catalКатализ в промышленностиKataliz v promyshlennosti1816-03872413-6476LLC "KALVIS"10.18412/1816-0387-2015-6-47-55catal-306Research ArticleКАТАЛИЗ В НЕФТЕПЕРЕРАБАТЫВАЮЩЕЙ ПРОМЫШЛЕННОСТИСATALYSIS IN PETROLEUM REFINING INDUSTRYПерспективы использования Мо- и W-содержащих катализаторов в процессах гидроизомеризации: обзор патентной информации. Часть 1. Катализаторы на основе фосфидов молибдена и вольфрамаProspects of Mo- and W-containing Catalysts for Hydroisomerization: Patentent Survey. Part 1. Catalysts Based on Molybdenum and Tungsten PhosphidesУржунцевГ. А.UrzhuntsevG. A.ctls@kalvis.ruТоктаревА. В.ToktarevA. V.atok@catalysis.ruЕчевскийГ. В.EchevskiyG. V.egv@catalysis.ruДелийИ. В.DeliyI. V.delij@catalysis.ruВласоваЕ. Н.VlasovaV. N.evgenia@catalysis.ruБухтияроваГ. А.BukhtiyarovaG. A.gab@catalysis.ruИнститут катализа им. Г.К. Борескова СО РАН, г. НовосибирскРоссияBoreskov Institute of Catalysis, NovosibirskRussian Federation2015290120161564755Copyright © LLC "KALVIS", 20162016LLC "KALVIS"LLC "KALVIS"https://www.catalysis-kalvis.ru/jour/about/submissions#copyrightNoticehttps://www.catalysis-kalvis.ru/jour/article/view/306

Проведен анализ патентной информации в области способов приготовления и использования каталитических систем, содержащих фосфиды молибдена и вольфрама, в процессах гидроизомеризации парафиновых углеводородов. Анализ патентной информации показал, что модификация кислотных носителей фосфидами молибдена и вольфрама позволяет решить задачу создания стабильного катализатора гидроизомеризации парафиновых фракций, устойчивого к примесям серы в сырье гидроизомеризации.

Patent research was focused on methods for preparation and use of molybdenum and tungsten phosphide containing catalytic systems for hydroisomerization of paraffin hydrocarbons. Analysis of the patent data showed that modification of acidic supports with molybdenum and tungsten phosphides is promising for creating a stable catalyst for hydroisomerization of paraffin fractions, which would be stable to sulfur impurities in hydroisomerization feedstock.

молибденвольфрамфосфидыкатализаторгидрированиеизомеризацияmolybdenumtungstenphosphidescatalysthydrogenationisomerizationReferencesТехнический регламент «О требованиях к бензинам, дизельному и судовому топливу, топливу для реактивных двигателей и топочному мазуту». Утв. Постановлением Правительства РФ от 27 февраля 2008 г. № 118, г. Москва (в ред. Пост. Правительства РФ от 07.09.2011. № 148).Технический регламент «О требованиях к бензинам, дизельному и судовому топливу, топливу для реактивных двигателей и топочному мазуту». Утв. Постановлением Правительства РФ от 27 февраля 2008 г. № 118, г. Москва (в ред. Пост. Правительства РФ от 07.09.2011. № 148).C. Márquez-Alvarez, J.B. Calridge, A.P.E. York, J. Sloan, M.L.H. Green // Studies in Surface Science and Catalysis. 1997. V. 106. P. 485–490.C. Márquez-Alvarez, J.B. Calridge, A.P.E. York, J. Sloan, M.L.H. Green // Studies in Surface Science and Catalysis. 1997. V. 106. P. 485–490.J.-S. Choi, G. Bugli, G. Djéga-Mariadassou // J. Catal. 2000. V. 193. P. 238–247.J.-S. Choi, G. Bugli, G. Djéga-Mariadassou // J. Catal. 2000. V. 193. P. 238–247.M. Usman, D. Li, R. Razzaq, M. Yaseen, Ch. Li, S. Zhang // J. Ind. Eng. Chem. 2015. V. 23. P. 21–26.M. Usman, D. Li, R. Razzaq, M. Yaseen, Ch. Li, S. Zhang // J. Ind. Eng. Chem. 2015. V. 23. P. 21–26.A.P.E. York, C. Pham-Huu, P. Del Gallo, Marc J. Ledoux // Catal. Today. 1997. V. 35. P. 51–57.A.P.E. York, C. Pham-Huu, P. Del Gallo, Marc J. Ledoux // Catal. Today. 1997. V. 35. P. 51–57.F.H. Ribeiro, M. Boudart, R.A. Dalla Betta, E. Iglesia // J. Catal. 1991. V. 130. P. 498–513.F.H. Ribeiro, M. Boudart, R.A. Dalla Betta, E. Iglesia // J. Catal. 1991. V. 130. P. 498–513.P. Liu, M. Wu, J. Wang, W. Zhang, Y. Li // Fuel Process. Technol. 2015. V. 131. P. 311–316.P. Liu, M. Wu, J. Wang, W. Zhang, Y. Li // Fuel Process. Technol. 2015. V. 131. P. 311–316.Y. Choi, J. Lee, J. Shin, S. Lee, D. Kim, J. Kyoo Lee // Appl. Catal. A: General. 2015. V. 492. P. 140–150.Y. Choi, J. Lee, J. Shin, S. Lee, D. Kim, J. Kyoo Lee // Appl. Catal. A: General. 2015. V. 492. P. 140–150.Sh.J. Ardakani, K.J. Smith // Appl. Catal. A: General. 2011. V. 403. P. 36–47.Sh.J. Ardakani, K.J. Smith // Appl. Catal. A: General. 2011. V. 403. P. 36–47.Y. Kim, G. Yun, Y. Lee // Catal. Commun. 2014. V. 45. P. 133–138.Y. Kim, G. Yun, Y. Lee // Catal. Commun. 2014. V. 45. P. 133–138.D.-V.N. Vo, A.A. Adesina // Appl. Catal. A: General. 2011. V. 399. P. 221–232.D.-V.N. Vo, A.A. Adesina // Appl. Catal. A: General. 2011. V. 399. P. 221–232.A. Griboval-Constant, J.-M. Giraudon, I. Twagishema, G. Leclercq, M.E. Rivas, J. Alvarez, M.J. Perez-Zurita, M.R. Goldwasser // J. Mol. Catal. A: Chemical. 2006. V. 259. P. 187–196.A. Griboval-Constant, J.-M. Giraudon, I. Twagishema, G. Leclercq, M.E. Rivas, J. Alvarez, M.J. Perez-Zurita, M.R. Goldwasser // J. Mol. Catal. A: Chemical. 2006. V. 259. P. 187–196.E. Furimsky // Appl. Catal. A: General. 2003. V. 240. P. 1–28.E. Furimsky // Appl. Catal. A: General. 2003. V. 240. P. 1–28.S. Ted Oyama, T. Gott, H. Zhao, Y.-K. Lee // Catal. Today. 2009. V. 143. P. 94–107.S. Ted Oyama, T. Gott, H. Zhao, Y.-K. Lee // Catal. Today. 2009. V. 143. P. 94–107.L. Volpe, M. Boudart // J. Solid State Chem. 1985. V. 59. P. 348–356.L. Volpe, M. Boudart // J. Solid State Chem. 1985. V. 59. P. 348–356.M.J. Ledoux, C. Pram Huu, J. Guille, H. Dunlop // J. Catal. 1992. V. 134. P. 383–398.M.J. Ledoux, C. Pram Huu, J. Guille, H. Dunlop // J. Catal. 1992. V. 134. P. 383–398.S. Carenco, A. Leyva-Perez, P. Concepcion, C. Boissiere, N. Mezailles, C. Sanchez, A. Corma // Nano Today. 2012. V. 7. P. 21–28.S. Carenco, A. Leyva-Perez, P. Concepcion, C. Boissiere, N. Mezailles, C. Sanchez, A. Corma // Nano Today. 2012. V. 7. P. 21–28.F. Sun, W. Wu, Z. Wu, J. Guo, Z. Wei, Y. Yang, Z. Jiang, F. Tian, C. Li // J. Catal. 2004. V. 228. P. 298–310.F. Sun, W. Wu, Z. Wu, J. Guo, Z. Wei, Y. Yang, Z. Jiang, F. Tian, C. Li // J. Catal. 2004. V. 228. P. 298–310.A. Infantes-Molina, C. Moreno-Leon, B. Pawelec, J. Fierro, E. Rodriguez-Castellon, A. Jimenez-Lopez // Appl. Catal. B: Environmental. 2012. V. 113–114. P. 87–99.A. Infantes-Molina, C. Moreno-Leon, B. Pawelec, J. Fierro, E. Rodriguez-Castellon, A. Jimenez-Lopez // Appl. Catal. B: Environmental. 2012. V. 113–114. P. 87–99.C. Stinner, R. Prins, Th. Weber // J. Catal. 2001. V. 202. P. 187–194.C. Stinner, R. Prins, Th. Weber // J. Catal. 2001. V. 202. P. 187–194.V. Zuzaniuk, R. Prins // J. Catal. 2003. V. 219. P. 85–96.V. Zuzaniuk, R. Prins // J. Catal. 2003. V. 219. P. 85–96.H. Shi, J. Chen, Y. Yang, Sh. Tian // Fuel Process. Technol. 2014. V. 118. P. 161–170.H. Shi, J. Chen, Y. Yang, Sh. Tian // Fuel Process. Technol. 2014. V. 118. P. 161–170.P. Bui, J.A. Cecilia, S. Ted Oyama, A. Takagaki, A. Infantes-Molina, H. Zhao, D. Li , E. Rodríguez-Castellón, A.J. López // J. Catal. 2012. V. 294. P. 184–198.P. Bui, J.A. Cecilia, S. Ted Oyama, A. Takagaki, A. Infantes-Molina, H. Zhao, D. Li , E. Rodríguez-Castellón, A.J. López // J. Catal. 2012. V. 294. P. 184–198.S. Tian, J. Chen // Fuel Process. Technol. 2014. V. 122. P. 120–128.S. Tian, J. Chen // Fuel Process. Technol. 2014. V. 122. P. 120–128.S. Ted Oyama // J. Catal. 2003. V. 216. P. 343–352.S. Ted Oyama // J. Catal. 2003. V. 216. P. 343–352.P. Clark, S.T. Oyama // Journal of Catalysis. 2003. V. 218. P. 78–87.P. Clark, S.T. Oyama // Journal of Catalysis. 2003. V. 218. P. 78–87.M.V. Landau, M. Herskowitz, T. Hoffman, D. Fuks, E. Liverts, D. Vingurt, N. Froumin // Ind. Eng. Chem. Res. 2009. V. 48. P. 5239–5249.M.V. Landau, M. Herskowitz, T. Hoffman, D. Fuks, E. Liverts, D. Vingurt, N. Froumin // Ind. Eng. Chem. Res. 2009. V. 48. P. 5239–5249.K. Soni, P. Boahene, N. Rambabu, A.K. Dalai, J. Adjaye // Catal. Today. 2013. V. 207. P. 119–126.K. Soni, P. Boahene, N. Rambabu, A.K. Dalai, J. Adjaye // Catal. Today. 2013. V. 207. P. 119–126.J.A. Rodriguez, F. Viñes, P. Liu, F. Illas. Chapter 6. Role of C and P Sites on the Chemical Activity of Metal Carbides and Phosphides: From Clusters to Single-Crystal Surfaces in Model Systems in Catalysis, Editor: R. Rioux, Springer. 2010. Р. 117–132.J.A. Rodriguez, F. Viñes, P. Liu, F. Illas. Chapter 6. Role of C and P Sites on the Chemical Activity of Metal Carbides and Phosphides: From Clusters to Single-Crystal Surfaces in Model Systems in Catalysis, Editor: R. Rioux, Springer. 2010. Р. 117–132.Pat. WO 0123501. Novel transition metal phosphide catalysts / S.T. Oyama; Virginia Polytechnic Institute and State University (US); заявл. 30.09.1999; опубл. 05.04.2001.Pat. WO 0123501. Novel transition metal phosphide catalysts / S.T. Oyama; Virginia Polytechnic Institute and State University (US); заявл. 30.09.1999; опубл. 05.04.2001.Pat. EP 2218502. Transition metal phosphide catalysts / S.T. Oyama; Institut Français du Pétrole - IFP (FR); заявл. 30.09.1999; опубл. 18.08.2010.Pat. EP 2218502. Transition metal phosphide catalysts / S.T. Oyama; Institut Français du Pétrole - IFP (FR); заявл. 30.09.1999; опубл. 18.08.2010.Pat. CN 1463792. Novel molybdenum phosphorized hydrogenation desulfurization denitrification de-olefin catalyst and method for making same / F. Li, C. Li, T. Zhao; Beijing Stone Petrol Chemical (CN); заявл. 03.06.2002; опубл. 31.12.2003.Pat. CN 1463792. Novel molybdenum phosphorized hydrogenation desulfurization denitrification de-olefin catalyst and method for making same / F. Li, C. Li, T. Zhao; Beijing Stone Petrol Chemical (CN); заявл. 03.06.2002; опубл. 31.12.2003.Pat. CN 1492025. Process for preparing load type transition metal phosphide deep hydrogenation desulfurizing catalyst / A. Wang, L. Ruan; Dalian University of Technology, Department of Materials Science and Chemical Engineering (CN); заявл. 27.08.2003; опубл. 28.04.2004.Pat. CN 1492025. Process for preparing load type transition metal phosphide deep hydrogenation desulfurizing catalyst / A. Wang, L. Ruan; Dalian University of Technology, Department of Materials Science and Chemical Engineering (CN); заявл. 27.08.2003; опубл. 28.04.2004.Pat. CN 1660695. Method for preparing phosphide of transition metal / C. Li, F. Sun, J. Guo; Dalian Institute of Chemistry and Physics CAS (CN); заявл. 26.02.2004; опубл. 31.08.2005.Pat. CN 1660695. Method for preparing phosphide of transition metal / C. Li, F. Sun, J. Guo; Dalian Institute of Chemistry and Physics CAS (CN); заявл. 26.02.2004; опубл. 31.08.2005.Pat. US 7446075. Transition metal phosphides and hydrotreating process using the same / E.T. Kolev; UOP LLC (US); заявл. 23.08.2005; опубл. 04.11.2008.Pat. US 7446075. Transition metal phosphides and hydrotreating process using the same / E.T. Kolev; UOP LLC (US); заявл. 23.08.2005; опубл. 04.11.2008.Pat. CN 101011664. Method for preparing metal phosphide hydrogenation refining catalyst by using hydrogen plasma reduction method / A.Q. Wamg; Dalian University of Technology (CN); заявл. 09.01.2007; опубл. 08.08.2007.Pat. CN 101011664. Method for preparing metal phosphide hydrogenation refining catalyst by using hydrogen plasma reduction method / A.Q. Wamg; Dalian University of Technology (CN); заявл. 09.01.2007; опубл. 08.08.2007.Pat. CN 101011665. Double-metal phosphide hydrogenation refining catalyst / A.D. Wang; Dalian University of Technology (CN); заявл. 09.01.2007; опубл. 08.08.2007.Pat. CN 101011665. Double-metal phosphide hydrogenation refining catalyst / A.D. Wang; Dalian University of Technology (CN); заявл. 09.01.2007; опубл. 08.08.2007.Pat. CN 101623647. Molybdenum phosphide (MoP) prepared by hypophosphite precursor thermal decomposition method / W. Li, Q. Guan; Nankai University (СN); заявл. 12.08.2009; опубл. 13.01.2010.Pat. CN 101623647. Molybdenum phosphide (MoP) prepared by hypophosphite precursor thermal decomposition method / W. Li, Q. Guan; Nankai University (СN); заявл. 12.08.2009; опубл. 13.01.2010.Pat. CN 101658796. New method for preparing molybdenum phosphide by reducing molybdenum trioxide precursor / W. Li, Q. Guan, M. Zhang; Nankai University (СN); заявл. 17.09.2009; опубл. 03.03.2010.Pat. CN 101658796. New method for preparing molybdenum phosphide by reducing molybdenum trioxide precursor / W. Li, Q. Guan, M. Zhang; Nankai University (СN); заявл. 17.09.2009; опубл. 03.03.2010.Pat. CN 102211032. Preparation method of hydrodesulfurization phosphide catalyst for diesel oil / G. Shaohui, L. Ling; PetroChina Company Limited (CN); заявл. 07.04.2010; опубл. 12.10.2011.Pat. CN 102211032. Preparation method of hydrodesulfurization phosphide catalyst for diesel oil / G. Shaohui, L. Ling; PetroChina Company Limited (CN); заявл. 07.04.2010; опубл. 12.10.2011.Pat. CN 101992109. Transition metal phosphide hydrofined catalyst and a preparation method thereof / L. Mohong, L. Mingshi; Changzhou Jiekong Materials Co LTD (CN); заявл. 06.09.2010; опубл. 30.03.2011.Pat. CN 101992109. Transition metal phosphide hydrofined catalyst and a preparation method thereof / L. Mohong, L. Mingshi; Changzhou Jiekong Materials Co LTD (CN); заявл. 06.09.2010; опубл. 30.03.2011.Pat. CN 102989492. Supported composite sulfur phosphide hydrotreatment catalyst, preparation and applications thereof / G. Shaohui, L. Kunhong, L.Ling et al.; PetroChina Company Limited (CN); заявл. 15.09.2011; опубл. 27.03.2013.Pat. CN 102989492. Supported composite sulfur phosphide hydrotreatment catalyst, preparation and applications thereof / G. Shaohui, L. Kunhong, L.Ling et al.; PetroChina Company Limited (CN); заявл. 15.09.2011; опубл. 27.03.2013.Pat. CN 102989493. Heavy oil hydrotreating composite catalyst preparation method / G. Shaohui, L. Kunhong, L.Ling et al.; PetroChina Company Limited (CN); заявл. 15.09.2011; опубл. 27.03.2013.Pat. CN 102989493. Heavy oil hydrotreating composite catalyst preparation method / G. Shaohui, L. Kunhong, L.Ling et al.; PetroChina Company Limited (CN); заявл. 15.09.2011; опубл. 27.03.2013.Pat. CN 102994147. Method for producing intermediate distillate oil through heavy oil medium pressure hydrocracking / G. Shaohui, L. Ling, M. An et al.; PetroChina Company Limited (CN); заявл. 15.09.2011; опубл. 27.03.2013.Pat. CN 102994147. Method for producing intermediate distillate oil through heavy oil medium pressure hydrocracking / G. Shaohui, L. Ling, M. An et al.; PetroChina Company Limited (CN); заявл. 15.09.2011; опубл. 27.03.2013.Pat. CN 103157497. Preparation method of thermometal phosphide hydrofining catalyst / L. Wei, W. Ruchao; Nankai University (СN); заявл. 08.04.2013; опубл. 19.06.2013.Pat. CN 103157497. Preparation method of thermometal phosphide hydrofining catalyst / L. Wei, W. Ruchao; Nankai University (СN); заявл. 08.04.2013; опубл. 19.06.2013.Pat. CN 102994141. Poor quality aviation kerosene hydrotreatment method / L. Kunhong, H. Yuandong, L.Ling et al.; PetroChina Company Limited (CN); заявл. 15.09.2011; опубл. 27.03.2013.Pat. CN 102994141. Poor quality aviation kerosene hydrotreatment method / L. Kunhong, H. Yuandong, L.Ling et al.; PetroChina Company Limited (CN); заявл. 15.09.2011; опубл. 27.03.2013.Pat. EP 2415520. Metal phosphorus compound for preparing biodiesel and method preparing biodiesel using the same / S.I. Lee, D.W. Kim, H.J. Jeon, S.J. Ju, J.W. Ryu, S.H. Oh, J.H. Koh; SK Innovation Co LTD (KR); заявл. 01.04.2010; опубл. 08.02.2012.Pat. EP 2415520. Metal phosphorus compound for preparing biodiesel and method preparing biodiesel using the same / S.I. Lee, D.W. Kim, H.J. Jeon, S.J. Ju, J.W. Ryu, S.H. Oh, J.H. Koh; SK Innovation Co LTD (KR); заявл. 01.04.2010; опубл. 08.02.2012.Pat. US 2014150332. Metal phosphorus compound for preparing biodiesel and method preparing biodiesel using the same / S.I. Lee, D.W. Kim, H.J. Jeon, S.J. Ju, J.W. Ryu, S.H. Oh, J.H. Koh; SK Innovation Co LTD (KR); заявл. 01.04.2010; опубл. 05.06.2014.Pat. US 2014150332. Metal phosphorus compound for preparing biodiesel and method preparing biodiesel using the same / S.I. Lee, D.W. Kim, H.J. Jeon, S.J. Ju, J.W. Ryu, S.H. Oh, J.H. Koh; SK Innovation Co LTD (KR); заявл. 01.04.2010; опубл. 05.06.2014.Pat. CN 102585876. Method for preparing hydrocarbon from higher aliphatic ester by metal phosphide catalyst / J. Chen, K. Li, L. Li, H. Shi; Tianjin University (CN); заявл. 07.03.2012; опубл. 18.07.2012.Pat. CN 102585876. Method for preparing hydrocarbon from higher aliphatic ester by metal phosphide catalyst / J. Chen, K. Li, L. Li, H. Shi; Tianjin University (CN); заявл. 07.03.2012; опубл. 18.07.2012.Pat. CN 103756794. Method for producing second-generation biodiesel by hydrogenation production of illegal cooking oil / L. Lihua, L. Shiqun, S. Dengming et al.; Hebei Normal University (CN); заявл. 30.04.2014; опубл. 14.01.2015.Pat. CN 103756794. Method for producing second-generation biodiesel by hydrogenation production of illegal cooking oil / L. Lihua, L. Shiqun, S. Dengming et al.; Hebei Normal University (CN); заявл. 30.04.2014; опубл. 14.01.2015.Pat. CN 102887809. Method for hydroisomerizing normal alkane by using supported nickel phosphide catalyst / J. Chen, S. Tian; Tianjin University (CN); заявл. 17.10.2012; опубл. 23.01.2013.Pat. CN 102887809. Method for hydroisomerizing normal alkane by using supported nickel phosphide catalyst / J. Chen, S. Tian; Tianjin University (CN); заявл. 17.10.2012; опубл. 23.01.2013.Pat. CN 101168132. Process for preparing high dispersion supported type transition metal phosphide catalyst / R. Cheng, T. Zhang; Dalian Chemical Physics Institute (CN); заявл. 25.10.2006; опубл. 30.04.2008.Pat. CN 101168132. Process for preparing high dispersion supported type transition metal phosphide catalyst / R. Cheng, T. Zhang; Dalian Chemical Physics Institute (CN); заявл. 25.10.2006; опубл. 30.04.2008.R. Zarchin, M. Rabaev, R. Vidruk-Nehemya, M.V. Landau, M. Herskowitz. Hydroprocessing of soybean oil on nickel-phosphide supported catalysts // Fuel. 2015. V. 139. P. 684–691.R. Zarchin, M. Rabaev, R. Vidruk-Nehemya, M.V. Landau, M. Herskowitz. Hydroprocessing of soybean oil on nickel-phosphide supported catalysts // Fuel. 2015. V. 139. P. 684–691.

The authors declare that there are no conflicts of interest present.