Fully deuterated hydrocarbons production
https://doi.org/10.18412/1816-0387-2010-3-
Abstract
The possibility of obtaining a new material (a fully deuterated hydrocarbon by Fischer-Tropsch synthesis) is the first step to create the pilot unit. The isotope effect is absent, i.e. the main characteristics of synthesis and the resulting products are determined by the properties of the catalyst and process conditions, regardless of what is used in the original mixture – hydrogen or deuterium. Removing of wax from the catalyst surface occurs in mild conditions and requires no additional equipment or moving of the catalyst in another reactor. The selected catalyst has high stability and can be applied in a pilot unit for a fully deuterated wax. Evaluation of properties of new materials showed the prospects for their application as solvents for NMR, radioactive labels, targets, inhibitors of neutron fluxes, etc.
About the Authors
L. V. SinevaRussian Federation
E. A. Kozyukov
Russian Federation
V. S. Ermolaev
Russian Federation
I. G. Solomonik
Russian Federation
A. Yu. Krylova
Russian Federation
V. Z. Mordkovich
Russian Federation
References
1. Левин В. Е. Ядерная физика и ядерные реакторы. М.: Атомиздат, 1979.
2. Robertson B.C. Modern Physics for Applied Science. New York: J. Wiley, 1983.
3. Elliger C.A. // Journal of Labelled Compounds and Radiopharmaceuticals. 1983. Vol. 20, Issue 1. P. 135–141.
4. Пат. 2279912 (РФ). Кобальтовые катализаторы на основе смешанных оксидов кобальта и алюминия для синтеза Фишера–Тропша / А.Ю.Крылова, Я.В.Михайлова, С.А.Свидерский. 2006.
5. Крылова А.Ю., Синева Л.В., Тараканов Д.А. // Катализ в промышленности. 2006. № 3. С. 18–25.
6. Jongsomjit B., Panpranot J., Goodwin J.G. // J. Catal. 2001. Vol. 204. P. 98.
7. Berge P.J. van, Loosdrecht J. van der, Barradas S., Kraan A.M. van der. // Catal. Today. Vol. 58. P. 321.
8. Chemierohstoffe aus Kohle / Herausgegeben von Ju. Falbe. Stutgart: Georg Thieme Verlag, 1977.
9. Лапидус А.Л., Крылова А.Ю., Синева Л.В., Хухрик А.В. // Химия твердого топлива. 1999. № 4. С. 58–63.
10. Сторч Г., Голамбик Н., Андерсон Р. // Синтез углеводородов из окиси углерода и водорода. М.: ИЛ, 1954. С. 129.
11. Fischer–Tropsch Technology. Studies in Surface Science and Catalysis. Ed. By Dry M., Steynberg A. Amsterdam: Elsiver, 2004.
Review
For citations:
Sineva L.V., Kozyukov E.A., Ermolaev V.S., Solomonik I.G., Krylova A.Yu., Mordkovich V.Z. Fully deuterated hydrocarbons production. Kataliz v promyshlennosti. 2010;(3). (In Russ.) https://doi.org/10.18412/1816-0387-2010-3-