219EWang C., Xu W., Qin Z., Mintova S. // Catal. Commun. 2019. V. 119. P. 39-41. https://doi.org/10.1016/j.catcom.2018.10.014Wang C., Xu W., Qin Z., Mintova S. // Catal. Commun. 2019. V. 119. P. 39-41. https://doi.org/10.1016/j.catcom.2018.10.014Wang C., Ding J., Zhao G., Deng T., Liu Y., Lu Y. // ACS Appl. Mater. Interfaces. 2017. V. 9(11). P. 9795-9804. https://doi.org/10.1021/acsami.7b00889Wang C., Ding J., Zhao G., Deng T., Liu Y., Lu Y. // ACS Appl. Mater. Interfaces. 2017. V. 9(11). P. 9795-9804. https://doi.org/10.1021/acsami.7b00889Xu Z., Sun J., Lin C., Jiang X., Chen Q., Peng S., Wang M., Guo G. // ACS Catal. 2013. V. 3. P. 118-122. https://doi.org/10.1021/cs300759hXu Z., Sun J., Lin C., Jiang X., Chen Q., Peng S., Wang M., Guo G. // ACS Catal. 2013. V. 3. P. 118-122. https://doi.org/10.1021/cs300759hLim B., Jiang M. J., Tao J., Camargo P. H. C., Zhu Y. M., Xia Y. N. // Adv. Funct. Mater. 2009. V. 19. P. 189−200. https://doi.org/10.1002/adfm.200801439Lim B., Jiang M. J., Tao J., Camargo P. H. C., Zhu Y. M., Xia Y. N. // Adv. Funct. Mater. 2009. V. 19. P. 189−200. https://doi.org/10.1002/adfm.200801439Qu Y., Wang Y., Li J., Xu Q., Liang X., Jiang A. // Mol. Catal. 2020. V. 490. P. 110949. https://doi.org/10.1016/j.mcat.2020.110949Qu Y., Wang Y., Li J., Xu Q., Liang X., Jiang A. // Mol. Catal. 2020. V. 490. P. 110949. https://doi.org/10.1016/j.mcat.2020.110949Tan H.-Z., Wang Z.-Q., Xu Z.-N., Sun J., Chen Z.-N., Chen Q.-S., Chen Y., Guo G.-C. // Catal. Sci. Technol. 2017. V. 7. P. 3785-3790. https://doi.org/10.1039/C7CY01305ATan H.-Z., Wang Z.-Q., Xu Z.-N., Sun J., Chen Z.-N., Chen Q.-S., Chen Y., Guo G.-C. // Catal. Sci. Technol. 2017. V. 7. P. 3785-3790. https://doi.org/10.1039/C7CY01305AWang Z.-Q., Sun J., Xu Z.-N., Guo G.-C. // Nanoscale. 2020. V. 12. P. 20131-20140. https://doi.org/10.1039/D0NR03008BWang Z.-Q., Sun J., Xu Z.-N., Guo G.-C. // Nanoscale. 2020. V. 12. P. 20131-20140. https://doi.org/10.1039/D0NR03008BZhuo G., Jiang X. // Chinese Journal of Catalysis. 2003. V. 24(7). P. 509-512.Zhuo G., Jiang X. // Chinese Journal of Catalysis. 2003. V. 24(7). P. 509-512.Uchiumi S., Ataka K., Matsuzaki T. // J. Organomet. Chem. 1999. V. 576. P. 279-289. https://doi.org/10.1016/S0022-328X(98)01064-XUchiumi S., Ataka K., Matsuzaki T. // J. Organomet. Chem. 1999. V. 576. P. 279-289. https://doi.org/10.1016/S0022-328X(98)01064-XYamamoto Y. // Catal. Surv. Asia. 2010. V. 14. P 103-110. https://doi.org/10.1007/s10563-010-9102-8Yamamoto Y. // Catal. Surv. Asia. 2010. V. 14. P 103-110. https://doi.org/10.1007/s10563-010-9102-8Wang C., Han L., Chen P., Zhao G., Liu Y., Lu Y. // J. Catal. 2016. V. 337. P. 145-156. https://doi.org/10.1016/j.jcat.2016.02.008Wang C., Han L., Chen P., Zhao G., Liu Y., Lu Y. // J. Catal. 2016. V. 337. P. 145-156. https://doi.org/10.1016/j.jcat.2016.02.008Ji Y., Liu G., Li W., Xiao W. // J. Mol. Catal. A: Chem. 2009. V. 314. P. 63-70. https://doi.org/10.1016/j.molcata.2009.08.018Ji Y., Liu G., Li W., Xiao W. // J. Mol. Catal. A: Chem. 2009. V. 314. P. 63-70. https://doi.org/10.1016/j.molcata.2009.08.018Peng S., Xu Z., Chen Q., Wang Z., Chen Y., Lv D., Lu G., Guo G. // Catal. Sci. Technol. 2014. V. 4. P. 1925-1930. https://doi.org/10.1039/C4CY00245HPeng S., Xu Z., Chen Q., Wang Z., Chen Y., Lv D., Lu G., Guo G. // Catal. Sci. Technol. 2014. V. 4. P. 1925-1930. https://doi.org/10.1039/C4CY00245HYang L., Pan Z., Wang D., Wang S., Wang X., Ma H., Liu H., Wang C., Qu W., Tian Z. // ACS Appl. Mater. Interfaces. 2021. V. 13. P. 28064-28071. https://doi.org/10.1021/acsami.1c04051Yang L., Pan Z., Wang D., Wang S., Wang X., Ma H., Liu H., Wang C., Qu W., Tian Z. // ACS Appl. Mater. Interfaces. 2021. V. 13. P. 28064-28071. https://doi.org/10.1021/acsami.1c04051Peng S., Xu Z., Chen Q., Wang Z., Lv D., Sun J., Chen Y., Guo G. // ACS Catal. 2015. V. 5. P. 4410-4417. https://doi.org/10.1021/acscatal.5b00365Peng S., Xu Z., Chen Q., Wang Z., Lv D., Sun J., Chen Y., Guo G. // ACS Catal. 2015. V. 5. P. 4410-4417. https://doi.org/10.1021/acscatal.5b00365Jing K., Fu Y., Chen Z., Zhang T., Sun J., Xu Z., Guo G. // ACS Appl. Mater. Interfaces. 2021. V. 13. P. 24856-24864. https://doi.org/10.1021/acsami.1c04523Jing K., Fu Y., Chen Z., Zhang T., Sun J., Xu Z., Guo G. // ACS Appl. Mater. Interfaces. 2021. V. 13. P. 24856-24864. https://doi.org/10.1021/acsami.1c04523Wang C., Jia Y., Zhang Z., Zhao G., Liu Y., Lu Y. // Appl. Surf. Sci. 2019. V. 478. P. 840-845. https://doi.org/10.1016/j.apsusc.2019.02.031Wang C., Jia Y., Zhang Z., Zhao G., Liu Y., Lu Y. // Appl. Surf. Sci. 2019. V. 478. P. 840-845. https://doi.org/10.1016/j.apsusc.2019.02.031Gao Z., Hu C., Li Z., He F., Xu G. // Chinese Journal of Catalysis. 2004. V. 25(3). P. 205-209Gao Z., Hu C., Li Z., He F., Xu G. // Chinese Journal of Catalysis. 2004. V. 25(3). P. 205-209Zhao X., Lin Q., Xiao W. // Appl. Catal. A. 2005. V. 284. P. 253-257. https://doi.org/10.1016/j.apcata.2005.02.004Zhao X., Lin Q., Xiao W. // Appl. Catal. A. 2005. V. 284. P. 253-257. https://doi.org/10.1016/j.apcata.2005.02.004Li B., Zhu J., Huang Z., Jia B., Guo B., Liu J., Zhang Q. // ChemistrySelect. 2024. V. 9. e202305131. https://doi.org/10.1002/slct.202305131Li B., Zhu J., Huang Z., Jia B., Guo B., Liu J., Zhang Q. // ChemistrySelect. 2024. V. 9. e202305131. https://doi.org/10.1002/slct.202305131Gao X., Zhao Y., Wang S., Yin Y., Wang B., Ma X. // Chem. Eng. Sci. 2011. V. 66. P. 3513-3522. https://doi.org/10.1016/j.ces.2011.04.012Gao X., Zhao Y., Wang S., Yin Y., Wang B., Ma X. // Chem. Eng. Sci. 2011. V. 66. P. 3513-3522. https://doi.org/10.1016/j.ces.2011.04.012Wang C., Xu W., Qin Z., Liu X., Mintova S. // Catal. Today. 2020. V. 354. P. 158-166. https://doi.org/10.1016/j.cattod.2019.03.005Wang C., Xu W., Qin Z., Liu X., Mintova S. // Catal. Today. 2020. V. 354. P. 158-166. https://doi.org/10.1016/j.cattod.2019.03.005Rogozhnikov V.N., Salanov A.N., Potemkin D.I., Pakharukova V.P., Stonkus O.A., Glotov A.P., Boev S.S., Zasypalov G.O., Melnikov D.P., Snytnikov P.V. // Materials Letters. 2022. V. 310. P. 131481. https://doi.org/10.1016/j.matlet.2021.131481Rogozhnikov V.N., Salanov A.N., Potemkin D.I., Pakharukova V.P., Stonkus O.A., Glotov A.P., Boev S.S., Zasypalov G.O., Melnikov D.P., Snytnikov P.V. // Materials Letters. 2022. V. 310. P. 131481. https://doi.org/10.1016/j.matlet.2021.131481Shoynkhorova T.B., Rogozhnikov V.N., Ruban N.V., Shilov V.A., Potemkin D.I., Simonov P.A., Belyaev V.D., Snytnikov P.V., Sobyanin V.A. // International Journal of Hydrogen Energy. 2019. V. 44. P. 9941-9948. https://doi.org/10.1016/j.ijhydene.2018.12.148Shoynkhorova T.B., Rogozhnikov V.N., Ruban N.V., Shilov V.A., Potemkin D.I., Simonov P.A., Belyaev V.D., Snytnikov P.V., Sobyanin V.A. // International Journal of Hydrogen Energy. 2019. V. 44. P. 9941-9948. https://doi.org/10.1016/j.ijhydene.2018.12.148Urlukov A.S., Uskov S.I., Sobyanin V.A., Snytnikov P.V., Potemkin D.I. // Chemical Engineering Journal. 2022. V. 446. P. 136993. https://doi.org/10.1016/j.cej.2022.136993Urlukov A.S., Uskov S.I., Sobyanin V.A., Snytnikov P.V., Potemkin D.I. // Chemical Engineering Journal. 2022. V. 446. P. 136993. https://doi.org/10.1016/j.cej.2022.136993Shoynkhorova T.B., Snytnikov P.V., Simonov P.A., Potemkin D.I., Rogozhnikov V.N., Gerasimov E.Y., Salanov A.N., Belyaev V.D., Sobyanin V.A. // Applied Catalysis B: Environmental. 2019. V. 245. P. 40-48. https://doi.org/10.1016/j.apcatb.2018.12.037Shoynkhorova T.B., Snytnikov P.V., Simonov P.A., Potemkin D.I., Rogozhnikov V.N., Gerasimov E.Y., Salanov A.N., Belyaev V.D., Sobyanin V.A. // Applied Catalysis B: Environmental. 2019. V. 245. P. 40-48. https://doi.org/10.1016/j.apcatb.2018.12.037Ruban N., Rogozhnikov V., Zazhigalov S., Zagoruiko A., Emelyanov V., Snytnikov P., Sobyanin V., Potemkin D. // Materials. 2022. V. 15. P. 7336. https://doi.org/10.3390/ma15207336Ruban N., Rogozhnikov V., Zazhigalov S., Zagoruiko A., Emelyanov V., Snytnikov P., Sobyanin V., Potemkin D. // Materials. 2022. V. 15. P. 7336. https://doi.org/10.3390/ma15207336Kuenen H.J., Mengers H.J., van der Ham A.G.J., Kiss A. A. // Computer Aided Chemical Engineering. 2016. V. 38. P. 991-996. https://doi.org/10.1016/B978-0-444-63428-3.50170-3Kuenen H.J., Mengers H.J., van der Ham A.G.J., Kiss A. A. // Computer Aided Chemical Engineering. 2016. V. 38. P. 991-996. https://doi.org/10.1016/B978-0-444-63428-3.50170-3Патент US 2787631, опубл. 02.04.1957.Патент US 2787631, опубл. 02.04.1957.Fang S., Fujimoto K. // Appl. Catal., A. 1996. V. 142. P. L1–L3. https://doi.org/10.1016/0926-860X(96)00081-6Fang S., Fujimoto K. // Appl. Catal., A. 1996. V. 142. P. L1–L3. https://doi.org/10.1016/0926-860X(96)00081-6Sakakura T., Choi J., Saito Y., Masuda T., Sako T., Oriyama T. // J. Org. Chem. 1999. V. 64. P. 4506–4508. https://doi.org/10.1021/jo990155tSakakura T., Choi J., Saito Y., Masuda T., Sako T., Oriyama T. // J. Org. Chem. 1999. V. 64. P. 4506–4508. https://doi.org/10.1021/jo990155tHonda M., Tamura M., Nakagawa Y., Sonehara S., Suzuki K., Fujimoto K. I., Tomishige K. // ChemSusChem. 2013. V. 6. P. 1341–1344. https://doi.org/10.1002/cssc.201300229Honda M., Tamura M., Nakagawa Y., Sonehara S., Suzuki K., Fujimoto K. I., Tomishige K. // ChemSusChem. 2013. V. 6. P. 1341–1344. https://doi.org/10.1002/cssc.201300229Keller N., Rebmann G., Keller V. // Journal of Molecular Catalysis A: Chemical. 2010. V. 317. P. 1-18. https://doi.org/10.1016/j.molcata.2009.10.027Keller N., Rebmann G., Keller V. // Journal of Molecular Catalysis A: Chemical. 2010. V. 317. P. 1-18. https://doi.org/10.1016/j.molcata.2009.10.027Wang M., Wang H., Zhao N., Wei W., Sun Y. // Industrial & Engineering Chemistry Research. 2007. V. 46. P. 2683–2687. https://doi.org/10.1021/ie061101uWang M., Wang H., Zhao N., Wei W., Sun Y. // Industrial & Engineering Chemistry Research. 2007. V. 46. P. 2683–2687. https://doi.org/10.1021/ie061101uBunsaksit C., Methaapanon R., Bumroongsakulsawat P., Bumroongsri P., Kim-Lohsoontorn P. // Journal of Cleaner Production. 2024. V. 434. P. 139586. https://doi.org/10.1016/j.jclepro.2023.139586Bunsaksit C., Methaapanon R., Bumroongsakulsawat P., Bumroongsri P., Kim-Lohsoontorn P. // Journal of Cleaner Production. 2024. V. 434. P. 139586. https://doi.org/10.1016/j.jclepro.2023.139586Wu X., Kang M., Yin Y., Wang F., Zhao N., Xiao F., Wei W., Sun Y. // Applied Catalysis A: General. 2014. V. 473. P. 13-20. https://doi.org/10.1016/j.apcata.2013.12.034Wu X., Kang M., Yin Y., Wang F., Zhao N., Xiao F., Wei W., Sun Y. // Applied Catalysis A: General. 2014. V. 473. P. 13-20. https://doi.org/10.1016/j.apcata.2013.12.034Минигулов Ф.Г., Пресняков В.В., Шигабутдинов А.К., Сафин Д.Х., Пресняков А.В., Валитов А.Р., Сафин А.Ф. // Пластические массы. 2020. №. (5-6). С. 45-47. https://doi.org/10.35164/0554-2901-2020-5-6-45-47Минигулов Ф.Г., Пресняков В.В., Шигабутдинов А.К., Сафин Д.Х., Пресняков А.В., Валитов А.Р., Сафин А.Ф. // Пластические массы. 2020. №. (5-6). С. 45-47. https://doi.org/10.35164/0554-2901-2020-5-6-45-47Deng W., Shi L., Yao J., Zhang Z. // Carbon Resources Conversion. 2019. V. 2. P. 198-212. https://doi.org/10.1016/j.crcon.2019.10.004Deng W., Shi L., Yao J., Zhang Z. // Carbon Resources Conversion. 2019. V. 2. P. 198-212. https://doi.org/10.1016/j.crcon.2019.10.004Williams D.B.G., Sibiya M.S., van Heerden P.S., Kirk M., Harris R. // J. Mol. Catal. A: Chem. 2009. V. 304. P. 147–152. https://doi.org/10.1016/j.molcata.2009.02.005Williams D.B.G., Sibiya M.S., van Heerden P.S., Kirk M., Harris R. // J. Mol. Catal. A: Chem. 2009. V. 304. P. 147–152. https://doi.org/10.1016/j.molcata.2009.02.005Wei T., Wang M., Wei W., Sun Y., Zhong B. // Fuel Process Technol. 2003. V. 83. P. 175–182. https://doi.org/10.1016/S0378-3820(03)00065-1Wei T., Wang M., Wei W., Sun Y., Zhong B. // Fuel Process Technol. 2003. V. 83. P. 175–182. https://doi.org/10.1016/S0378-3820(03)00065-1Murugan C., Bajaj H., Jasra R. // Catal. Lett. 2010. V. 137. P. 224-231. https://doi.org/10.1007/s10562-010-0348-6Murugan C., Bajaj H., Jasra R. // Catal. Lett. 2010. V. 137. P. 224-231. https://doi.org/10.1007/s10562-010-0348-6De Filippis P., Scarsella M., Borgianni C., Pochetti F. // Energy Fuels. 2006. V. 20.P. 17-20. https://doi.org/10.1021/ef050142kDe Filippis P., Scarsella M., Borgianni C., Pochetti F. // Energy Fuels. 2006. V. 20.P. 17-20. https://doi.org/10.1021/ef050142kSankar M., Nair C.M., Murty K., Manikandan P. // Appl. Catal. A: Gen. 2006. V. 312. P. 108-114. https://doi.org/10.1016/j.apcata.2006.06.034Sankar M., Nair C.M., Murty K., Manikandan P. // Appl. Catal. A: Gen. 2006. V. 312. P. 108-114. https://doi.org/10.1016/j.apcata.2006.06.034Bhanage B.M., Fujita S.-I., Ikushima Y., Arai M. // Appl. Catal. A: Gen. 2001. V. 219. P. 259-266. https://doi.org/10.1016/S0926-860X(01)00698-6Bhanage B.M., Fujita S.-I., Ikushima Y., Arai M. // Appl. Catal. A: Gen. 2001. V. 219. P. 259-266. https://doi.org/10.1016/S0926-860X(01)00698-6Song Z., Jin X., Hu Y., Subramaniam B., Chaudhari R.V. // ACS Sustainable Chem. Eng. 2017. V. 5. P. 4718–4729. https://doi.org/10.1021/acssuschemeng.7b00095Song Z., Jin X., Hu Y., Subramaniam B., Chaudhari R.V. // ACS Sustainable Chem. Eng. 2017. V. 5. P. 4718–4729. https://doi.org/10.1021/acssuschemeng.7b00095Kumar P., Srivastava V.C., Mishra I.M. // Catal. Commun. 2015. V. 60. P. 27–31. https://doi.org/10.1016/j.catcom.2014.11.006Kumar P., Srivastava V.C., Mishra I.M. // Catal. Commun. 2015. V. 60. P. 27–31. https://doi.org/10.1016/j.catcom.2014.11.006Kumar P., Srivastava V.C., Mishra I.M. // Appl. Clay Sci. 2017. V. 150. P. 275–281. https://doi.org/10.1016/j.clay.2017.09.020Kumar P., Srivastava V.C., Mishra I.M. // Appl. Clay Sci. 2017. V. 150. P. 275–281. https://doi.org/10.1016/j.clay.2017.09.020Saada R., AboElazayem O., Kellici S., Heil T., Morgan D., Lampronti G.I., Saha B. // Appl. Catal. B: Environ. 2018. V. 226. P. 451–462. https://doi.org/10.1016/j.apcatb.2017.12.081Saada R., AboElazayem O., Kellici S., Heil T., Morgan D., Lampronti G.I., Saha B. // Appl. Catal. B: Environ. 2018. V. 226. P. 451–462. https://doi.org/10.1016/j.apcatb.2017.12.081Патент US 5631396, опубл. 20.05.1997.Патент US 5631396, опубл. 20.05.1997.Pacheco M. A., Marshall C. L. // Energy & Fuels. 1997. V. 11. P. 2-29. https://doi.org/10.1021/ef9600974Pacheco M. A., Marshall C. L. // Energy & Fuels. 1997. V. 11. P. 2-29. https://doi.org/10.1021/ef9600974Патент EP 425197, опубл. 02.05.1991.Патент EP 425197, опубл. 02.05.1991.Lv D.M., Xu Z.N., Peng S.Y., Wang Z.Q., Chen Q.S., Chen Y., Guo G.C. // Catal. Sci. Technol. 2015. V. 5. P. 3333–3339. https://doi.org/10.1039/C5CY00251FLv D.M., Xu Z.N., Peng S.Y., Wang Z.Q., Chen Q.S., Chen Y., Guo G.C. // Catal. Sci. Technol. 2015. V. 5. P. 3333–3339. https://doi.org/10.1039/C5CY00251FMatsuzaki T., Nakamura A. // Catalysis Survey of Japan. 1997. V. 1. P. 77-88. https://doi.org/10.1023/A:1019020812365Matsuzaki T., Nakamura A. // Catalysis Survey of Japan. 1997. V. 1. P. 77-88. https://doi.org/10.1023/A:1019020812365Патент US 5292916, опубл. 08.03.1994.Патент US 5292916, опубл. 08.03.1994.Патент US 5214184, опубл. 25.05.1993.Патент US 5214184, опубл. 25.05.1993.Chen S., Wang S., Ma X., Gong J. // Chem. Commun. 2011. V. 47. P. 9345-9347. https://doi.org/10.1039/C1CC12391BChen S., Wang S., Ma X., Gong J. // Chem. Commun. 2011. V. 47. P. 9345-9347. https://doi.org/10.1039/C1CC12391BDelledonne D., Rivetti F., Romano U. // Applied Catalysis A: General. 2001. V. 221. P. 241-251. https://doi.org/10.1016/S0926-860X(01)00796-7Delledonne D., Rivetti F., Romano U. // Applied Catalysis A: General. 2001. V. 221. P. 241-251. https://doi.org/10.1016/S0926-860X(01)00796-7Dong Y., Huang S., Wang S., Zhao Y., Gong J., Ma X. // ChemCatChem. 2013. V. 5 P. 2174-2177. https://doi.org/10.1002/cctc.201300170Dong Y., Huang S., Wang S., Zhao Y., Gong J., Ma X. // ChemCatChem. 2013. V. 5 P. 2174-2177. https://doi.org/10.1002/cctc.201300170Guo R., Hou Z., Chen J., Qin Y., Chai G., Yao Y. // Fuel. 2022. V. 330. P. 125484. https://doi.org/10.1016/j.fuel.2022.125484Guo R., Hou Z., Chen J., Qin Y., Chai G., Yao Y. // Fuel. 2022. V. 330. P. 125484. https://doi.org/10.1016/j.fuel.2022.125484Guo R., Qin Y., Qiao L., Chen J., Wu X., Yao Y. // Catal. Commun. 2017. V. 88. P. 94-98. https://doi.org/10.1016/j.catcom.2016.10.007Guo R., Qin Y., Qiao L., Chen J., Wu X., Yao Y. // Catal. Commun. 2017. V. 88. P. 94-98. https://doi.org/10.1016/j.catcom.2016.10.007Wu S., Chen J., Guo R., Tong H., Zong S., Diao Z., Qin Y., Yao Y. // Chemical Engineering Journal. 2024. V. 486. P. 150188. https://doi.org/10.1016/j.cej.2024.150188Wu S., Chen J., Guo R., Tong H., Zong S., Diao Z., Qin Y., Yao Y. // Chemical Engineering Journal. 2024. V. 486. P. 150188. https://doi.org/10.1016/j.cej.2024.150188Wu S., Guo R., Chen J., Ye R., Qin Y., Wu H., Zong S., Liu Y., Yao Y. // Fuel. 2023. V. 342. P. 127756. https://doi.org/10.1016/j.fuel.2023.127756Wu S., Guo R., Chen J., Ye R., Qin Y., Wu H., Zong S., Liu Y., Yao Y. // Fuel. 2023. V. 342. P. 127756. https://doi.org/10.1016/j.fuel.2023.127756Патент US 4218391, опубл. 19.08.1980.Патент US 4218391, опубл. 19.08.1980.Romano U., Tesel R., Mauri M.M., Rebora P. // Industrial & Engineering Chemistry Product Research and Development. 1980. V. 19. P. 396-403. https://doi.org/10.1021/i360075a021Romano U., Tesel R., Mauri M.M., Rebora P. // Industrial & Engineering Chemistry Product Research and Development. 1980. V. 19. P. 396-403. https://doi.org/10.1021/i360075a021https://cdn.ihs.com/www/pdf/RP301-toc.pdf – дата обращения 18.09.2025https://cdn.ihs.com/www/pdf/RP301-toc.pdf – дата обращения 18.09.2025Патент US 4318862, опубл. 9.03.1982.Патент US 4318862, опубл. 9.03.1982.Патент EP 534545, опубл. 31.03.1993.Патент EP 534545, опубл. 31.03.1993.Патент US 4625044, опубл. 25.11.1986.Патент US 4625044, опубл. 25.11.1986.Патент US 5004827, опубл. 02.04.1991.Патент US 5004827, опубл. 02.04.1991.Itoh H., Watanabe Y., Mori K., Umino H. // Green Chemistry. 2003. V. 5. P. 558-562. https://doi.org/10.1039/B304618BItoh H., Watanabe Y., Mori K., Umino H. // Green Chemistry. 2003. V. 5. P. 558-562. https://doi.org/10.1039/B304618BHan M.S., Lee B.G., Suh I., Kim H.S., Ahn B.S., Hong S.I. // Journal of Molecular Catalysis A: Chemical. 2001. V. 170. P. 225-234. https://doi.org/10.1016/S1381-1169(01)00073-5Han M.S., Lee B.G., Suh I., Kim H.S., Ahn B.S., Hong S.I. // Journal of Molecular Catalysis A: Chemical. 2001. V. 170. P. 225-234. https://doi.org/10.1016/S1381-1169(01)00073-5Punnoose A., Seehra M.S., Dunn B.C., Eyring E.M. // Energy & Fuels. 2002. V. 16. P. 182-188. https://doi.org/10.1021/ef010180dPunnoose A., Seehra M.S., Dunn B.C., Eyring E.M. // Energy & Fuels. 2002. V. 16. P. 182-188. https://doi.org/10.1021/ef010180dCurnutt G.L., Harley D.L. Oxygen Complexes and Oxygen Activation by Transition Metals. Plenum Publishing Co., New York, 1988, 215 p.Curnutt G.L., Harley D.L. Oxygen Complexes and Oxygen Activation by Transition Metals. Plenum Publishing Co., New York, 1988, 215 p.Ma X., Zhao R., Xu G., He F., Chen H. // Catal. Today. 1996. V. 30. P. 201-206. https://doi.org/10.1016/0920-5861(96)00013-2Ma X., Zhao R., Xu G., He F., Chen H. // Catal. Today. 1996. V. 30. P. 201-206. https://doi.org/10.1016/0920-5861(96)00013-2Han M.S., Lee B.G., Ahn B.S., Kim H.S., Moon D.J., Hong S.I. // J. Mol. Catal. A: Chem. 2003. V. 203. P. 137-143. https://doi.org/10.1016/S1381-1169(03)00131-6Han M.S., Lee B.G., Ahn B.S., Kim H.S., Moon D.J., Hong S.I. // J. Mol. Catal. A: Chem. 2003. V. 203. P. 137-143. https://doi.org/10.1016/S1381-1169(03)00131-6Zhang G., Li Z., Zheng H., Fu T., Ju Y., Wang Y. // Applied Catalysis B: Environmental. 2015. V. 179. P. 95-105. https://doi.org/10.1016/j.apcatb.2015.05.001Zhang G., Li Z., Zheng H., Fu T., Ju Y., Wang Y. // Applied Catalysis B: Environmental. 2015. V. 179. P. 95-105. https://doi.org/10.1016/j.apcatb.2015.05.001Zhang G., Li Z., Zheng H., Hao Z., Wang X., Wang J. // Applied Surface Science. 2016. V. 390. P. 68-77. https://doi.org/10.1016/j.apsusc.2016.08.054Zhang G., Li Z., Zheng H., Hao Z., Wang X., Wang J. // Applied Surface Science. 2016. V. 390. P. 68-77. https://doi.org/10.1016/j.apsusc.2016.08.054Wang J., Shi R., Hao P., Sun W., Liu S., Li Z., Ren J. // Journal of Materials Science. 2017. V. 53. P. 1833-1850. https://doi.org/10.1007/s10853-017-1639-8Wang J., Shi R., Hao P., Sun W., Liu S., Li Z., Ren J. // Journal of Materials Science. 2017. V. 53. P. 1833-1850. https://doi.org/10.1007/s10853-017-1639-8Fu T., Wang X., Zheng H., Li Z. // Carbon. 2017. V. 115. P. 363-374. https://doi.org/10.1016/j.carbon.2017.01.004Fu T., Wang X., Zheng H., Li Z. // Carbon. 2017. V. 115. P. 363-374. https://doi.org/10.1016/j.carbon.2017.01.004Ren X., Quan Y., Yang W., Zhao J., Shi R., Ren J. // Molecular Catalysis. 2022. V. 531. P. 112694. https://doi.org/10.1016/j.mcat.2022.112694Ren X., Quan Y., Yang W., Zhao J., Shi R., Ren J. // Molecular Catalysis. 2022. V. 531. P. 112694. https://doi.org/10.1016/j.mcat.2022.112694

The authors declare that there are no conflicts of interest present.