Kataliz v promyshlennosti
Kataliz v promyšlennosti

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ISSN 2413-6476 (Online)

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Catalytic Hydrogenation of Furfural

K. E. Sal’nikova, V. S. Isaev, V. G. Matveeva, A. I. Sidorov, A. V. Bykov, I. P. Shkilyeva, E. M. Sul’man

https://doi.org/10.18412/1816-0387-2018-2-6-10

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Abstract

Palladium catalysts for selective hydrogenation of furfural to furfuryl alcohol were studied. Properties of the catalytic systems prepared using different supports (alumina and hypercrosslinked polystyrene) and different precursors (palladium chloride and palladium chloride bisacetonitrile) were compared. The natures of the support and precursor were demonstrated to affect considerably the catalyst morphology and activity to the selective hydrogenation of furfural. The furfural conversion in the presence of the most effective catalyst 3% Pd/MN270 (PdCl₂) reached more than 95 % at the selectivity for furfuryl alcohol as high as 94 %.

Keywords

palladium catalysts, hydrogenation, furfural, furfuryl alcohol, hypercrosslinked polystyrene, the nature of the precursor

About the Authors

K. E. Sal’nikova

Tver State Technical University; Tver State University
Russian Federation

V. S. Isaev

Tver State Technical University
Russian Federation

V. G. Matveeva

Tver State Technical University; Tver State University
Russian Federation

A. I. Sidorov

Tver State Technical University
Russian Federation

A. V. Bykov

Tver State Technical University
Russian Federation

I. P. Shkilyeva

Tver State Technical University
Russian Federation

E. M. Sul’man

Tver State Technical University
Russian Federation

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Review

For citations:

Sal’nikova K.E., Isaev V.S., Matveeva V.G., Sidorov A.I., Bykov A.V., Shkilyeva I.P., Sul’man E.M. Catalytic Hydrogenation of Furfural. Kataliz v promyshlennosti. 2018;18(2):6-10. (In Russ.) https://doi.org/10.18412/1816-0387-2018-2-6-10

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ISSN 1816-0387 (Print)
ISSN 2413-6476 (Online)