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Нестационарные циклические технологии разложения сероводорода на водород и серу
https://doi.org/10.18412/1816-0387-2025-1-34-49
Аннотация
Сероводород является весьма привлекательным сырьем для производства водорода. Энергия диссоциации H2S (21 кДж/моль при комнатной температуре) намного ниже, чем у воды (286 кДж/моль) или даже углеводородов (76 кДж/моль для метана); более того, энергия связи водорода в молекуле H2S имеет наименьшее значение среди всех природных соединений водорода. Тем не менее, сероводород на сегодняшний день так и не нашел широкого промышленного применения в качестве сырья для производства водорода. Главным препятствием на пути создания эффективной технологии для этой цели являются весьма жесткие термодинамические ограничения реакции разложения сероводорода на элементы: H2S ↔ S + Н2 – Q. Настоящий обзор посвящен анализу известных подходов к получению водорода и серы из сероводорода, их недостатков, обуславливающих неуспех предложенных ранее технологий, а также пути возможного создания эффективных процессов для этой цели. В обзоре сделан особый фокус на нестационарных циклических процессах, которые можно считать одним из наиболее перспективных путей для создания эффективной технологии разложения H2S.
Об авторах
А. Н. Загоруйко
Институт катализа СО РАН, Новосибирск
Россия
Россия
Д. О. Кондрашев
Уфимский государственный нефтяной технический университет, Уфа
Россия
Россия
М. В. Попов
Российский химико-технологический университет, Москва
Россия
Россия
А. В. Клейменов
ПАО «Газпром нефть», Санкт-Петербург
Россия
Россия
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Рецензия
Для цитирования:
Загоруйко А.Н., Кондрашев Д.О., Попов М.В., Клейменов А.В. Нестационарные циклические технологии разложения сероводорода на водород и серу. Катализ в промышленности. 2025;25(1):34-49. https://doi.org/10.18412/1816-0387-2025-1-34-49
For citation:
Zagoruiko A.N., Kondrashev D.O., Popov M.V., Kleymenov A.V. Existing and Promising Technologies for Hydrogen Sulfide Decomposition into Hydrogen and Sulfur. Kataliz v promyshlennosti. 2025;25(1):34-49. (In Russ.) https://doi.org/10.18412/1816-0387-2025-1-34-49
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