catalКатализ в промышленностиKataliz v promyshlennosti1816-03872413-6476LLC "KALVIS"10.18412/1816-0387-2023-1-37-55catal-864Research ArticleКАТАЛИЗ В ХИМИЧЕСКОЙ И НЕФТЕХИМИЧЕСКОЙ ПРОМЫШЛЕННОСТИCATALYSIS IN CHEMICAL AND PETROCHEMICAL INDUSTRYАлкоксикарбонилирование ненасыщенных субстратов растительного происхождения с использованием палладиевых катализаторов как путь к получению сложноэфирных продуктовAlkoxycarbonylation of Unsaturated Phytogenic Substrates Using Palladium Catalysts as a Way for Obtaining Ester ProductsСевостьяноваН. Т.SevostyanovaN. T.ctls@kalvis.ruБаташевС. А.BatashevS. A.ctls@kalvis.ruТульский государственный педагогический университет им. Л.Н. ТолстогоРоссияTula State Lev Tolstoy Pedagogical UniversityRussian Federation2023170120232313755Copyright © LLC "KALVIS", 20232023LLC "KALVIS"LLC "KALVIS"https://www.catalysis-kalvis.ru/jour/about/submissions#copyrightNoticehttps://www.catalysis-kalvis.ru/jour/article/view/864

Синтез сложных эфиров алкоксикарбонилированием ненасыщенных субстратов растительного происхождения открывает возможность перехода на альтернативные сырьевые источники и позволяет решить целый ряд проблем, стоящих перед химической промышленностью: ресурсосбережения, минимизации отходов и повышения экологической безопасности и экономичности реализуемых процессов. Однако на данный момент в промышленности реализуется только производство метилметакрилата, включающее как одну из стадий метоксикар-бонилирование этилена. Цель данного обзора – систематизация и анализ литературных данных, опубликованных с 2010 г., в области синтеза сложных эфиров алкоксикарбонилированием субстратов растительного происхождения в мягких условиях. Было установлено, что за указанный период осуществлено алкоксикарбонилирование пентеновых и ундеценовых кислот, олеиновой, линолевой и эруковой кислот или их сложных эфиров и терпеновых соединений – цитронелловой кислоты и β-мирцена. Показано, что высокие выходы и селективности по продуктам линейного строения обеспечивались в мягких условиях главным образом применением гомогенных палладий-дифосфиновых катализаторов. Результаты этих работ открывают широкие перспективы реализации новых для промышленности процессов алкоксикарбонилирования субстратов растительного происхождения для получения актуальных химических продуктов, прежде всего полимеров.

The synthesis of esters by alkoxycarbonylation of unsaturated phytogenic substrates makes it possible to use alternative feedstocks and solve a series of problems in the chemical industry: resource saving, waste minimization, and improvement of environmental safety and economicalefficiency of the processes being implemented. However, only the production of methyl methacrylate, which includes methoxycarbonylation of ethylene as one of the steps, has been implemented on the industrial scale by now. The aim of this review is to systematize and analyze the literature data published since 2010 on the synthesis of esters by alkoxycarbonylation of phytogenic substrates under mild conditions. It was found that the alkoxycarbonylation of pentenoic and undecenoic acids, oleic, linoleic and erucic acids or their esters as well as terpene compounds – citronellic acid and b-myrcene – has been performed in the indicated period. High yields and selectivities to the linear structured products were reached under mild conditions mostly due to the application of homogeneous palladium-diphosphine catalysts. Results of these studies open up ample opportunities for implementing new industrial processes of alkoxycarbonylation of phytogenic substrates aimed to obtain the advanced chemical products, particularly polymers.

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The authors declare that there are no conflicts of interest present.