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The Catalytic Activity of Amberlyst A-21 to Disproportionation of Trichlorosilane at Critical Temperatures
https://doi.org/10.18412/1816-0387-2018-2-50-56
Abstract
Catalytic properties of anion-exchange resin Amberlyst A-21 in gas-phase disproportionation of trichlorosilane (TCS) at resine critical temperature (up to 423 K) were studied for the first time. The thermodesorprtion followed by pyrolysis were used to establish thermal destruction of Amberlyst A-21 undergoes to form methyl chloride and of the spherical matrix at above 423 K. When Amberlyst A-21 operated at 333–423 K, the apparent activation energy of TCS disproportionation was 37.12 kJ/mol, and the reaction rate constant 0.80 s–1 (at 423 K). Three-month testing of the resin for TCS disproportionation at 423 K demonstrated the stabile catalytic activity.
About the Authors
A. V. Vorotyntsev
Nizhny Novgorod State Technical University
Russian Federation
Russian Federation
A. N. Petukhov
Nizhny Novgorod State Technical University
Russian Federation
Russian Federation
E. N. Razov
Institute of Machine Construction Problems, Nizhny Novgorod
Russian Federation
Russian Federation
D. A. Makarov
Nizhny Novgorod State Technical University
Russian Federation
Russian Federation
V. M. Vorotyntsev
Nizhny Novgorod State Technical University
Russian Federation
Russian Federation
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For citations:
Vorotyntsev A.V., Petukhov A.N., Razov E.N., Makarov D.A., Vorotyntsev V.M. The Catalytic Activity of Amberlyst A-21 to Disproportionation of Trichlorosilane at Critical Temperatures. Kataliz v promyshlennosti. 2018;18(2):50-56. (In Russ.) https://doi.org/10.18412/1816-0387-2018-2-50-56
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