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Studies of the Influence of Promoting the Ni/Al2O3 Catalyst with Copper on the Activity to Hydrotreatment of Esters
https://doi.org/10.18412/1816-0387-2019-1-40-49
Abstract
The influence of the composition of the active component of copper-doped nickel catalysts on the activity and selectivity to hydrodeoxygenation (HDO) of model vegetable oils (esters) to eliminate oxygen and produce alkanes was studied. The Ni/Al2O3 andNi-Cu/Al2O3 catalysts were shown to be active to this process. They catalyzed HDO of a mixture of methyl ester of hexadecane acid and ethyl ester of decane acid to produce C6–C16 alkanes and oxygen-containing compounds, methane and ethane being detected in the gas phase. A decrease in the Ni/Cu ratio in the catalyst led to a decrease in the ester conversion and in the catalyst activity to hydrogenolysis of C–C bonds. Hence, the introduction of copper may favor preservation of the carbon skeleton of HDO-produced alkanes and a decrease in the methane yield. XRD studies revealed the formation of solid solutions Ni1–xCux upon addition of copper to the Ni/Al2O3 catalyst. From XPS data, an increase in the copper proportion in the Ni-Cu/Al2O3 catalyst resulted in a decrease in the Ni/Cu ration on the catalyst surface.
About the Authors
R. G. Kukushkin
Boreskov Institute of Catalysis, Novosibirsk; Novosibirsk State University
Russian Federation
Russian Federation
P. M. Eletskiy
Boreskov Institute of Catalysis, Novosibirsk
Russian Federation
Russian Federation
O. A. Bulavchenko
Boreskov Institute of Catalysis, Novosibirsk; Novosibirsk State University
Russian Federation
Russian Federation
A. A. Saraev
Boreskov Institute of Catalysis, Novosibirsk; Novosibirsk State University
Russian Federation
Russian Federation
V. A. Yakovlev
Boreskov Institute of Catalysis, Novosibirsk; Novosibirsk State University
Russian Federation
Russian Federation
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Review
For citations:
Kukushkin R.G., Eletskiy P.M., Bulavchenko O.A., Saraev A.A., Yakovlev V.A. Studies of the Influence of Promoting the Ni/Al2O3 Catalyst with Copper on the Activity to Hydrotreatment of Esters. Kataliz v promyshlennosti. 2019;19(1):40-49. (In Russ.) https://doi.org/10.18412/1816-0387-2019-1-40-49
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