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Deliberate Synthesis of a Copper Catalyst with a Nanostructured Active Component
https://doi.org/10.18412/1816-0387-2016-2-41-47
Abstract
The influence of hydrodynamic mode of mixing a copper-ammonium-carbonate slurry containing aluminosilica support on the chemical and phase composition of the active component (AC) precursor of the catalyst for dehydrogenation of cyclohexanol in the production of caprolactam was studied. XPS, DTA and adsorption techniques were used to establish that, under conditions of the advanced turbulent mode, the precursor is mainly deposited in the form of nanostructured hydroxocarbonates anchored tightly to the support. The lab-scale technology was scaled-up to industrial level. Properties of the new copper catalyst were studied to reveal that it is not inferior in the selectivity to the best known industrial (commercial) catalysts, but superior to them in the activity and thermostability.
About the Authors
V. I. Vanchurin
Mendeleev Russian Chemical and Technological University, Moscow
Russian Federation
Russian Federation
Yu. L. Pavlov
Mendeleev Russian Chemical and Technological University, Moscow
Russian Federation
Russian Federation
A. Yu. Petrov
Mendeleev Russian Chemical and Technological University, Moscow
Russian Federation
Russian Federation
L. I. Marachuk
GrodnoAzot JSC, Grodno
Belarus
Belarus
O. I. Karachenko
GrodnoAzot JSC, Grodno
Belarus
Belarus
A. V. Dul’nev
NIAP-KATALIZATOR LLC, Novomoscovsk
Russian Federation
Russian Federation
L. D. Rudnik
Plazmatekh JSC, Novomoscovsk
Russian Federation
Russian Federation
References
1. Пат. 2218987 РФ. Опубл. 20.12.2003, Бюл. №35.
2. Пат. 2157279 РФ. Опубл. 17.12.1999, Бюл. №28.
3. Пат. 2241540 РФ. Опубл. 10.12.2004, Бюл. № 34.
4. Ванчурин В.И., Костюченко В.В., Джумамухамедов Д.Ш., Половинкин М.А., Павлов Ю.Л., Марачук Л.И. // Химическая технология. Т.15. 2014. № 5. С. 283—288.
5. Ванчурин В.И., Джумамухамедов Д.Ш., Попова Н.А. // Стекло и керамика. 2014. № 11. C. 32—36.
6. Аксенов Н.Н., Тарасова Т.В., Костров В.В. // Труды ГИАП. Москва, 1990. С. 31—40.
7. Комова З.В., Зрелова И.П., Вейнбендер А.Я., Шкитина В.И., Крендель А.И., Шаркина В.И., Боевская Е.А. // Катализ в промышленности. 2007. № 5. С. 43—51.
8. Щанкина В.Г., Шаркина В.И., Боевская Е.А., Мельникова Т.И., Серегина Л.К., Меньшиков В.В. // Вестник МИТХТ. Химия и технология неорганических материалов. 2013. Т. 8. № 2.
9. Пахомов Н.А. Научные основы приготовления катализаторов. Промышленный катализ в лекциях / Под ред. А.С. Носкова. М.: Калвис. Вып. 1. 2005. 136 с. С. 122.
10. Чукин Г.Д. Строение оксида алюминия и катализаторов гидрообессеривания. Механизмы реакций. М.: Типография Паладин, ООО Принта, 2010. 288 с.
11. Gyung Soo Jeon, Gon Seo, Jong Shik Chung // Korean J. of Chem. Eng., - 1996. 13(4), P. 412—414.
12. Guoyi Bai, Hailong Wang, Huisen Ning, Fei He, Guofeng Chen // React. Kinet. Catal. Lett. 2008. 94(2). P. 375—383.
13. Guoyi Bai, Xinxin Fan, Hailong Wang, Fei He, Huisen Ning // React. Kinet. Catal. Lett. 2009. № 98. P. 341—348.
14. Nagaraja B.M., Kumar V.S., Shashikala V., Padmasri A.H., Reddy S.S., Raju B.D., Rama Rao K.S. // Journal of Molecular Catalysis A: Chemical. 223. 2004. P. 339—345.
Review
For citations:
Vanchurin V.I., Pavlov Yu.L., Petrov A.Yu., Marachuk L.I., Karachenko O.I., Dul’nev A.V., Rudnik L.D. Deliberate Synthesis of a Copper Catalyst with a Nanostructured Active Component. Kataliz v promyshlennosti. 2016;16(2):41-47. (In Russ.) https://doi.org/10.18412/1816-0387-2016-2-41-47
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