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Influence of thermal recovery modes on the formation, stability and catalytic properties of polymer-stabilized palladium nanoparticles in the reaction of selective hydrogenation of acetylenic alcohols
Abstract
Thermal destruction of palladium acetate at temperatures ranging from 200 to 325 °C in an industrial hypercrosslinked polystyrene MN-270 was investigated by TGA and XPS and described in this article. The studies have shown that the palladium acetate distributed into hypercrosslinked polystyrene collapses with forming of metal palladium at lower temperatures than the pure salt powder. The formation and stabilization of palladium clusters Pd7–Pd10 and their partial aggregation with the formation of palladium nanoparticles happens during the of destruction. The catalytic testing of obtained systems in the selective hydrogenation of the triple bond dimethyl-ethynyl carbinol in toluene at 90 °C showed their considerable superiority in activity and selectivity in comparison with a commercial Lindlyar catalyst: TOF increase more than doubled when the selectivity 97,8 %.
About the Authors
A. V. Bykov
Тверской государственный технический университет
Russian Federation
Russian Federation
L. J. Nikoshvili
Тверской государственный технический университет
Russian Federation
Russian Federation
N. A. Lyubimova
Тверской государственный технический университет
Russian Federation
Russian Federation
K. P. Komar
Тверской государственный технический университет
Russian Federation
Russian Federation
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Review
For citations:
Bykov A.V., Nikoshvili L.J., Lyubimova N.A., Komar K.P. Influence of thermal recovery modes on the formation, stability and catalytic properties of polymer-stabilized palladium nanoparticles in the reaction of selective hydrogenation of acetylenic alcohols. Kataliz v promyshlennosti. 2014;(2):72-79. (In Russ.)
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