catalКатализ в промышленностиKataliz v promyshlennosti1816-03872413-6476LLC "KALVIS"catal-934Research Article2011 – МЕЖДУНАРОДНЫЙ ГОД ХИМИИ2011 - INTERNATIONAL YEAR OF CHEMISTRYПрименение катализаторов на основе карбидов молибдена и вольфрама в реакции конверсии оксида углерода с водяным паромThe use of catalysts based on molybdenum and tungsten carbides in the reaction of carbon monoxide conversion with steamСеминГ. Л.SeminG. L.ctls@kalvis.ruДубровскийА. Р.DubrovskyA. R.ctls@kalvis.ruСнытниковП. В.SnytnikovP. V.ctls@kalvis.ruКузнецовС. А.KuznetsovS. A.ctls@kalvis.ruСобянинВ. А.SobyaninV. A.ctls@kalvis.ruИнститут катализа им. Г.К. Борескова СО РАН, Новосибирск; Новосибирский государственный университет, НовосибирскРоссияBoreskov Institute of Catalysis SB RAS, Novosibirsk; Novosibirsk State UniversityRussian FederationИнститут химии и технологии редких элементов и минерального сырья им. И.В. Тананаева РАН, АпатитыРоссияInstitute of Chemistry and Technology of Rare Elements and Mineral Raw Materials. I.V. Tananaev RAS, ApatityRussian FederationИнститут катализа им. Г.К. Борескова СО РАН, Новосибирск; Новосибирский государственный университет, Новосибирск; ООО «УНИКАТ», НовосибирскРоссияBoreskov Institute of Catalysis SB RAS, Novosibirsk; Novosibirsk State University; UNIKAT LLC, NovosibirskRussian Federation201127042023054453Copyright © LLC "KALVIS", 20232023LLC "KALVIS"LLC "KALVIS"https://www.catalysis-kalvis.ru/jour/about/submissions#copyrightNoticehttps://www.catalysis-kalvis.ru/jour/article/view/934

В обзоре представлены данные об основных направлениях применения карбидов молибдена и вольфрама в качестве катализаторов ряда промышленно важных реакций и рассмотрены основные решения по синтезу катализаторов. Некоторые из предложенных методов могут рассматриваться в качестве начального этапа разработки технологии промышленных катализаторов на основе карбидов молибдена и вольфрама. Наибольшей перспективой как катализатора в реакции конверсии СО водяным паром обладают композиции на основе Мо2С.

The review presents data on the main areas of application of molybdenum and tungsten carbides as catalysts for several industrially important reactions and the basic solutions for the synthesis of catalysts. Some of these methods can be considered as the initial phase of technology development of industrial catalysts based on molybdenum and tungsten carbides. The greatest prospect as a catalyst in the CO conversion by water vapor have a composition based on Mo2C.

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The authors declare that there are no conflicts of interest present.