catalКатализ в промышленностиKataliz v promyshlennosti1816-03872413-6476LLC "KALVIS"10.18412/1816-0387-2020-2-100-109catal-684Research ArticleКАТАЛИЗ В ХИМИЧЕСКОЙ И НЕФТЕХИМИЧЕСКОЙ ПРОМЫШЛЕННОСТИCATALYSIS IN CHEMICAL AND PETROCHEMICAL INDUSTRYCинтез Фишера – Тропша c кобальтовым катализатором на модифицированном оксидом титана карбиде кремнияThe Fischer – Tropsch synthesis with a cobalt catalyst on titania-doped silicon carbideСоломоникИ. Г.SolomonikI. G.ctls@kalvis.ruГоршковА. С.GorshkovA. S.ctls@kalvis.ruМордковичВ. З.MordkovichV. Z.ctls@kalvis.ruТехнологический институт сверхтвердых и новых углеродных материалов» (ТИСНУМ), МоскваРоссияTechnological Institute for Superhard and Novel Carbon Materials (TISNCM), MoscowRussian FederationООО «ИНФРА», МоскваРоссияINFRA Ltd, MoscowRussian Federation202001042020202100109Copyright © LLC "KALVIS", 20202020LLC "KALVIS"LLC "KALVIS"https://www.catalysis-kalvis.ru/jour/about/submissions#copyrightNoticehttps://www.catalysis-kalvis.ru/jour/article/view/684

A cobalt catalyst supported on titania-doped silicon carbide for the Fischer – Tropsch synthesis was synthesized and comprehensively studied using various physicochemical methods. The dynamics of behavior and deactivation of the catalyst, which showed a stable operation for 1500 hours, was studied in a continuous pilot-plant lifecycle test with periodic variation of flow rate, syngas pressure and process temperature. This catalyst has two types of active sites on which products with different parameters of the Schulz – Flory distribution are formed. Depending on the process mode, the efficient formation of «soft waxes» or products with a higher molecular weight can occur.

синтез Фишера – Тропшаноситель карбид кремния-оксид титанапараметр Шульца – Флорипилотная установкаFischer – Tropsch synthesissilicon carbide – titanium dioxide supportSchulz – Flory parameterpilot plantReferenceshttps://ru.infratechnology.com/technology/https://ru.infratechnology.com/technology/Mordkovich V.Z., Sineva L.V., Kulchakovskaya E.V., Ermolaev I.S., Solomonik I.G., Gryaznov K.O. // 8th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT8), August 5-10, 2018; YOKOHAMA, JAPAN. Abstracts, P2005 1 - P2005 2.Mordkovich V.Z., Sineva L.V., Kulchakovskaya E.V., Ermolaev I.S., Solomonik I.G., Gryaznov K.O. // 8th Tokyo Conference on Advanced Catalytic Science and Technology (TOCAT8), August 5-10, 2018; YOKOHAMA, JAPAN. Abstracts, P2005 1 - P2005 2.Solomonik I.G., Gryaznov K.O., Skok V.F., Mordkovich V.Z. // RSC Adv., 2015, 5, P. 78586—78597; DOI: 10.1039/c5ra11853k.Solomonik I.G., Gryaznov K.O., Skok V.F., Mordkovich V.Z. // RSC Adv., 2015, 5, P. 78586—78597; DOI: 10.1039/c5ra11853k.Грязнов К.О., Соломоник И.Г., Асалиева Е.Ю., Мордкович В.З. // Автозаправочный комплекс + альтернативное топливо. 2015. № 5 (98). С. 10—20.Грязнов К.О., Соломоник И.Г., Асалиева Е.Ю., Мордкович В.З. // Автозаправочный комплекс + альтернативное топливо. 2015. № 5 (98). С. 10—20.R??ler S., Kern C., Jess A. // Catalysis Science &Technology, DOI: 10.1039/c9cy00671k.R??ler S., Kern C., Jess A. // Catalysis Science &Technology, DOI: 10.1039/c9cy00671k.R??ler S., Kern C.,Jess A. // Catal. Sci. Technol., 2019, DOI: 10.1039/C8CY02551G.R??ler S., Kern C.,Jess A. // Catal. Sci. Technol., 2019, DOI: 10.1039/C8CY02551G.Solomonik I.G. ,Sineva L.V., Mordkovich V.Z. // MCR-IX, St Peterburg, October 22-25, 2012. ABSTRACTS, p. 267.Solomonik I.G. ,Sineva L.V., Mordkovich V.Z. // MCR-IX, St Peterburg, October 22-25, 2012. ABSTRACTS, p. 267.Lapidus A., Krylova A., Rathouskp J., Zukal A., Jan Eilkov M. // Applied Catalysis A: General 80 (1992). p. l-11.Lapidus A., Krylova A., Rathouskp J., Zukal A., Jan Eilkov M. // Applied Catalysis A: General 80 (1992). p. l-11.Jorge A. Delgado, Carmen Claver, Sergio Castill?n, Daniel Curulla-Ferr?, Vitaly V. Ordomsky, Cyril Godard // Applied Catalysis A: General 513 (2016) p.39—46 http://dx.doi.org/10.1016/j.apcata.2015.12.019.Jorge A. Delgado, Carmen Claver, Sergio Castill?n, Daniel Curulla-Ferr?, Vitaly V. Ordomsky, Cyril Godard // Applied Catalysis A: General 513 (2016) p.39—46 http://dx.doi.org/10.1016/j.apcata.2015.12.019.Ilse van Ravenhorst, Charlotte Vogt, Heiko Oosterbeek, Koen Bossers, Jose Moya Cancino, Alexander van Bavel, Ad van der Eerden, David Vine, Frank de Groot, Florian Meirer, Bert Marc Weckhuysen // Angew. Chem. Int. Ed. 10.1002/anie.201806354.Ilse van Ravenhorst, Charlotte Vogt, Heiko Oosterbeek, Koen Bossers, Jose Moya Cancino, Alexander van Bavel, Ad van der Eerden, David Vine, Frank de Groot, Florian Meirer, Bert Marc Weckhuysen // Angew. Chem. Int. Ed. 10.1002/anie.201806354.Mej?a C.H., van Deelen T.W, de Jong K.P. Nature Communications, (2018) 9:4459, DOI: 10.1038/s41467-018-06903-w.Mej?a C.H., van Deelen T.W, de Jong K.P. Nature Communications, (2018) 9:4459, DOI: 10.1038/s41467-018-06903-w.Van Deelen T.W., Nijhuis J.J., Krans N.A., Jovana Ze?evi?, de Jong K.P. // ACS Catal., ACS Catal. 2018, 8, 11, 10581-105 89, https://doi.org/10.1021/acscatal.8b03094.Van Deelen T.W., Nijhuis J.J., Krans N.A., Jovana Ze?evi?, de Jong K.P. // ACS Catal., ACS Catal. 2018, 8, 11, 10581-105 89, https://doi.org/10.1021/acscatal.8b03094.Косолапова Т.Я. Карбиды. М.: Металлургия, 1968.Косолапова Т.Я. Карбиды. М.: Металлургия, 1968.www.sicatcatalyst.comwww.sicatcatalyst.comГлебов Л.С., Клигер Г.А. Успехи химии. 1994. 63 (2). С. 192—202.Глебов Л.С., Клигер Г.А. Успехи химии. 1994. 63 (2). С. 192—202.Yuefeng Liu, Benoit de Tymowski, Fabrice Vigneron, Ileana Florea, Ovidiu Ersen, Christian Meny, Patrick Nguyen, Charlotte Pham, Francis Luck, Cuong Pham-Huu. ACS Catal. 2013, 3,3, 393-404, https://doi.org/10.1021/cs300729p.Yuefeng Liu, Benoit de Tymowski, Fabrice Vigneron, Ileana Florea, Ovidiu Ersen, Christian Meny, Patrick Nguyen, Charlotte Pham, Francis Luck, Cuong Pham-Huu. ACS Catal. 2013, 3,3, 393-404, https://doi.org/10.1021/cs300729p.

The authors declare that there are no conflicts of interest present.