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Ruthenium Promoted Cobalt-Aluminium Catalysts for Synthesis of Solid High-Molecular Hydrocarbons from CO and Hydrogen
https://doi.org/10.18412/1816-0387-2016-4-57-66
Abstract
The influence of the promotion of Fischer – Tropsch Co-Al catalysts with ruthenium on the temperature of the reductive catalyst activation and on the catalytic behavior in the Fischer – Tropsch synthesis was studied. The ruthenium addition in proportion of 0,2 % to 1 wt.% was shown to reduce the temperature of the reductive activation from 500 down to 330–350 °C at the preserved high catalytic activity and selectivity to C5+ products of the Fisher – Tropsch synthesis. The ruthenium promoted Co-Al catalysts were more selective to high-molecular hydrocarbons, their experimental parameter αАSF of the paraffin series distribution was 0,93–0,94; hence the estimated selectivity to synthetic waxes C20+ was 48 wt.% including 23 wt.% selectivity to ceresins C35+. The ruthenium promoted catalysts also were more selective to olefins.
About the Authors
O. A. Kungurova
Research and Educational Center of Energy-Efficient Catalysis of the Novosibirsk State University, Novosibirsk; Boreskov Institute of Catalysis, Novosibirsk; Tomsk State University
Russian Federation
Russian Federation
N. V. Shtertser
Boreskov Institute of Catalysis, Novosibirsk
Russian Federation
Russian Federation
G. K. Chermashentseva
Boreskov Institute of Catalysis, Novosibirsk
Russian Federation
Russian Federation
I. I. Simentsova
Boreskov Institute of Catalysis, Novosibirsk
Russian Federation
Russian Federation
A. A. Khassin
Research and Educational Center of Energy-Efficient Catalysis of the Novosibirsk State University, Novosibirsk; Boreskov Institute of Catalysis, Novosibirsk
Russian Federation
Russian Federation
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Review
For citations:
Kungurova O.A., Shtertser N.V., Chermashentseva G.K., Simentsova I.I., Khassin A.A. Ruthenium Promoted Cobalt-Aluminium Catalysts for Synthesis of Solid High-Molecular Hydrocarbons from CO and Hydrogen. Kataliz v promyshlennosti. 2016;16(4):57-66. (In Russ.) https://doi.org/10.18412/1816-0387-2016-4-57-66
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