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Application of Low-Temperature Molten Dialkylimidazole Salts for Catalytic Alkylation and Hydrodechlorination
https://doi.org/10.18412/1816-0387-2018-4-48-56
Abstract
The paper deals with the possibility of preparing a mixture of 1,3-dialkylimidazole salts from commercially available reagents via multicomponent condensation. Main factors affecting the yield of the target product, as well as the obtained experimental data needed for scaling-up the process are discussed. It is shown that the prepared mixtures are close in some key properties (viscosity at different temperatures, heat capacity etc.) to the pure salts. The possibility of the application of the prepared salts as solvents for catalytic hydrodechlorination and catalyst components for alkylation of aromatic compounds is demonstrated.
About the Authors
A. S. Klimenko
Boreskov Institute of Catalysis SB RAS, Novosibirsk; Volgograd Department of the Boreskov Institute of Catalysis SB RAS
Russian Federation
Russian Federation
S. A. Prikhod’ko
Boreskov Institute of Catalysis SB RAS, Novosibirsk
Russian Federation
Russian Federation
A. M. Beskopylnyi
Boreskov Institute of Catalysis SB RAS, Novosibirsk; Volgograd Department of the Boreskov Institute of Catalysis SB RAS
Russian Federation
Russian Federation
I. V. Tertishnikov
Volgograd Department of the Boreskov Institute of Catalysis SB RAS
Russian Federation
Russian Federation
N. Yu. Adonin
Boreskov Institute of Catalysis SB RAS, Novosibirsk
Russian Federation
Russian Federation
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Review
For citations:
Klimenko A.S., Prikhod’ko S.A., Beskopylnyi A.M., Tertishnikov I.V., Adonin N.Yu. Application of Low-Temperature Molten Dialkylimidazole Salts for Catalytic Alkylation and Hydrodechlorination. Kataliz v promyshlennosti. 2018;18(4):48-56. (In Russ.) https://doi.org/10.18412/1816-0387-2018-4-48-56
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