Buy (625 RUB)
|Generate QR code
Open Access
Subscription or Fee Access
New Method for Production of Substituted Anthraquinones via Diene Synthesis in the Presence of Mo-V-P Heteropoly Acid Solution: Catalyst Regeneration
https://doi.org/10.18412/1816-0387-2016-3-24-30
Abstract
Feasibility of catalytic synthesis of 2-methylanthraquinone from 1,4-naphthaquinone (NQ) and isoprene and of synthesis of 2,3-dimethylanthraquinone
from NQ and 2,3-dimethylbutadiene in the presence of an aqueous solution of high-vanadium heteropoly acid (HPA) as the bifunctional catalyst was demonstrated. Two methods for the catalyst regeneration are discussed: oxidation with oxygen at PO2 = 0,3÷0,4 MPa and with nitric acid at atmospheric pressure. It is shown that the regeneration with nitric acid provides deeper oxidation of the reduced catalyst. The full catalyst recovery after the regeneration allows its recycling in the processes under discussion.
About the Authors
L. L. Gogin
Boreskov Institute of Catalysis, Novosibirsk
Russian Federation
Russian Federation
E. G. Zhizhina
Boreskov Institute of Catalysis, Novosibirsk
Russian Federation
Russian Federation
Z. P. Pai
Boreskov Institute of Catalysis, Novosibirsk
Russian Federation
Russian Federation
References
1. Anthraquinone Dyes and Intermediates, in Ullmann’s Encyclopedia of Industrial Chemistry, Vol. A, 2007.
2. Anthraquinone, in Kirk-Othmer Encyclopedia of chemical technology, 5th Ed, Vol. 2, 2006.
3. Abdel-Yamid A.M., Solbiati J.O., Cann I.R.O. // Adv. Appl. Microbiol. 2013. V. 82. P. 1.
4. Kozhevnikov I.V. Catalysis for Fine Chemical Synthesis. Chichester (UK): John Wiley & Sons, LTD, 2002. V. 2.
5. Hill C.L., Kholdeeva O.A., in Liqiud Phase Oxidation via Heterogeneous Catalysis, Chapter 6; Clerici, M.G.; Kholdeeva, O.A., Eds.; Hoboken (NJ, USA): J. Wiley & Sons, 2013.
6. Misono M., in Studies in Surface Science and Catalysis (Solid acid and oxidation catalysts; primary, secondary and tertiary structures), Chapter 4; 2013. V. 176. P. 97.
7. Védrine J.C., Millet J.-M.M., in Metal Oxide Catalysis, Vol. 2 (Eds.: S. David Jackson, Justin S.J. Hargreaves), Wiley-VCH, Weinheim, 2009, Р. 561.
8. Lopez X., Carbó J.J., Bo C., Poblet J.M. // Chem. Soc. Rev. 2012. V. 41. P. 7537.
9. Zhizhina E.G., Odyakov V.F. // ChemCatChem. 2012. V. 4. P. 1405.
10. Одяков В.Ф., Жижина E.Г., Матвеев K. И. // Журнал неорганической химии. 2000. Т. 45 .С. 1258.
11. Zhizhina E.G., Odyakov V.F. // Appl. Catal., А. 2009. V. 358. P. 254.
12. Odyakov V.F., Zhizhina E.G., Maksimovskaya R.I. // Appl. Catal., A. 2008. V. 342. P. 126.
Review
For citations:
Gogin L.L., Zhizhina E.G., Pai Z.P. New Method for Production of Substituted Anthraquinones via Diene Synthesis in the Presence of Mo-V-P Heteropoly Acid Solution: Catalyst Regeneration. Kataliz v promyshlennosti. 2016;16(3):24-30. (In Russ.) https://doi.org/10.18412/1816-0387-2016-3-24-30
Views:
513
Email this article 