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CH4 conversion to С2-С3 hydrocarbons over Pt/MgAlOх catalysts in a cyclic mode
https://doi.org/10.18412/1816-0387-2025-2-68-78
Abstract
A dynamics of the reaction of non-oxidative methane coupling at 6000C catalyzed by 1%Pt/MgAlOх and 1%Pt/g-Al2O3 with close size of platinum clusters has been studied. In contrast to reference 1%Pt/g-Al2O3 sample, carbonaceous strongly adsorbed compounds accumulated during reaction running can be burnt out completely in 1%Pt/MgAlOх catalysts at the same temperature, which restored their catalytic activity. A possibility to increase the duration of their operation with maximal C2-C3 products yield under cyclic mode and minimal CO and CO2 formation during regeneration has been shown.
About the Authors
L. G. Pinaeva
Boreskov Institute of Catalysis, Novosibirsk
Russian Federation
Russian Federation
O. B. Belskaya
Center of New Chemical Technologies BIC, Boreskov Institute of Catalysis, Omsk
Russian Federation
Russian Federation
I. P. Prosvirin
Boreskov Institute of Catalysis, Novosibirsk
Russian Federation
Russian Federation
V. A. Likholobov
Boreskov Institute of Catalysis, Novosibirsk
Russian Federation
Russian Federation
A. S. Noskov
Boreskov Institute of Catalysis, Novosibirsk
Russian Federation
Russian Federation
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Review
For citations:
Pinaeva L.G., Belskaya O.B., Prosvirin I.P., Likholobov V.A., Noskov A.S. CH4 conversion to С2-С3 hydrocarbons over Pt/MgAlOх catalysts in a cyclic mode. Kataliz v promyshlennosti. 2025;25(2):68-78. (In Russ.) https://doi.org/10.18412/1816-0387-2025-2-68-78
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