catalКатализ в промышленностиKataliz v promyshlennosti1816-03872413-6476LLC "KALVIS"10.18412/1816-0387-2026-2-85-93catal-1257Research ArticleКАТАЛИЗ В НЕФТЕПЕРЕРАБАТЫВАЮЩЕЙ ПРОМЫШЛЕННОСТИСATALYSIS IN PETROLEUM REFINING INDUSTRYСульфидные NiMo/цеолит-Al2O3-катализаторы для гидроочистки сырья, включающего в себя хлорсодержащее термолизное маслоNiMo/zeolite-Al2O3 sulfide catalysts for hydrotreating feedstocks including chlorine-containing thermolysis oilБогомоловаТ. С.BogomolovaT. S.ctls@kalvis.ruКрестьяниноваВ. С.KrestyaninovaV. S.ctls@kalvis.ruРомановаТ. С.RomanovaT. S.ctls@kalvis.ruМухачёваП. П.MukhachevaP. P.ctls@kalvis.ruСаломатинаА. А.SalomatinaA. A.ctls@kalvis.ruНадеинаК. А.NadeinaK. A.ctls@kalvis.ruВатутинаЮ. В.VatutinaYu. V.ctls@kalvis.ruКлимовО. В.KlimovO. V.ctls@kalvis.ruИнститут катализа им. Г.К. Борескова СО РАН, НовосибирскРоссияG.K. Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of ScienceRussian FederationИнститут катализа им. Г.К. Борескова СО РАН, Новосибирск; Новосибирский институт органической химии им. Н.Н. Ворожцова СО РАН, НовосибирскРоссияG.K. Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Science; N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of the Siberian Branch of the Russian Academy of ScienceRussian Federation2026300320262628593Copyright © LLC "KALVIS", 20262026LLC "KALVIS"LLC "KALVIS"https://www.catalysis-kalvis.ru/jour/about/submissions#copyrightNoticehttps://www.catalysis-kalvis.ru/jour/article/view/1257

Последние годы ознаменовались не только широким применением пластика во многих отраслях промышленности, но и ростом актуальности переработки и поиска альтернативных методов утилизации пластиковых отходов. В работе предложено внедрение продукта переработки пластиков в гидроочистку традиционных нефтяных фракций. Проведено исследование влияния использования моно- (Y/ZSM-23) и бицеолитных (Y+ZSM-23) сульфидных NiMo-катализаторов на процесс гидроочистки сырья, в состав которого входит хлорсодержащее термолизное масло. Показано, что все синтезированные катализаторы обеспечивают конверсию хлорсодержащих соединений выше 92 %. Обнаружено, что цеолитсодержащие катализаторы в процессе гидроочистки оказывают влияние на фракционный состав полученных гидрогенизатов за счет реакций крекинга и изомеризации, способствуя увеличению выхода светлых фракций. Показано, что катализатор на основе цеолита Y демонстрирует перспективу его применения благодаря высокой активности в превращении гетероатомных соединений и высококипящих н-алканов.

Recent years have seen not only by the widespread use of plastics in many industries but also by the growing importance of recycling and the search for alternative methods for plastic waste disposal. The work proposes the integration of plastic refining products into the hydrotreating process of traditional petroleum fractions. The effect of mono- (Y/ZSM-23) and bi-zeolite (Y+ZSM-23) sulfide NiMo catalysts on the hydrotreating process of feedstock comprising chlorine-containing thermolysis oil is studied. It is shown that all synthesized catalysts provide conversion of chlorine-containing compounds above 92%. It is found that zeolite-containing catalysts in the hydrotreating process affect the fractional composition of the obtained products due to cracking and isomerization reactions, contributing to an increase in the yield of light fractions. It is shown that the catalyst based on zeolite Y demonstrates the potential for its application due to its high activity in the conversion of heteroatomic compounds and high-boiling n-alkanes.

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