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Ni-Based Catalysts on Ternary LaCeY Oxide Supports for Dry Reforming of Methane
https://doi.org/10.18412/1816-0387-2025-3-37-50
Abstract
Supported 10%Ni/LaCeY(n)Ox catalyst with different Y content (n = 0.5–10.0 mol.%) are studied in the present work. Ternary oxide supports are synthesized using citrate method. Structure and phase composition of supports and catalysts are characterized by different physical-chemical methods. Formation of active surface depending on yttrium introduction route is studied. Variation of yttrium content allows determining the optimal dopant content (0.5–1.0 mol.% Y) that sustains activity and stability of catalysts in DRM. The most stable Ni/LaCeY(1)Ox catalyst shows a decrease of the CH4 and CO2 conversions from initial values by 7.05 % and 4.52 %, respectively. Multi-walled carbon nanotubes with open edge Ni particles are dominant carbon species in spent Ni/LaCeY(1)Ox catalyst.
About the Authors
N. V. Dorofeeva
Tomsk State University
Russian Federation
Russian Federation
P. K. Putanenko
Tomsk State University
Russian Federation
Russian Federation
V. A. Svetlichnyi
Tomsk State University
Russian Federation
Russian Federation
O. V. Vodyankina
Tomsk State University
Russian Federation
Russian Federation
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For citations:
Dorofeeva N.V., Putanenko P.K., Svetlichnyi V.A., Vodyankina O.V. Ni-Based Catalysts on Ternary LaCeY Oxide Supports for Dry Reforming of Methane. Kataliz v promyshlennosti. 2025;25(3):37-50. (In Russ.) https://doi.org/10.18412/1816-0387-2025-3-37-50
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