Quinoline Inhibiting of Hydrodesulfurization and Hydrogenation Reactions over Co(Ni)PMo(W)/Al2O3 Catalysts: Influence of the Active Phase Composition on the Stability during Hydrotreatment of Model and Oil Feedstock

Co(Ni)-PMo(W)/Al₂O₃ catalysts were prepared using Keggin heteropoly acids H₃PMo(W)₁₂O₄₀ and cobalt (nickel) citrate. Physicochemicalproperties of the catalysts were characterized using low-temperature nitrogen adsorption, XPS and HRTEM techniques. Catalytic properties were studied during hydrotreatment of a model feedstock containing dibenzothiophene, naphthalene and quinoline in different proportions (up to 1000 ppm of nitrogen), as well as during hydrotreatment of straight-run diesel fraction and vacuum gasoil. The composition of Со(Ni)-PMo(W)/Al₂O₃ catalysts was shown to play a crucial role in the hydrotreatment of complex hydrocarbon feedstock. The Ni-PW/Al₂O₃ catalyst was more stable to organonitrogen inhibitors than Ni(Co)-PMo/Al₂O₃ bearing more reactive active centers. The highest conversions of sulfur- and nitrogen-containing compounds and polycyclic aromatic hydrocarbons during hydrotreatment of vacuum gasoil were observed with the Ni-PW/Al₂O₃ catalyst.

1. Stanislaus A., Marafi A., Rana M.S. // Catal. Today. 2010. V. 153. P. 1.

2. Song C. // Catal. Today. 2003. V. 86. P. 211.

3. Topsøe H., Clausen B.S., Massoth F.E., Anderson J.R., Boudart M. (Eds.) // Catalysis — Science and Technology. Hydrotreating Catalysis. 1996. V. 11. P. 310.

4. Reinhoudt H.R., Boons C.H.M., van Langeveld A.D., van Veen J.A.R., Sie S.T., Moulijn J.A. // Appl. Catal., A: General. 2001. V. 207. P. 25—36.

5. Spojakinaa A., Palchevaa R., Jiratovab K., Tyulieva G., Petrov L. // Catal. Lett. 2005. V. 104. № 1—2. P. 45—52

6. Mozhaev A.V., Nikulshin P.A., Pimerzin A.A., Maslakov K.I., Pimerzin A.A. // Catal. Today. 2016. V. 271. P. 80—90.

7. Nikulshin P.A., Minaev P.P., Mozhaev A.V., Maslakov K.I., Kulikova M.S., Pimerzin A.A. // Appl. Catal., B: Environmental. 2015. V. 176-177. P. 374—384.

8. Minaev P.P., Nikulshin P.A., Kulikova M.S., Pimerzin A.A., Kogan V.M. // Appl. Catal., A: General. 2015. V. 505. P. 456—466.

9. Nikulshin P.A., Ishutenko D.I. Mozhaev A.A., Maslakov K.I., Pimerzin A.A. // J. Catal. 2014. V. 312. P. 152—169.

10. Speight J.G. // The Chemistry and Technology of Petroleum. 2006. P. 984.

11. Halachev T., Nava R., Dimitrov L. // Appl. Catal., A: General. 1998. V. 169. P. 111—117.

12. Speight J.G. // The chemistry and technology of petroleum. 2007. P. 36.

13. Knudsen K.G., Cooper B.H., Topsøe H. // Appl. Catal., A: General. 1999. V. 189. P. 205.

14. Andari M. K., Abu-Seedo F., Stanislaus A., Qabazard H.M. // Fuel. 1996. V. 75 № 14. P. 1664—1670.

15. Сальников В.А., Никульшин П.А., Пимерзин А.А. // Нефтехимия. 2013. Т. 53. № 4. С. 267—279.

16. Egorova M., Prins R. // Catal. Lett.. 2004. V. 92. P. 3.

17. Beltramone A.R., Crossley S., Resasco D.E., Alvarez W.E., Choudhary T.V. // Catal. Lett.. 2008. V. 123. P. 181.

18. Shih S.S., Mizrahi S., Green L.A., Sarli M.S. // Ind. Eng. Chem. Res. 1992. V. 31. P. 1232.

19. Whitehurst D.D., Isoda T., Mochida I. // Advances in Catalysis. 1998. V. 42. P. 345.

20. Oyama T.S. // J. Catal. A. 2003. V. 216. P. 343.

21. Chun X., Yong-ming C., Yun-qi L., Chen-guang L. // Journal of Fuel Chemistry and Technology. 2008. V. 36. № 6. P. 684.

22. Lio K., Ng F.T.T. // Catal. Today. 2010. V. 149. P. 28.

23. Kabe T., Ishihara A., Tajima H. // Ind. Eng. Chem. Res. 1992.

24. V. 31. P. 1577. 24. Macaud M., Milenkovic A., Schulz E., Lemaire M., Vrinat M. // J. Catal. 2000. V. 193. № 2. P. 255—263.

25. Liu Z., Zheng Y., Wang W., Zhang Q., Jia L. // Appl. Catal., A: General. 2008. V. 339. № 2. P. 209—220.

26. Rana M.S., Navarro R., Leglise J. // Catal. Today. 2004. V. 98. P. 67.

27. Logadottir A., Moses P.G., Hinnemann P., Topsøe N.Y., Knudsen K.G., Topsøe H., Nørskov J.K. // Catal. Today. 2006. V. 111. P. 44.

28. Mizutani H., Godo H., Ohsaki T., Kato Y., Fujikawa T., Saih Y., Funamoto T., Segawa K. // Appl. Catal., A: General. 2005. V. 295. P. 193.

29. Egorova M., Prins R. // J. Catal.. 2004. V. 221. P. 11.

30. Egorova M., Prins R. // J. Catal. 2004. V. 224. P. 278.

31. Laredo G.C., Montesinos A., De los Reyes J.A. // Appl. Catal., A: General. 2004. V. 265. P. 171.

32. Koltai T., Macaud M., Guevara A., Schulz E., Lemaire M., Bacaud R., Vrinat M. // Appl. Catal., A: General. 2002. V. 231. № 1. P. 253—261.

33. Laredo S., Georgina C., J.Antonio De los Reyes H., J Luis Cano D., J Jesús Castillo M. // Appl. Catal., A: General. 2001. V. 207. № 1. P. 103—112.

34. Сирюк А.Г., Зимина К.И. // Химия и технология топлив и масел. 1963. № 2. P. 52—56.

35. Еремина Ю.В. Изучение особенностей реакций гидродесульфирования и гидрирования компонентов дизельных фракций на молибденсодержащих катализаторах. Самара: СамГТУ. 2006. P.136.

36. Tayeb K.B., Lamonier C., Lancelot C., Fournier L., Bonduelle-Skrzypczak A., Bertoncini F. // Catal. Lett. 2014. V. 144. № 3. P.460—468.

37. Tayeb K.B., Lamonier C., Lancelot C., Fournier L., Payen E., Bonduelle A., Bertoncini F. // Catal. Today. 2010. V. 150. № 3-4. P. 207—212.

38. Zuo D., Vrinat M., Nie H., Maugéc F., Shi Y., Lacroix M., Dadong Li. // Catal. Lett.. 2004. V. 93-95. P. 751—760.

39. Coulier L., Kishan G., van Veen J.A.R., Niemantsverdriet J.W. // J. Phys. Chem. B. 2002. V. 106. № 23. P. 5897—5906.

40. Mogica-Betancourt J.C., López-Benítez A., Montiel-López J.R., Massin L., Aouine M., Vrinat M., Berhault G., Guevara-Lara A. // J. Catal. 2014. V. 313. P. 9—23.