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Sulfocationites in Processes of Synthesis of Linear Alkylphenols
https://doi.org/10.18412/1816-0387-2015-6-39-46
Abstract
Kinetic parameters of transformations during alkylation of phenol with linear (C9, C16) alkenes over sulfocationites Amberlyst 15 Dry, Amberlyst 35 Dry, Amberlyst 36 Dry, Amberlyst 70, Amberlyst DT, Tulsion 66 MP, Lewatit K2640, Lewatit K 2431, Relite EXC8D were experimentally determined. Activities of the said catalysts to various type reactions were compared. The transition from 1-nonene to linear hexadecane was shown to be accompanied by a decrease in rate constants of all the transformations. It was established that the ortho-APh/para-APh ratio was statistically equal in phenol alkylation with linear alkenes over all the sulfocationites under study in their operation regions.
About the Authors
T. N. Nesterova
Samara State Technical University, Samara
Russian Federation
Russian Federation
D. A. Chernyshov
Novokuibyshevsk Oils and Additives Plant, LLC, Novokuibyshevsk
Russian Federation
Russian Federation
V. A. Shakun
Samara State Technical University, Samara; SANORS Holding, Novokuibyshevsk
Russian Federation
Russian Federation
N. Yu. Krymkin
Samara State Technical University, Samara
Russian Federation
Russian Federation
A. V. Tarasov
Novokuibyshevsk Oils and Additives Plant, LLC, Novokuibyshevsk
Russian Federation
Russian Federation
O. I. Voronin
Samara State Technical University, Samara; SANORS Holding, Novokuibyshevsk
Russian Federation
Russian Federation
N. V. Bilenchenko
Samara State Technical University, Samara
Russian Federation
Russian Federation
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Review
For citations:
Nesterova T.N., Chernyshov D.A., Shakun V.A., Krymkin N.Yu., Tarasov A.V., Voronin O.I., Bilenchenko N.V. Sulfocationites in Processes of Synthesis of Linear Alkylphenols. Kataliz v promyshlennosti. 2015;15(6):39-46. (In Russ.) https://doi.org/10.18412/1816-0387-2015-6-39-46
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