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Destruction of High-Molecular Components of Natural Bitumens over Mesoporous Nickel-Containing Aluminosilicate Catalyst
https://doi.org/10.18412/1816-0387-2018-3-64-71
Abstract
The studies dealt with the influence of mesoporous aluminosilicate (MP-Al-Si) and its mixture with nanosize nickel powder (MP-Al-Si/Ni) on the product composition of cracking of natural bitumens (Tatarstan Republic) containing less than 7 % of ibp-200°C fractions in an autoclave reactor. Addition of mesoporous aluminosilicate (5 wt.%) to bitumen was shown to favor the deep destruction of high-molecular components and to increase the proportion of fractions boiling aut below 360°C. In the presence of the MP-Al-Si/1%Ni mixture, the coke formation slowed down to less than half, the content of ibp-360 °C fractions being increased by 14.2–14.7 wt % and that of the products tars and asphaltene destruction by 1.4–2.7 wt % against their contents in the bitumen cracking products in the presence of MP-Al-Si. The use of MP-Al-Si allows the effective processing of heavy hydrocarbon materials to gasoline and diesel fraction at low yields of gas and seal products.
About the Authors
N. N. Sviridenko
Institute of Petroleum Chemistry SB RAS, Tomsk
Russian Federation
Russian Federation
E. B. Krivtsov
Institute of Petroleum Chemistry SB RAS, Tomsk
Russian Federation
Russian Federation
A. K. Golovko
Institute of Petroleum Chemistry SB RAS, Tomsk
Russian Federation
Russian Federation
A. V. Vosmerikov
Institute of Petroleum Chemistry SB RAS, Tomsk
Russian Federation
Russian Federation
M. R. Agliulin
Institute of Petrochemistry and Catalysis of RAS, Ufa
Russian Federation
Russian Federation
B. I. Kutepov
Institute of Petrochemistry and Catalysis of RAS, Ufa
Russian Federation
Russian Federation
I. S. Korol
Tomsk Division of Trofimuk Institute of Petroleum-Gas Geology and Geophysics SB RAS, Tomsk
Russian Federation
Russian Federation
References
1. Муслимов Р.Х., Романов Г.В., Каюкова Г.П., Юсупова Т.Н., Петров С.М. // ЭКО. 2012. №. 1. С. 35—40.
2. Окунев А.Г., Пархомчук Е.В., Лысиков А.И., Парунин П.Д., Семейкина В.С., Пармон В.Н. // Успехи химии. 2015. № 9. С. 987—999.
3. Shahandeh H., Li Z. // Energy & Fuels. 2016. V. 30. P. 5202—5213.
4. Styles Y., de Klerk A. // Energy & Fuels. 2016. V. 30. P. 5214— 5222.
5. Nassar N.N., Hassan A., Pereira-Almao P. // Energy & Fuels. 2011. № 25. P. 1566—1570.
6. Sodero A.C.R., Silva H.S., Level P.G., Bouyssiere B., Korb J-P., Carrie H., Alfarra A., Bégué D., Baraille I. // Energy&Fuels. 2016. V. 30. P. 4758-4766.
7. Sviridenko N.N., Krivtsov E.B., Golovko A.K. // Chemistry and Technology of Fuels and Oils. 2016. V. 52. № 3. P. 285—292.
8. Свириденко Н.Н., Кривцов Е.Б., Головко А.К. // Катализ в промышленности. 2017. № 2. С. 137—144.
9. Dhir S., Mahapatra N., Kurian V., Alipour M., Gupta R. // Energy&Fuels. 2016. V. 30. P. 6132—6142.
10. Gabrienko A.A., Martyanov O.N., Kazarian S.G. // Energy & Fuels. 2016. V. 30. P. 4750 —4757.
11. Jia N., Zhao H., Yang T., Ibatullin T., Gao J. // Energy&Fuels. 2016. V. 30. P. 5291—5299.
12. Hauser A., Humaidan F., Al-Rabiah H., Halabi M.A. // Energy & Fuels. 2014. V. 28. P 4321-4332.
13. Zhang J.X., Zhou Y., Xu Y., Tian H.P. // China petroleum processing & petrochemical technology. 2014. V. 16. P. 7—11.
14. Agliullin M.R., Grigor'eva N.G., Danilova I.G., Magaev O.V., Vodyankina O.V. // Kinitics and Сatalysis. 2015. V. 56. P. 501-508.
15. Головко А.К., Горбунова Л.В., Камьянов В.Ф. // Геология и геофизика. 2010. Т. 51 (3). С. 364—374.
Review
For citations:
Sviridenko N.N., Krivtsov E.B., Golovko A.K., Vosmerikov A.V., Agliulin M.R., Kutepov B.I., Korol I.S. Destruction of High-Molecular Components of Natural Bitumens over Mesoporous Nickel-Containing Aluminosilicate Catalyst. Kataliz v promyshlennosti. 2018;18(3):64-71. (In Russ.) https://doi.org/10.18412/1816-0387-2018-3-64-71
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