<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD JATS (Z39.96) Journal Publishing DTD v1.3 20210610//EN" "JATS-journalpublishing1-3.dtd">
<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">catal</journal-id><journal-title-group><journal-title xml:lang="ru">Катализ в промышленности</journal-title><trans-title-group xml:lang="en"><trans-title>Kataliz v promyshlennosti</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">1816-0387</issn><issn pub-type="epub">2413-6476</issn><publisher><publisher-name>LLC "KALVIS"</publisher-name></publisher></journal-meta><article-meta><article-id custom-type="elpub" pub-id-type="custom">catal-65</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>КАТАЛИЗ В ХИМИЧЕСКОЙ И НЕФТЕХИМИЧЕСКОЙ ПРОМЫШЛЕННОСТИ</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>CATALYSIS IN CHEMICAL AND PETROCHEMICAL INDUSTRY</subject></subj-group></article-categories><title-group><article-title>Парциальное окисление метана в синтез-газ на ката- лизаторах на основе ячеистых металлических носи- телей</article-title><trans-title-group xml:lang="en"><trans-title>Partial oxidation of methane to synthesis gas on catalysts based on metal honeycomb supports</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Тарасов</surname><given-names>А. Л.</given-names></name><name name-style="western" xml:lang="en"><surname>Tarasov</surname><given-names>A. L.</given-names></name></name-alternatives><bio xml:lang="ru"><p>канд. хим. наук, ст. науч. сотрудник лаборатории № 14. Тел.: (499) 137-29-35</p></bio><email xlink:type="simple">atarasov@ioc.ac.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Кустов</surname><given-names>Л. М.</given-names></name><name name-style="western" xml:lang="en"><surname>Kustov</surname><given-names>L. M.</given-names></name></name-alternatives><bio xml:lang="ru"><p>д-р хим. наук, проф., зав. лабораторией № 14. Тел. тот же</p></bio><email xlink:type="simple">lmk@ioc.ac.ru</email><xref ref-type="aff" rid="aff-1"/></contrib></contrib-group><aff xml:lang="ru" id="aff-1"><institution>Институт органической химии им. Н.Д. Зелинского РАН, г. Москва</institution><country>Russian Federation</country></aff><pub-date pub-type="collection"><year>2012</year></pub-date><pub-date pub-type="epub"><day>21</day><month>11</month><year>2014</year></pub-date><volume>0</volume><issue>6</issue><fpage>7</fpage><lpage>13</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; LLC "KALVIS", 2014</copyright-statement><copyright-year>2014</copyright-year><copyright-holder xml:lang="ru">LLC "KALVIS"</copyright-holder><copyright-holder xml:lang="en">LLC "KALVIS"</copyright-holder><license xlink:href="https://www.catalysis-kalvis.ru/jour/about/submissions#copyrightNotice" xlink:type="simple"><license-p>https://www.catalysis-kalvis.ru/jour/about/submissions#copyrightNotice</license-p></license></permissions><self-uri xlink:href="https://www.catalysis-kalvis.ru/jour/article/view/65">https://www.catalysis-kalvis.ru/jour/article/view/65</self-uri><abstract><p>С целью разработки эффективных катализаторов на основе металлических ячеистых носителей для парциального окисления метана в синтез-газ проведены сравнительные испытания металлических катализаторов (Pd, Ni, Co, Cu, нанесенные на металлическую сетку и фехралевую фольгу), полученных двумя способами: термохимическим и электрохимическим осаждением металлов. Испытания проводили в интервале температур 680–1000 °С в проточном реакторе (внутренний диаметр 10 мм) с вмонтированным катализатором в виде скрученной в рулон металлической сетки или фехралевой фольги. Показано, что металлические носители (сетка, фольга) с нанесенными на них металлами (Pd, Ni) перспективны для использования в качестве катализаторов получения синтез-газа по реакции парциального окисления метана в узком диапазоне мольного соотношения кислород/метан (О2/СН4 = 0,45÷0,55). При изучении поверхности катализаторов методом СЭМ установлено, что при термохимическом осаждении металлов VIII группы формируется более разветвленная поверхность активных металлов, обеспечивающая уже при 900 °С практически 100 %-ную конверсию метана при селективности по СО более 90 %.</p></abstract><trans-abstract xml:lang="en"><p>To develop effective catalysts based on metal meshy supports for the reaction of the methane partial oxidation to synthesis gas there were the comparative tests of metal catalysts (Pd, Ni, Co, Cu, supported on a metal grid and fechral foil) obtained two ways: thermochemical and electrochemical deposition of metals. Tests were carried out in the temperature range 680–1000 °C in a flow reactor (internal diameter 10 mm) with integrated catalyst in the form of a twisted roll of wire mesh or fechral foil. It is shown that the metal supports (grid or foil) with metals (palladium, nickel) putted on them are promising for use as catalysts in the production of synthesis gas by the reaction of partial oxidation of methane in a narrow range of the molar ratio oxygen/methane (O2/СН4 = = 0,45÷0,55). In the study of catalyst surfaces by SEM there was revealed that the thermochemical deposition of VIII group metal more extensive area of active metals is formed, providing even at 900 °C almost 100 % conversion of methane with selectivity for CO over 90 %.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>катализ</kwd><kwd>окисление</kwd><kwd>синтез-газ</kwd><kwd>метан</kwd><kwd>никель</kwd><kwd>палладий</kwd><kwd>фехраль</kwd><kwd>металлические сетки</kwd></kwd-group><kwd-group xml:lang="en"><kwd>catalysis</kwd><kwd>oxidation</kwd><kwd>synthesis gas</kwd><kwd>methane</kwd><kwd>nickel</kwd><kwd>palladium</kwd><kwd>fechral</kwd><kwd>metal mesh</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Zaman Z. Oxidative processes in natural gas conversion, Fuel Processing Technology. 1999. Vol. 58. Р. 61—81.</mixed-citation><mixed-citation xml:lang="en">Zaman Z. Oxidative processes in natural gas conversion, Fuel Processing Technology. 1999. Vol. 58. Р. 61—81.</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Пат. США № 4,088,435. Method for combustion of carbonaceous fuel utilizing high temperature stable catalysts / Hindin, at. al.</mixed-citation><mixed-citation xml:lang="en">Пат. США № 4,088,435. Method for combustion of carbonaceous fuel utilizing high temperature stable catalysts / Hindin, at. al.</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Hickman D.A., Schmidt L.D. Synthesis gas formation by direct oxidation of methane over Pt monoliths // J. Catalysis. 1992. Vol. 138. Р. 267—282.</mixed-citation><mixed-citation xml:lang="en">Hickman D.A., Schmidt L.D. Synthesis gas formation by direct oxidation of methane over Pt monoliths // J. Catalysis. 1992. Vol. 138. Р. 267—282.</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Пат. США № 5,654,491. Process for partial oxidation of alkanes / Goetsch, at. al.</mixed-citation><mixed-citation xml:lang="en">Пат. США № 5,654,491. Process for partial oxidation of alkanes / Goetsch, at. al.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Пат. США №5,648,582. Stable, ultra-low residence time partial oxidation / Schmidt, at. al.</mixed-citation><mixed-citation xml:lang="en">Пат. США №5,648,582. Stable, ultra-low residence time partial oxidation / Schmidt, at. al.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">U.S. Patent Application Publication No. 2006/0029539 Al, published Feb. 9, 2006. Synthesis Gas Processing Comprising Partial Oxidation Using Controlled and Optimized Temperature Profile / Dutta S., Wright H.A.</mixed-citation><mixed-citation xml:lang="en">U.S. Patent Application Publication No. 2006/0029539 Al, published Feb. 9, 2006. Synthesis Gas Processing Comprising Partial Oxidation Using Controlled and Optimized Temperature Profile / Dutta S., Wright H.A.</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">An LIF Stugy of Methane Oxidation over Noble Metal Gause Catalysts. Abstract of 1999 Meeting in Dallas of Texas Assoc. Indust. Chem. Eng. Р. 289b.</mixed-citation><mixed-citation xml:lang="en">An LIF Stugy of Methane Oxidation over Noble Metal Gause Catalysts. Abstract of 1999 Meeting in Dallas of Texas Assoc. Indust. Chem. Eng. Р. 289b.</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Yong Lu, Yu Liu, Shikong Shen. Design of stable Ni catalysts for partial oxidation of methane to synthesis gas // J. Catalysis. 1998. Vol. 177. Р. 386—388.</mixed-citation><mixed-citation xml:lang="en">Yong Lu, Yu Liu, Shikong Shen. Design of stable Ni catalysts for partial oxidation of methane to synthesis gas // J. Catalysis. 1998. Vol. 177. Р. 386—388.</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Пат. РФ № 2153631. Способ неполного сгорания топлива (варианты) и каталитическая система, содержащая палладиевые катализаторы неполного сгорания (варианты) / Цуруми К. и др.</mixed-citation><mixed-citation xml:lang="en">Пат. РФ № 2153631. Способ неполного сгорания топлива (варианты) и каталитическая система, содержащая палладиевые катализаторы неполного сгорания (варианты) / Цуруми К. и др.</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
