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Dichloro-[2,2]-paracyclophane. Methods for Synthesis
https://doi.org/10.18412/1816-0387-2018-5-19-30
Abstract
Methods for synthesis of dichloro-[2,2]-paracyclophane (dichloroPCP) are discussed. DichloroPCP is a valuable monomer to prepare polymer coats for electronics. This monomer is not produced in Russia. Analysis of available synthetic techniques leads to conclude that the Hofmann method for cleavage of quaternary ammonium salts is the most appropriate for the industrial production. Application of catalytic technologies – alkali catalysis and catalysis by Lewis acids – is the promising way for practical implementation of this four-stage process.
About the Authors
L. L. Gogin
Boreskov Institute of Catalysis, Novosibirsk
Russian Federation
Russian Federation
D. Yu. Yushchenko
Boreskov Institute of Catalysis, Novosibirsk
Russian Federation
Russian Federation
V. N. Konev
Boreskov Institute of Catalysis, Novosibirsk
Russian Federation
Russian Federation
E. E. Sergeev
Boreskov Institute of Catalysis, Novosibirsk
Russian Federation
Russian Federation
E. G. Zhizhina
Boreskov Institute of Catalysis, Novosibirsk
Russian Federation
Russian Federation
T. B. Khlebnikova
Boreskov Institute of Catalysis, Novosibirsk
Russian Federation
Russian Federation
Z. P. Pai
Boreskov Institute of Catalysis, Novosibirsk
Russian Federation
Russian Federation
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Review
For citations:
Gogin L.L., Yushchenko D.Yu., Konev V.N., Sergeev E.E., Zhizhina E.G., Khlebnikova T.B., Pai Z.P. Dichloro-[2,2]-paracyclophane. Methods for Synthesis. Kataliz v promyshlennosti. 2018;18(5):19-30. (In Russ.) https://doi.org/10.18412/1816-0387-2018-5-19-30
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