References

catal

Катализ в промышленности

Kataliz v promyshlennosti

1816-03872413-6476

LLC "KALVIS"

10.18412/1816-0387-2023-4-6-32

catal-957

Research Article

КАТАЛИЗ В ХИМИЧЕСКОЙ И НЕФТЕХИМИЧЕСКОЙ ПРОМЫШЛЕННОСТИ

CATALYSIS IN CHEMICAL AND PETROCHEMICAL INDUSTRY

Каталитическое гидрирование СО2 как способ получения ценных химических продуктов

Catalytic hydrogenation of CO2 as a method for obtaining valuable chemical products

Макарян

И. А.

Makaryan

I. A.

ctls@kalvis.ru

Седов

И. В.

Sedov

I. V.

ctls@kalvis.ru

Савченко

В. И.

Savchenko

V. I.

ctls@kalvis.ru

Федеральное государственное учреждение науки Федеральный исследовательский центр проблем химической физики и медицинской химии Российской академии наук (ФГБУН ФИЦ ПХФ и МХ РАН), ЧерноголовкаРоссияFederal Research Center of Problems of Chemical Physics and Medicinal Chemistry RAS, Chernogolovka, Moscow regionRussian Federation

Федеральное государственное учреждение науки Федеральный исследовательский центр проблем химической физики и медицинской химии Российской академии наук (ФГБУН ФИЦ ПХФ и МХ РАН), Черноголовка; Национальный исследовательский университет «Высшая школа экономики» (НИУ ВШЭ), МоскваРоссияFederal Research Center of Problems of Chemical Physics and Medicinal Chemistry RAS, Chernogolovka, Moscow region; National Research University – Higher School of Economics, MoscowRussian Federation

2023

08092023

234632

2023

LLC "KALVIS"

https://www.catalysis-kalvis.ru/jour/about/submissions#copyrightNotice

https://www.catalysis-kalvis.ru/jour/article/view/957

Представлен обзор, посвященный обобщению и сравнительному анализу литературных данных последних лет по исследованиям в области конверсии диоксида углерода в метанол, диметиловый эфир и углеводороды С2+, включая олефины, путем каталитического гидрирования. Показано, что основными путями достижения высокой активности и селективности таких процессов являются направленный дизайн катализаторов и подбор условий проведения процессов гидрирования, в том числе с использованием сверхкритического CO2 и альтернативных традиционным физико-химических методик активации CO2 (электрокатализ, фотокатализ).

The review is devoted to generalization and comparative analysis of recent literature data on the conversion of carbon dioxide to methanol, dimethyl ether and hydrocarbons С2+, including olefins, by catalytic hydrogenation. The main ways for achieving high activity and selectivity of such processes were shown to be the deliberate design of catalysts and the selection of conditions for hydrogenation processes, particularly with the use of supercritical CO2 and alternative physicochemical methods of CO2 activation (electrocatalysis and photocatalysis).

диоксид углеродагидрированиетермодинамикакатализаторысверхкритический СО2метанолдиметиловый эфируглеводороды С2+олефины

carbon dioxidehydrogenationthermodynamicscatalystssupercritical СО2methanoldimethyl etherhydrocarbons С2+olefins

References1

Porosoff M.D., Yan B., Chen J.G. // Energy & Environmental Science. 2016. V. 9. P. 62–73. https://doi.org/10.1039/C5EE02657A

International Energy Agency, Global Energy & CO 2 Status Report, Paris, 2019. URL: https://www.iea.org/reports/global-energy-co2-status-report-2019.

Ramirez A., Gevers L., Chowdhury A.D., Abou-Hamad E., Aguilar-Tapia A., Hazemann J-L., Wehbe N., Al Abdulghani A.J., Kozlov S.M., Luigi Cavallo L., Gascon J. // ChemCatChem. 2019. V. 11(12). P. 2879–2886. https://doi.org/10.1002/cctc.201900762

Sutter J.D., Berlinger J. Final draft of climate deal formally accepted in Paris. CNN. Cable News Network, Turner Broadcasting System, Inc. URL: https://www.academia.edu/36485719/Main_assignment_tunvir_sir_Cop21.

Crippa M., Guizzardi D., Muntean M., Schaaf E., Solazzo E., Monforti-Ferrario F., Olivier J.G.J., Vignati E. Fossil CO2 emissions of all world countries - 2020 Report, EUR 30358 EN, Publications Office of the European Union, Luxembourg, 2020, ISBN 978-92-76-21515-8. https://doi.org/10.2760/143674

Global CO2 emissions rose less than initially feared in 2022 as clean energy growth offset much of the impact of greater coal and oil use. IEA. 02 March 2023. URL: https://www.iea.org/news/global-co2-emissions-rose-less-than-initially-feared-in-2022-as-clean-energy-growth-offset-much-of-the-impact-of-greater-coal-and-oil-use

United Nations Framework Convention on Climate Change (UNFCCC). Adoption of the Paris Agreement. FCCC/CP/2015/L.9/Rev.1. 2015. URL: https://unfccc.int/sites/default/files/resource/docs/2015/cop21/eng/l09r01.pdf

North M., Styring P. // Faraday Discuss. 2015. V. 183. P. 489–502. https://doi.org/10.1039/C5FD900H

Ateka A., Rodriguez-Vega P., Erena J, Aguayo A.T, Bilbao J. // Fuel Processing Technology. 2022. V. 233. Article 107310. https://doi.org/10.1016/j.fuproc.2022.107310

Kamkeng A.D.N., Wang M., Hu J., Du W., Qian F. // Chem. Eng. J. 2021. V. 409. Article 128138. https://doi.org/10.1016/j.cej.2020.128138.

De S., Dokania A., Ramirez A., Gascon J. // ACS Catal. 2020. V. 10. P. 14147–14185. https://dx.doi.org/10.1021/acscatal.0c04273

Yaashikaa P.R., Kumar P.S., Varjani S.J., Saravanan A. // Journal of CO2 Utilization. 2019. V. 33. P. 131–147. https://doi.org/10.1016/j.jcou.2019.05.017

Chen G., Wang L. Godfroid T., Snyders R. // Plasma Chem. Gas Convers. IntechOpen. 2018. 86 p. ISBN 978-1-78984-841-0. https://doi.org/10.5772/intechopen.80798.

Jarvis S.M., Samsatli S. // Renewable and Sustainable Energy Reviews. 2018. V. 85. P. 46–68. https://doi.org/10.1016/j.rser.2018.01.007

Donphai W., Witoon T., Faungnawakij K., Chareonpanich M. // Journal of CO2 Utilization. 2016. V. 16. P. 245–256. https://doi.org/10.1016/j.jcou.2016.07.011

Yan N., Philippot K. // Curr. Opin. Chem. Eng. 2018. V. 20. P. 86–92. https://doi.org/10.1016/j.coche.2018.03.006

Advances in Science, Technology & Innovation. IEREK Interdisciplinary Series for Sustainable Development. Inamuddin, Rajender Boddula, Mohd Imran Ahamed, Anish Khan Editors. Springer Nature Switzerland AG. ISBN 978-3-030-72876-2. Carbon Dioxide Utilization to Sustainable Energy and Fuels. 2021. 354 p. https://doi.org/10.1007/978-3-030-72877-9

CO2 Hydrogenation Catalysis. Edited by Yuichiro Himeda. Wiley-VCH. 2021. 320 p. ISBN: 978-3-527-34663-9. URL: https://www.wiley.com/en-us/CO2+Hydrogenation+Catalysis-p-9783527824106

Wang M., Oko E. // Int. J. Coal Sci. Technol. 2017. V. 4. P. 1–4. https://doi.org/10.1007/s40789-017-0162-5

Peters M., Kçhler B., Kuckshinrichs W., Leitner W. // ChemSusChem. 2011. V. 4. P. 1216–1240. https://doi.org/10.1002/cssc.201000447

Salvi B.L., Jindal S. // SN Appl. Sci. 2019. V. 1. Article 885. https://doi.org/10.1007/s42452-019-0909-2

Rubin E.S., Mantripragada H., Marks A., Versteeg P., Kitchin J. // Prog. Energy Combust. Sci. 2012. V. 38. P. 630–671. https://doi.org/10.1016/j.pecs.2012.03.003

Al-Mamoori A., Krishnamurthy A., Rownaghi A.A., Rezaei F. // Energy Technol. 2017. V. 5. P. 834–849. https://doi.org/10.1002/ente.201600747

Horowitz C.A. Paris Agreement, Int. Leg. Mater. 2016. URL: https://doi.org/10.1017/s0020782900004253.

Fu H-C., You F, Li H-R., He L-N. // Front. Chem. 2019. V. 7. Article 525. https://doi.org/10.3389/fchem.2019.00525

Макарян И.А., Седов И.В., Максимов А.Л. // Журнал прикладной химии. 2020. Т. 93. № 12. С. 1716–1733. https://doi.org/10.31857/S0044461820120038. / Makaryan I.A., Sedov I.V., Maksimov A.L. // Russ J Appl Chem. 2020. V. 93. P. 1815–1830. https://doi.org/10.1134/S1070427220120034

Pearson R.J., Eisaman M.D., Turner J.W.G., Edwards P.P., Jiang Z., Kuznetsov V.L., Littau K.A., Di Marco L., Taylor S.R.G. // Proceedings of the IEEE. February 2012. Vol. 100, No. 2. P. 440 – 460. https://doi.org/10.1109/JPROC.2011.2168369

Недоливко В.В., Засыпалов Г.О., Вутолкина А.В., Гущин П.А., Винокуров В.А., Куликов Л.А., Егазарьянц С.В., Караханов Э.А., Максимов А.Л., Глотов А.П. // Журнал прикладной химии. 2020. Т. 93. № 6. C. 763–787. https://doi.org/10.31857/S0044461820060018

De Falco M., Iaquaniello G., Centi G. Editors. CO2: A Valuable Source of Carbon, Green Energy Tech. Springer-Verlag. London 2013. ISSN 1865-3529. https://doi.org/10.1007/978-1-4471-5119-7.

Kaiser P., Unde R.B., Kern C., Jess A. // Chem.Ing. Tech. 2013. V. 85. P. 489–499. https://doi.org/10.1002/cite.201200179.

Su X., Yang X., Zhao B., Huang Y. // Journal of Energy Chemistry. 2017. V. 26(5). P. 854–867. https://doi.org/10.1016/j.jechem.2017.07.006E.

Dzuryk R.S. // Chemical Engineering Research and Design. 2019. V. 144. P. 354–369. http://dx.doi.org/10.1016/j.jechem.2017.07.006.

Trusov B.G. // Proc. XIV Int. Symp. on Chemical Thermodynamics, St. Petersburg, Russia, 2002, P. 483–484.

Smith R.J., Muruganandam L, Murthy S.S. // International Journal of Chemical Reactor Engineering. 2010. V. 8(1). https://doi.org/10.2202/1542-6580.2238

Савченко В.И., Зимин Я.С., Бузило Э., Никитин А.В., И.В. Седов А.В., Арутюнов В.С. // Нефтехимия. (в печати).

Li Y.N., He L.N., Liu A.H., Lang X.D., Yang Z.Z., Yu B., Luan C-R. // Green Chem. 2013. V. 15. P. 2825–2829. https://doi.org/10.1039/C3GC41265B

Rezayee N.M., Huff C.A., Sanford M.S. // J. Am. Chem. Soc. 2015. V. 137. P. 1028–1031. https://doi.org/10.1021/ja511329m.

Kothandaraman J., Goeppert A., Czaun M., Olah G.A., Prakash G.K. // J. Am. Chem. Soc. 2016. V. 138. P. 778–781. https://doi.org/10.1021/jacs.5b12354

Kothandaraman J., Goeppert A., Czaun M., Olah G.A., Prakash G.K.S. // Green Chem. 2016. V. 18. P. 5831–5838. https://doi.org/10.1039/c6gc01165a

Su J., Lu M., Lin H.F. // Green Chem. 2015. V. 17. P. 2769–2773. https://doi.org/10.1039/c5gc00397k

Reller C., Pöge M., Lißner A., Mertens F.O.R.L. // Environ. Sci. Technol. 2014. V. 48 P. 14799–14804. https://doi.org/10.1021/es503914d

Bobadilla L.F., Riesco-García J.M., Penelás-Pérez G., Urakawa A. // J. CO2 Util. 2016. V. 14. P. 106–111. https://doi.org/10.1016/j.jcou.2016.04.003

Su X., Yang X.F., Huang Y., Liu B., Zhang T. // Acc. Chem. Res. 2019. V. 52(3). P. 656–664. https://doi.org/10.1021/acs.accounts.8b00478

Daza Y.A., Kuhn J.N. // SC Adv. 2016. V. 6. P. 49675–49691. https://doi.org/10.1039/c6ra05414e

Chen X., Su X., Su H.-Y., Liu X., Miao S., Zhao Y., Sun K., Huang Y., Zhang T. // ACS Catal. 2017 V. 7(7). P. 4613–4620. https://doi.org/10.1021/acscatal.7b00903

Aziz M.A.A., Jalil A.A., Triwahyono S., Ahmad A. // Green Chem. 2015, V. 17(5). P. 2647–2663. https://doi.org/10.1039/C5GC0011F

Wang Y., Winter L.R., Chen J.G., Yan B. // Green Chem. 2021. V. 23. P. 249–267. https://doi.org/10.1039/D0GC03506H

Kattel S., Liu P., Chen J.G. // J. Am. Chem. Soc. 2017. V. 139. P. 9739–9754. https://doi.org/10.1021/jacs.7b05362

Li Y.N., He L.N., Lang X.D., Liu X.F., Zhang S. // RSC Adv. 2014. V. 4. P. 49995–50002. https://doi.org/10.1039/c4ra08740b.

Li W., Wang H., Jiang X., Zhu J., Liu Z., Guo X.,

Song C. // RSC Adv. 2018. V. 8. P. 7651–7669. https://doi.org/10.1039/c7ra13546g

Sharma P., Sebastian J., Ghosh S., Creaser D., Olsson L. // Catal. Sci. Technol. 2021. V. 11. P. 1665–1697. https://doi.org/10.1039/d0cy01913e

Rafiee A., Khalilpour K.R., Milani D., Panahi M. // J. Environ. Chem. Eng. 2018. V. 6. P. 5771–5794, https://doi.org/10.1016/j.jece.2018.08.065.

Shoinkhorova T., Cordero-Lanzac T., Ramirez A., Chung S.H., Dokania A., Ruiz- Martinez J., Gascon J. // ACS Catal. 2021. V. 11. P. 3602–3613. https://doi.org/ 10.1021/acscatal.0c05133.

Perez-Uriarte P., Ateka A., Gamero M., Aguayo A.T., Bilbao J. // Ind. Eng. Chem. Res. 2016. V. 55. P. 6569–6578. https://doi.org/ 10.1021/acs.iecr.6b00627.

Fan W.K., Tahir M. // Journal of Environmental Chemical Engineering. 2021. V. 9(4). Article 105460. https://doi.org/10.1016/j.jece.2021.105460

Galadima A., Muraza O. // Renewable and Sustainable Energy Reviews. 2019. V. 115(11). Article 109333. https://doi.org/10.1016/j.rser.2019.109333

Tahir M., Tahir B. // Chem. Eng. J. 2020. V. 400. Article 125868. https://doi.org/10.1016/j.cej.2020.125868

Azzolina-Jury F. // J. Ind. Eng. Chem. 2019. V. 71. P. 410–424. https://doi.org/10.1016/j.jiec.2018.11.053

Manthiram K., Beberwyck B.J., Alivisatos A.P. // J. Am. Chem. Soc. 2014. V. 136. P. 13319–13325. https://doi.org/10.1021/ja5065284

Alitalo A., Niskanen M., Aura E. // Bioresour. Technol. 2015. V. 196. P.

–605. https://doi.org/10.1016/j.biortech.2015.08.021.

Ryu U.J., Kim S.J., Lim H.-K., Kim H., Choi K.M., Kang J.K. // Sci. Rep. 2017. V. 7(1). Article 612. https://doi.org/10.1038/s41598-017-00574-1

Vogt C., Monai M., Kramer G.J., Weckhuysen B.M. // Nat. Catal. 2019. V. 2. P. 188–197. https://doi.org/10.1038/s41929-019-0244-4

Audi e-gas Project, Germany. Market Data. 2021. URL: https://www.power-technology.com/marketdata/audi-e-gas-project-germany/

Swickrath M.J, Anderson M. The Development of Models for Carbon Dioxide Reduction Technologies for Spacecraft Air Revitalization. 42nd International Conference on Environmental Systems, 15-19 July 2012, San Diego, California. AIAA 2012-3586. 2012. 19 р. https://doi.org/10.2514/6.2012-3586

Макарян И.А., Рудакова М.И., Савченко В.И., Арутюнов В.С. // Мир нефтепродуктов. Вестник нефтяных компаний. 2011. № 10. С. 3–9.

Макарян И.А., Рудакова М.И., Савченко В.И. // Мир нефтепродуктов. Вестник нефтяных компаний. 2011. № 11. С. 3–9.

Olah G.A., Goeppert A., Prakash G.K.S. Beyond Oil and Gas: The Methanol Economy, 2nd ed. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2009, ISBN: 98-3-527-32422-4.

Zhong J., Yang X., Wu Z., Linag B., Huang Y., Zhang T. // Chem. Soc. Rev. 2020. V. 4(5). P. 1385−1413. https://doi.org/10.1039/c9cs00614a

Dang S.S., Yang H.Y., Gao P., Wang H., Li X.P., Wei W., Sun Y.H. // Catal. Today. 2019. V. 330. P. 61−75. https://doi.org/10.1016/j.cattod.2018.04.021

Ye R.P., Ding J., Gong W., Argyle M.D., Zhong Q., Wang Y., Russell C.K., Xu Z., Russell A.G., Li Q., Fan M., Yao Y.G. // Nat. Commun. 2019. V. 10. P. 1–15. https://doi.org/10.1038/s41467-019-13638-9.

Din I.U., Shaharun M.S., Alotaibi M.A., Alharthi A.I., Naeem A. // J. CO2 Util. 2019. V. 34. P. 20−33. https://doi.org/10.1016/j.jcou.2019.05.036

Guil-Lopez R., Mota N., Llorente J., Millan E., Pawelec B., Fierro J.L.G., Navarro R.M. // Materials 2019. V. 12(23). Article 3902. https://doi.org/10.3390/ma12233902.

Hus M., Kopac D., Stefancic N.S., Jurkovic D.L., Dasireddy V.D.B.C., Likozar B. // Catal. Sci. Technol. 2017. V. 7. P. 5900–5913. https://doi.org/10.1039/c7cy01659j

Kopac D., Likozar B., Hus M. // Appl. Surf. Sci. 2019. V. 497. Article 143783. https://doi.org/10.1016/j.apsusc.2019.143783

Ojelade O.A., Zaman S.F. // Catal. Surv. Asia 2020. V. 24. P. 11–37. https://doi.org/10.1007/s10563-019-09287-z.

Martin O., Martín A.J., Mondelli C., Mitchell S., Segawa T.F., Hauert R., Drouilly C., Curulla-Ferre D., Perez-Ramírez J. // Angew. Chemie Int. Ed. 2016. V. 55, P. 6261–6265. https://doi.org/10.1002/anie.201600943.

Jiang Z., Xiao T., Kuznetsov V.L., Edwards P.P. // Phil. Trans. Roy. Soc. A, 2010. V. 368. P. 3343–3364. https://doi.org/10.1098/rsta.2010.0119

Balzarotti R., Ambrosetti M., Beretta A., Groppi G., Tronconi E. // Chem. Eng. J. 2020. V. 391. P. 123394–123405. https://doi.org/10.1016/j.cej.2019.123494

Kapteijn F., Moulijn J.A. // Catal. 2022. V. 383. P. 5–14. https://doi.org/10.1016/j.cattod.2020.09.026.

Gancarczyk A., Sindera K., Iwaniszyn M., Piątek M., Macek W. Jodłowski P.J., Wroński S., Sitarz M., Łojewska J., Kołodziej A. // Catalysts. 2019. V. 9(7). P. 587–599. https://doi.org/10.3390/catal9070587.

Rui N., Wang Z., Sun K., Ye J., Ge, Liu C. // Appl. Catal. B Environ. 2017. V. 218. P. 488–497. https://doi.org/10.1016/j.apcatb.2017.06.069

Rodriguez J.A., Liu P., Stacchiola D.J., Senanayake S., White M.G., Chen J.G. Hydrogenation of CO2 to Methanol: Importance of Metal-Oxide and

Metal-Carbide Interfaces in the Activation of CO2. Chemistry Department,

Brookhaven. National Laboratory, Upton, NY 11973, USA. BNL-108509-2015-JA. URL: https://www.bnl.gov/isd/documents/89413.pdf

Chakrabortty S., Nayak J., Ruj B., Pal P., Kumar R., Banerjee S., Sardar M., Chakraborty P. // Journal of Environmental Chemical Engineering. 2020. V. 8(4). Article 103935. https://doi.org/10.1016/j.jece.2020.103935

Bellotti D., Dierks M., Moellenbruck F., Magistri L., Görner K., Oeljeklaus G. // E3S Web of Conferences. 2019. V. 113. Article 01013. https://doi.org/10.1051/e3sconf/201911301013

Etim U.J., Song Y., Zhong Z. // Front. Energy Res., V. 8. Article 545431 https://doi.org/10.3389/fenrg.2020.545431

Zohour B., Yilgor I., Gulgun M.A., Birer O., Unal U., Leidholm C., Senkan S. // ChemCatChem. 2016. V. 8. P. 1464–1469. https://doi.org/10.1002/cctc.201600020

Fiordaliso E.M., Sharafutdinov I., Carvalho H.W.P., Grunwaldt J.D., Hansen T.W., Chorkendorff I., Wagner J.B., Damsgaard C.D. // ACS Catalysis. 2015. V. 5(10). P. 5827–5836. https://doi.org/10.1021/acscatal.5b01271

Studt F., Sharafutdinov I., Abild-Pedersen F., Elkjær C.F., Hummelshøj J.S., Dahl S., Chorkendorff I., Nørskov J.K. // Nature Chemistry. 2014. V. 6. P. 320–324. https://doi.org/10.1038/nchem.1873

Pavlisic A., Hus M., Prasnikar A., Likozar B. // J. Clean. Prod. 2020. V. 275. Article 122958. https://doi.org/10.1016/j.jclepro.2020.122958

Li S, Guo L, Ishihara T. // Catal. Today. 2020. V. 339. P. 352–361. https://doi.org/10.1016/j.cattod.2019.01.015

US Patent 8198338B2, 2012.

Hindman M. Methanol to gasoline (MTG) technology – An alternative for liquid fuel production, presented at the Gasification Technol. Conf., Colorado Springs, CO, Oct. 4–7, 2009. ISBN: 9781634390828. https://www.proceedings.com/23225.html

Bandi A., Specht M. Renewable carbon-based transportation fuels. In Landolt-Bornstein, vol. III/3C, Energy Technologies, Subvolume C: Renewable Energy. Berlin, Germany: Springer-Verlag. 2006. P. 441–482. ISBN: 978-3-540-42962-3.

Zhang H., Desideri U. // Energy. 2020. V. 199. Article 117498. https://doi.org/10.1016/j.energy.2020.117498 .

Dimethyl Ether Market Size, Share & COVID-19 Impact Analysis, By Application (LPG Blending, Aerosol Propellant, Transportation Fuel, and Others), and Regional Forecast, 2021-2028. URL: https://www.fortunebusinessinsights.com/

100

Дементьев К.И., Дементьева О.С., Иванцов М.И., Куликова М.В., Магомедова М.В., Максимов А.Л., Лядов А.С., Старожицкая А.В., Чудакова М.В. // Нефтехимия. 2022. Т. 62. № 3. С. 289–327. https://doi.org/10.31857/S0028242122030017

101

Ham H., Baek S.W., Shin C.-H., Bae J.W. // ACS Catal. 2018. V. 9. P. 679–690. https://doi.org/10.1021/acscatal.8b04060

102

Nie X., Jiang X., Wang H., Luo W., Janik M.J., Chen Y., Guom X., Song C. //ACS Catal. 2018. V. 8. P. 4873–4892. https://doi.org/10.1021/acscatal.7b04150

103

Saravanan K., Ham H., Tsubaki N., Bae J.W. // Appl. Catal. B Environ. 2017. V. 217. P. 494–522. https://doi.org/10.1016/j.apcatb.2017.05.085

104

Phienluphon R., Pinkaew K., Yang G., Li J., Wei Q., Yoneyama Y., Vitidsant T., Tsubaki N. // Chem. Eng. J. 2015. V. 270. P. 605–611. https://doi.org/10.1016/j.cej.2015.02.071

105

Sánchez-Contador M., Ateka A., Aguayo A.T., Bilbao J. // Fuel Processing Technology. 2018. V. 179. P. 258–268. https://doi.org/10.1016/j.fuproc.2018.07.009

106

Koohsaryan E., Anbia M. // Chinese Journal of Catalysis. 2016. V. 37(4). P. 447–467. https://doi.org/10.1016/S1872‐2067(15)61038‐5

107

Formic acid market - Growth, trends, covid-19 impact, and forecasts (2022–2027). URL: https:://www.mordorinitelligence.com/industry-reports/formic-acid-market

108

Onishi N., Kanega R., Kawanami H.. Himeda Y. // Molecules. 2022. V. 27. Article 455. https://doi.org/10.3390/molecules27020455

109

Sordakis K., Tang C., Vogt L.K., Junge H., Dyson P.J., Belle M., Laurenczy G. // Chem. Rev. 2018. V. 118(2). P. 372–433. https://doi.org/10.1021/acs.chemrev.7b00182

110

Sun R., Liao Y., Bai S-T., Zheng M., Zhou C., Zhang T., Sels B.F. // Energy Environ. Sci. 2021. V. 14 (3). P. 1247–1285. https://doi.org/10.1033/DoEE03575K

111

Roy S., Cherevotan A., Peter S.C. // ACS Energy Lett. 2018. V. 3. P. 1938–1966. https://doi.org/10.1021/acsenergylett.8b00740.

112

Wang W., Wang S., Ma X., Gong J. // Chem. Soc. Rev. 2011. V. 40. P. 3703–3727. https://doi.org/10.1039/C1CS15008A

113

Prieto G. // ChemSusChem 2017. V. 10. P. 1056–1070. https://doi.org/10.1002/cssc.201601591.

114

Yang H., Zhang C., Gao P., Wang H., Li X., Zhong L., Wei W., Sun Y. // Catalysis Science & Technology. 2017. V. 7(20). P. 4580–4598. https://doi.org/10.1039/C7CY01403A

115

Hwang S.M., Han S.J., Min J.E., Park H.G., Jun K.W., Kim S.K. // J. of CO2 Utilization. 2019. V. 34. P. 522–532. https://doi.org/10.1016/J.JCOU.2019.08.004.

116

Guo L., Cui Y., Zhang P., Peng X., Yoneyama Y., Yang G., Tsubaki N. // Chemistry-Select. 2018. V. 3(48). P. 13705–13711. https://doi.org/10.1002/SLCT.201803335.

117

Yao B., Ma W., Gonzalez-cortes S., Xiao T., Edwards, P.P. // Green-house Gases: Science and Technology. 2017. V. 15. P. 1–15. https://doi.org/10.1002/ghg.1694

118

Mikulcic H., Ridjan S.I., Dominkovic D.F., Wan Alwi S.R., Manan Z.A., Tan R., Duic N., Hidayah M.S.N., Wang X. // Renew. Sustain. Energy Rev. 2019. V. 114. Article 109338. https://doi.org/10.1016/j.rser.2019.109338

119

Saeidi S., Najari S., Hessel V., Wilson K., Keil F.J., Concepcion P., Suib S.L., Rodrigues A.E. // Prog. Energy Combust. Sci. 2021. V. 85. Article 100905. https://doi.org/10.1016/j.pecs.2021.100905.

120

Modak A., Bhanja P., Dutta S., Chowdhury B., Bhaumik A. // Green Chem. 2020. V. 22. P. 4002–4033, https://doi.org/10.1039/D0GC01092H.

121

Li J., Wang L., Cao Y., Zhang C., He P., Li H. // Chinese Journal of Chemical Engineering 2018. V. 26. P. 2266–2279. https://doi.org/10.1016/J.CJCHE.2018.07.008.

122

Khangale P.R. // Catal Lett. 2022. V. 152(3). P. 2745–2755. https://doi.org/10.1007/s10562-021-03849-5

123

Gao P., Zhang L., Li S., Zhou Z., Sun Y. // ACS Cent. Sci. 2020. V. 6(10). P. 1657–1670. https://doi.org/10.1021/acscentsci.0c00976

124

Wang W., Wang X., Zhang G., Wang K., Zhang F., Yan T., Miller J.T., Guo X., Song C. // Front. Chem. Eng. 2021. V. 3. Article 708014. https://doi.org/10.3389/fceng.2021.708014

125

Kim J.-S., Lee S.-B., Kang M.-C., Lee K.-W., Choi M.-J., Yong Kang Y. // Korean J. Chem. Eng. 2003. V. 20(5). P. 967–972. https://doi.org/10.1007/BF02697307

126

Gao P., Li S., Bu X., Dang S., Liu Z., Wang H., Zhong L., Qiu M., Yang C., Cai J., Wei W., Sun Y. // Nat Chem. 2017. V. 9(10). P. 1019–1024. https://doi.org/10.1038/nchem.2794.

127

Wei J., Ge Q., Yao R., Wen Z., Fang C., Guo L., Xu H., Sun J. // Nat. Commun. 2017. V. 8. P. 15174–15181. https://doi.org/10.1038/ncomms15174

128

Fujiwara M., Sakurai H., Shiokawa K., Iizuka Y. // Catalysis Today. 2015. V. 242. Part B. P. 255–260. https://doi.org/10.1016/j.cattod.2014.04.032

129

Owen R.E., O’ByrneJ.P., Mattia D., Plucinski P., Pascu S.I., Jones M.D. // Chemical Communications. 2013. V. 49. P. 11683–11685. https://doi.org/10.1039/C3CC46791K

130

Owen R.E., Plucinski P., Mattia D., Torrente-Murciano, L., Ting V.P., Jones M.D. // Journal of CO2 Utilization. 2016. V. 16. P. 97–103. https://doi.org/10.1016/j.jcou.2016.06.009

131

Owen R.E., Mattia D., Plucinski P., Jones M.D. // ChemPhysChem. 2017. V. 18. P. 3211–3218. https://doi.org/10.1002/cphc.201700422

132

Rodemerck U., Holeňa M., Wagner E., Smejkal Q., Barkschat A., Baerns M. // ChemCatChem. 2013. V. 5(7). P. 1948¬–1955. https://doi.org/10.1002/cctc.201200879.

133

Calizzi M., Mutschler R., Patelli N., Migliori A., Zhao K., Pasquini L., Züttel A. // Nanomaterials. 2020. V. 10. Article 1360. https://doi.org/10.3390/nano10071360.

134

Esquius J.R., Bahruji H., Bowker M., Hutchings G.J. // Faraday Discuss. 2021. V. 230. P. 52–67. https//doi.org/10.1039/d0fd00135j.

135

Choi Y.H., Jang Y.J., Park H., Kim W.Y., Lee Y.H., Choi S.H., Lee J.S. // Appl. Catal. B. 2017. V. 202. P. 605–610. https://doi.org/10.1016/j.apcatb.2016.09.072.

136

Qian Q., hang J., Cui M., Han B. // Nat. Commun. 2016. V. 7. Article 11481. https://doi.org/10.1038/ncomms11481

137

He Z., Cui M., Qingli Qian Q., Zhang J., Liu H., Han B. // PNAS Nexus. 2019. V. 116 (26). P. 12654–12659. https://doi.org/10.1073/pnas.1821231116

138

Wang Q., Chen Y., Li Z. // J. Nanosci. Nanotechnol. 2019. V. 19. P. 3162–3172. https://doi.org/10.1166/jnn.2019.16586.

139

Ma Z., Porosoff M.D. // ACS Catal. 2019. V. 9. P. 2639–2656. https://doi.org/10.1021/acscatal.8b05060

140

Ronda-Lloret M., Rothenberg G., Shiju N.R. // ChemSusChem 2019. V. 12. P. 3896–3914. https://doi.org/10.1002/cssc.201900915

141

Li Z., Wang J., Qu Y., Liu H., Tang C., Miao S., Feng Z., An H., Li C. // ACS Catal. 2017. V. 7. P. 8544–8548. https://doi.org/10.1021/acscatal.7b03251

142

Witoon T., Chaipraditgul N., Numpilai T., Lapkeatsere V., Ayodele B.V., Cheng C.K., Siri-Nguan N., Sornchamni T., Limtrakul J. // Chem. Eng. Sci. 2021. V. 233. Article 116428. https://doi.org/10.1021/acscatal.7b03251

143

Ojelade O.A., Zaman S.F. // Journal of CO2 Utilization. 2021. V. 47. Article 101506. https://doi.org/10.1016/j.jcou.2021.101506

144

Wang X., Zhang J., Chen J., Ma Q., Fan S., Zhao T. // Chinese J. of Chemical Engineering. 2018. V. 26(4). P. 761–767. https://doi.org/10.1016/J.CJCHE.2017.10.013

145

Jiang F., Liu B., Geng S., Xu Y., Liu X. // Catalysis Science & Technology. 2018. V. 8(16). P. 4097–4107. https://doi.org/10.1039/C8CY00850G

146

Wang S., Zhang L., Zhang W., Wang P., Qin Z., Yan W., Dong M., Li J., Wang J., He L., Olsbye U., Fan W. // Chem. 2020. V. 6(12). P. 3344–3363. https://doi.org/10.1016/J.CHEMPR.2020.09.025

147

Guo L., Cui Y., Li H., Fang Y., Prasert R., Wu J., Yang G., Yoneyama Y., Tsubaki N. // Catalysis Communications. 2019. V. 130. Article 105759. P. https://doi.org/10.1016/J.CATCOM.2019.105759

148

Dang S., Gao P., Liu Z., Chen X., Yang C., Wang H., Zhong L., Li S., Sun Y. // J. of Catalysis. 2018. V. 364. P. 382–393. https://doi.org/10.1016/J.JCAT.2018.06.010

149

Kangvansura P., Chew L.M., Saengsui W., Santawaja P., Pooarporn Y., Muhler M., Schulz H., Worayingyong A. // Catalysis Today. 2016. V. 275. P. 59–65. https://doi.org/10.1016/J.CATTOD.2016.02.045

150

Исмагилов З.Р., Пармон В.Н. // Энергетический вестник, МЦУЭР Международный центр устойчивого развития под эгидой ЮНЕСКО. 2021. С. 54–74.

151

European Patent EP1373166, 2004.

152

Алексеев Е.С., Алентьев А.Ю., Белова А.С., Богдан В.И., Богдан Т.В., Быстрова А.В., Гафарова Э.Р., Голубева Е.Н., Гребенник Е.А., Громов О.И., Даванков В.А., Злотин С.Г., Киселев М.Г., Коклин А.Е., Кононевич Ю.Н., Лажко А.Э., Лунин В.В., Любимов С.Е., Мартьянов О.Н., Мишанин И.И., Музафаров А.М., Нестеров Н.С., Николаев А.Ю., Опарин Р.Д., Паренаго О.О., Паренаго О.Р., Покусаева Я.А., Ронова И.А., Соловьева А.Б., Темников М.Н., Тимашев П.С., Турова О.В., Филатова Е.В., Филиппов А.А., Чибиряев А.М., Шалыгин А.С. // Успехи химии. 2020. Т. 89. № 12. С. 1337–1427. https://doi.org/10.1070/RCR4932. /[Alekseev E.S., Alentiev A.Yu., Belova A.S., Bogdan V.I., Bogdan T.V., Bystrova A.V., Gafarova E.R., Golubeva E.N., Grebenik E.A., Gromov O.I., Davankov V.A., Zlotin S.G., Kiselev M.G., Koklin A.E., Kononevich Yu.N., Lazhko A.E., Lunin V.V., Lyubimov S.E., Martyanov O.N., Mishanin I.I., Muzafarov A.M., Nesterov N.S., Nikolaev A.Yu., Oparin R.D., Parenago O.O., Parenago O.P., Pokusaeva Ya.A., Ronova I.A, Solovieva A.B., Temnikov M.N., Timashev P.S., Turova O.V., Filatova E.V., Philippov A.A., Chibiryaev A.M., Shalygin A.S. Supercritical fluids in chemistry // RUSS CHEM REV. 2020. V. 89(12). P. 1337–1427. https://doi.org/10.1070/RCR4932

153

Jessop P., Ikariya T., Noyori R. // Nature. 1994. V. 368. P. 231–233. https://doi.org/10.1038/368231a0

154

Jessop P.G., Hsiao Y., Ikariya T., Noyori R. // J. Am. Chem. Soc. 1996. V. 118(2). P. 344–355. https://doi.org/10.1021/ja953097b

155

Preti D., Resta C., Squarcialupi S., Fachinetti G. // Angew. Chem. 2011. V. 123. P. 12759–12762. https://doi.org/10.1002/anie.201105481https://doi.org/10.1002/anie.201105481

156

Патент WO 2010149507, 2010.

157

Zhang Z., Hu S., Song J., Li W., Yang G., Han B. Hydrogenation of CO2 to Formic Acid Promoted by a Diamine-Functionalized Ionic Liquid // ChemSusChem. 2009. V. 2. P. 234 – 238. https://doi.org/10.1002/cssc.200800252

158

Andrushkevich T.V., Popova G.Y., Danilevich E.V. Zolotarskii I.A., Nakrokhin V.B., Nikoro T.A., Stompel S.I., Parmon V.N. // Catal. Ind. 2014. V. 6. P. 17–24. https://doi.org/10.1134/S2070050414010024

159

Wesselbaum S., Hintermair U., Leitner W. // Chem. Int. Ed. 2012. V. 51(34). P. 8585–8588. https://doi.org/10.1002/anie.201203185

160

Span R., Wagner W. // J. Phys. Chem. Ref. Data. 1996. V. 25. P. 1509–1596, https://doi.org/10.1063/1.555991.

161

Evdokimenko N.D., Kustov A.L., Kim K.O., Igonina M.S., Kustov L.M. // Mendeleev Commun. 2018. V. 28. P. 147–149. https://doi.org/10.1016/j.mencom.2018.03.012.

162

Gothe M.L., Pérez-Sanz F.J., Braga A.H., Borges L.R., Abreu T.F., Bazito R.C., Gonçalves R.V., Rossi L.M., Vidinha P. // Journal of CO2 Utilization. 2020. V. 40. Article 101195. https://doi.org/10.1016/j.jcou.2020.101195.

163

Покусаева Я.А. Гидрирование диоксида углерода на Fe-, Co- и Ni-содержащих катализаторах в газовой фазе и в сверхкритических условиях. Дис. … канд. хим. наук. На правах рукописи. М. 2020. 128 с.

164

Bogdan V.I., Pokusaeva Y.A., Koklin A.E., Savilov S.V., Chernyak S.A., Lunin V.V., L.M. Kustov V.V. // Energy Technol. 2019. V. 7. Article 1900174. https://doi.org/10.1002/ente.201900174

165

Chernyak S.A., Ivanov A.S., Stolbov D.N., Maksimov S.V., Maslakov K.I., Chernavskii P.A., Pokusaeva Y.A., Koklin A.E., Bogdan V.I., Savilov S.V. // Carbon. 2020. V. 168. P. 475–484. https://doi.org/10.1016/J.CARBON.2020.06.067

166

Tamaki Y., Ishitani O. // ACS Catal. 2017. V. 7. P. 3394–3409. https://doi.org/10.1021/acscatal.7b00440.

167

Kuramochi Y., Ishitani O., Ishida H. // Coord. Chem. Rev. 2018. V. 373. P. 333–356. https://doi.org/10.1016/j.ccr.2017.11.023

168

Sekizawa K., Maeda K., Domen K., Koike K., Ishitani O. // J. Am. Chem. Soc. 2013. V. 135. P. 4596–4599. https://doi.org/10.1021/ja311541a

169

Kuramochi Y., Ishitani O. // Frontiers in Chemistry. 2019. V.7. Article 259. https://doi.org/10.3389/fchem.2019.00259

170

Yamazaki Y., Onoda T., Ishikawa J., Furukawa S., Tanaka C., Utsugi T., Tsubomura T. // Frontiers in Chemistry. 2019. V. 7. Article 288. https://doi.org/10.3389/fchem.2019.00288

171

Fan W.K., Tahir M. // Chemical Engineering Journal. 2022. V. 427. Article 131617. https://doi.org/10.1016/j.cej.2021.131617

172

Laura Rotundo, Emanuele Azzi, Annamaria Deagostino, Claudio Garino, Luca Nencini, Emanuele Priola, Pierluigi Quagliotto, Riccardo Rocca, Roberto Gobetto, Nervi C. // Frontiers in Chemistry. 2019. V. 7. Article 417. P. 64–76. https://doi.org/10.3389/fchem.2019.00417

173

Fu H.-C., You F., Li H.-R., He L.-N. // Frontiers in Chemistry. 2019. V. 7. Article 525. https://doi.org/10.3389/fchem.2019.00525

174

Talukdar K., Issa A., Jurss J.W. // Frontiers in Chemistry. 2019. V. 7. Article 330. https://doi.org/10.3389/fchem.2019.00330

175

Igarashi R., Takeuchi R., Kubo K., Mizuta T., Kume S. // Frontiers in Chemistry. 2019. V. 7. Article 860. https://doi.org/10.3389/fchem.2019.00860.

176

Liu M., Yi Y., Wang L, Guo H., Bogaerts A. // Catalysts. 2019. V. 9. Article 275. https://doi.org/10.3390/catal9030275

177

Snoeckx R, Bogaerts A. // Chemical Society Reviews. 2017. V. 46. P. 5805–5863. https://doi.org/10.1039/C6CS00066E

The authors declare that there are no conflicts of interest present.