Buy (625 RUB)
Generate QR code
Open Access
Subscription or Fee Access
Role of Zeolite in the Preparation of Liquid Hydrocarbons from CO and H2 on a Composite Со Catalyst
https://doi.org/10.18412/1816-0387-2015-4-6-13
Abstract
It has been found that the major role of zeolites in the Fischer-Tropsch synthesis on composite Co catalysts is to reduce the average molecular weight of hydrocarbons produced from CO and H2 on acid sites. Secondary transformations of hydrocarbons on zeolites presumably proceed by the carbocation mechanism. The total composition of the synthesis products depends on the properties of zeolite and on the interposition of active sites of the zeolite and cobalt. It is shown that in many cases the introduction of a zeolite in the H form into cobalt catalysts of the Fischer – Tropsch synthesis increases productivity and selectivity toward the synthetic oil and reduces the selectivity toward methane.
About the Authors
L. V. Sineva
Technological Institute for Superhard and Novel Carbon Materials, Moscow, Troitsk; LLC INFRA Technology, Moscow
Russian Federation
Russian Federation
E. Yu. Asalieva
Technological Institute for Superhard and Novel Carbon Materials, Moscow, Troitsk; Lomonosov Moscow State University, Moscow
Russian Federation
Russian Federation
V. Z. Mordkovich
Technological Institute for Superhard and Novel Carbon Materials, Moscow, Troitsk; LLC INFRA Technology, Moscow
Russian Federation
Russian Federation
References
1. Farrell A.E., Plevin R.J., Turner B.T., Jones A.D., O’Hare M., Kammen D.M. // Science. 2006. V. 311. P. 506.
2. Greener Fisсher–Tropsсh Processes / Ed. by Maitlis P.M., de Klerk A. Weinheim: Wiley–VCH, 2013. 372 pp.
3. Kibby C., Jothimurugesan K., Das T., LacheenHS, Rea T., Saxton R.J. // Catalysis Today. 2013. V. 215. P. 131.
4. Fischer–Tropsch Technology. Studies in Surface Science and Catalysis. / Ed. by Dry M., Steynberg A. Amsterdam: Elsiver, 2004. 700 pp.
5. Catalysis in the Refining of Fischer–Tropsch Syncrude. / Ed. by de Klerk A., Furimsky E. Cambridge, UK: RSC Publishing, 2010. 279 pp.
6. Van Steen E., Claeys M. // Chem. Eng. Technol. 2008. V. 31. P. 655.
7. Lapidus A.L., Krylova A.Yu., Mikhailova Ya.V., Sineva L.V., Erofeev A.B. // Solid Fuel Chemistry. 2011. V. 45. P. 71 [Химия твердого топлива. 2011. Т. 2. № 3. С. 3].
8. Li S.Z., Krishnamoorthy S., Li A.W., Meitzner G.D., Iglesia E. // J. Catal. 2002. V. 206. P. 202.
9. Лапидус А.Л., Крылова А.Ю. // Успехи химии. 1998. Т. 67. C. 1032.
10. Martinez A., Prieto G. // Top. Catal. 2009. V. 52. P. 75.
11. Cejka J., Corma A., Zones S. Zeolites and Catalysis. Weinheim: Wiley–VCH, 2010. 881 pp.
12. Li Y., Wang T., Wu C., Li H., Qin X., Tsubaki N. // Fuel Process. Technol. 2010. V. 91. P. 388.
13. Sartipi S., J van Dijk E., Gascon J., Kapteijn F. // Appl. Catal. A: Gen. 2013. V. 456. P. 11.
14. Martínez A., Rollán J., Arribas M.A., Cerqueira H.S., Costa A.F., Aguiar E.F.S. // J. Catal. 2007. V. 249. P. 162.
15. Freitez A., Pabst K., Kraushaar-Czarnetzki B., Schaub G. // Ind. Eng. Chem. Rev. 2011. V. 50. P. 13732.
16. Sineva L.V., Khatkova E.Yu., Kriventceva E.V., Mordkovich V.Z. // Mendeleev Commun. 2014. V. 24. P. 316.
17. Tsubaki N., Yoneyama Y., Michiki K., Fujimoto K. // Catal. Commun. 2003. V. 4. P. 108.
18. Sineva L.V., Mordkovich V.Z., Khatkova E.Yu. Mendeleev Commun. 2013. V. 23. P. 44.
19. Синева Л.В., Мордкович В.З., Ермолаев В.С., Ермолаев И.С., Митберг Э.Б., Соломоник И.Г. // Катализ в промышленности. 2012. № 6. С. 13.
20. Кривенцева Е.В., Грязнов К.О., Хатькова Е.Ю., Синева Л.В., Мордкович В.З. // Вестник МИТХТ. 2013. Т. 8. С. 9.
21. Nishiyama N., Miyamoto M., Egashira Y., Ueyama K. // Chem. Commun. 2001. V. 18. P. 1746.
22. Lai Z., Bonlla G., Diaz I., Nery J.G., Sujaoti K., Amat M.A., Kokkoli E., Terasaki O., Thompson R.W., Tsapatsis M.D., Vlachos G. // Science. 2003. V. 300. P. 456.
23. Feller A., Guzman A., Zuazo I., Lercher J.A. // J. Catal. 2004. V. 224. P. 80.
24. Sartipi S., van Dijk J.E., Gascon J., F Kapteijn. // Appl. Catal. A: Gen. 2013. V. 456. P. 11.
25. Derouane E.G., Roberts S.M. Catalysts for Fine Chemical Synthesis. Microporous and Mesoporous Solid Catalysts. England: John Wiley & Sons Ltd, 2006. 243 pp.
26. Пат. 2405625 РФ. Катализатор для синтеза углеводородов из СО и Н2 и способ его получения / Мордкович В.З., Синева Л.В., Соломоник И.Г., Ермолаев В.С., Митберг Э.Б. 2010.
27. Cheng K., Kang J., Huang S., You Z., Zhang Q. Ding, J., Hua W., Lou Y., Deng W., Wang Y. // ACS Catal. 2012. V. 2. P. 441.
28. Gopal D.V., Subrahmanyam M. // Green Chemistry. 2001. V. 3, P. 181.
29. Srinivas N., Singth A.P., Ramaswamy A.V., Finiels A., Moreau P. // Catalysis Letters. 2002. V. 80. No. 3–4. P. 181.
30. Wagholikar S.G., Niphadkar P.S., Mayadevi S., Sivasanker S. // Applied Catalysis A: Gen. 2007. V. 317. P. 250.
31. Субботина И.Р., Шелимов Б.Н., Казанский В.Б. // Кинетика и катализ. 2002. Т. 43. № 3. С. 445.
32. Bordiga S., Turnes P.G., Paze C., Zecchina A. // Microporous and Mesoporous Mater. 2000. V. 34. P. 67.
33. Corma A., Orchilles A.V. // Microporous and Mesoporous Mater. 2000. V. 35–36. P. 21.
34. Rahimi N., Karimzadeh R. // Appl. Catal. A: Gen. 2011. V. 398. P. 1.
35. Anderson B.G., Schumacher R.R., van Duren R., Singh A.P., van Santen R.A. // J. Mol. Catal. A: Chem. 2002. V. 181. P. 291.
36. Kustov L.M., Sachtler W.M.H. // J. Mol. Cat. 1992. V. 71. P. 233.
37. Caeiro G., Carvalho R.H., Wang X., Lemos M.A.N.D.A., Lemos F., Guisnet M., Ribeiro F.R. // J. Mol. Catal. A: Chem. 2006. V. 255. P. 131.
Review
For citations:
Sineva L.V., Asalieva E.Yu., Mordkovich V.Z. Role of Zeolite in the Preparation of Liquid Hydrocarbons from CO and H2 on a Composite Со Catalyst. Kataliz v promyshlennosti. 2015;15(4):6-13. (In Russ.) https://doi.org/10.18412/1816-0387-2015-4-6-13
Views:
685
Email this article 