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Multicycle PdII + Heteropoly Acid Catalytic System for Converting Linear α-Olefins to Sought-After 2-Ketones
https://doi.org/10.18412/1816-0387-2025-4-49-59
Abstract
The ability to undergo reversible electron addition while maintaining structural stability makes vanadium-containing polyoxometalates attractive objects for research in various fields of chemistry, including the creation of modern “green” processes. An effective Pd-containing catalytic system based on Pd(OAc)2 and high-vanadium heteropoly acid of the NaH10P4Mo18V7O87 composition, which allows performing two-stage oxidation of linear α-olefins C5–C10 into the corresponding 2-ketones with a yield above 93% in a two-phase aqueous-organic medium, has been developed. The system ensures the achievement of economically promising process efficiency indicators, is suitable for multicycle use, and makes it possible to avoid the application of high-pressure apparatus when carrying out the target reaction.
About the Authors
Y. A. Rodikova
Boreskov Institute of Catalysis SB RAS, Novosibirsk
Russian Federation
Russian Federation
E. G. Zhizhina
Boreskov Institute of Catalysis SB RAS, Novosibirsk
Russian Federation
Russian Federation
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Review
For citations:
Rodikova Y.A., Zhizhina E.G. Multicycle PdII + Heteropoly Acid Catalytic System for Converting Linear α-Olefins to Sought-After 2-Ketones. Kataliz v promyshlennosti. 2025;25(4):49-59. (In Russ.) https://doi.org/10.18412/1816-0387-2025-4-49-59
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