Buy (625 RUB)
Generate QR code
Open Access
Subscription or Fee Access
Hydrogenation of plant oil over a palladium catalyst supported on activated diatomite
https://doi.org/10.18412/1816-0387-2019-4-265-274
Abstract
A possibility of lowering the formation of trans-isomers during hydrogenation of plant oil over a low-loaded palladium catalyst supported on activated diatomite was studied. The comparison to the commercial nickel catalyst led to establish that the activated diatomite is a promising support of the catalyst for hydrogenation of plant oil. Palladium particles of 2–10 nm in size (3–6 nm particles predominated) were shown to be uniformly distributed over the support surface. It was shown experimentally that the Pd catalyst was more active and selective at low temperature than the nickel catalyst to provide two-fold decrease in the concentration of trans-isomers in the hydrogenated fat.
About the Authors
K. Toshtay
Al-Farabi Kazakh National University, Almaty
Kazakhstan
Kazakhstan
A. B. Auezov
Al-Farabi Kazakh National University, Almaty
Kazakhstan
Kazakhstan
References
1. O’Brien R.D. Fats and oils: formulating and processing for applications. New York: CRC Press, 2008.
2. List G.R., King J.W. Hydrogenation of fats and oils: theory and practice. AOCS Press, 2011.
3. Food and Drug Admistration, FDA acts to provide better information to consumers on trans fats, 2005(http://www.fda.gov/oc/initiatives/transfat/).
4. Mozaffarian D., Martijn B., Katan., Alberto A., Meir J.S., Walter C.W. // N. Engl. J. Med. 2006. V. 354. № 15. P. 1601-1613. https: DOI: 10.1056/NEJMra054035
5. Brouwer I.A., Wanders A.J., Katan M.B. // PloS one. 2010. V. 5. № 3. P. e9434. https://doi.org/10.1371/journal.pone.0009434
6. Cepeda E.A., Calvo B. // J. Food Eng. 2008. V. 89. № 4. P. 370-374. https://doi.org/10.1016/j.jfoodeng.2008.01.012
7. Alsobaai A.M., Al Shaibani A.M., Moustafa T., Yaakobd Z. //Arab. J. Sci. Eng. 2013. V. 38. № 9. P. 2273-2278. https://doi.org/10.1007/s13369-013-0558-5
8. US Patent 6391815, 2002.
9. Anwar F., Kazi T.G., Jakharani M.A., Sultana R., Sahito S.R. // J. Chem. Soc. Pak. 2003. V. 25. № 3. P. 210-214.
10. Savchenko V.I., Makaryan I.A. // Platin. Met. Rev. 1999. V. 43. № 2. P. 74-82.
11. Fernández, María B., Gabriela M.T, Daniel E. // Chem. Eng. J. 2009. V. 155. № 3. P. 941-949. https://doi.org/10.1016/j.cej.2009.09.037
12. McArdle S., Girish S., Leahy J.J., Curtin T. // J. Mol. Catal. A: Chem. 2011. V. 351. P. 179-187. https://doi.org/10.1016/j.molcata.2011.10.004
13. Nohair B., Especel, C., Marecot P., Montassier C., Hoang, L.C,. Barbier J. // C. R.Chim. 2004. V. 7. № 2. P. 113-118. https://doi.org/10.1016/j.crci.2003.10.012
14. Nasima Ch., Safia H., Joseph А., Khaled B. // Can. J. Chem. Eng. 2012. V. 90. № 1. P. 41-50. https://doi.org/10.1002/cjce.20672
15. Alshaibani A.M., Yaakob Z., Alsobaai A.M., Sahri M. // Braz. J. Chem. Eng. 2014. V. 31. № 1. P. 69-78. http://dx.doi.org/10.1590/S0104-66322014000100008
16. Simakova I.L., Simakova O.A., Anatoliy V., Dmitry Yu.M. // Ind. Eng. Chem. Res. 2008. V. 47. № 19. P. 7219-7225. DOI: 10.1021/ie800663j
17. Belkacemi K., Kemache N., Hamoudi S, Arul J. // Int. J. Chem. React. Eng. 2007. V. 5. P. 1-25. https://doi.org/10.2202/1542-6580.1528
18. Fernandez M.B., Piqueras C.M., Tonetto G.M., Crapiste G., Damiani D.E. // J. Mol. Catal. A: Chem. 2005. V. 233. № 1-2. P. 133-139. https://doi.org/10.1016/j.molcata.2005.02.012
19. Qiu Y., Xu X., Gao L. // React. Kinet. Mech. Catal. 2005. V. 85. № 2. P. 223-229. https://doi.org/10.1007/s11144-005-0264-8
20. Yemİşçİoğlu F., Bayaz M., Gümüşkesen A.S. // GIDA-J. Food. 2010. V. 35. № 1. P. 13-19.
21. Berben P.H., Blom P.J.W., Sollie J.C. Palladium and platinum catalyzed oil hydrogenation: effects of reaction conditions on trans isomer and saturate formation // Practical short course series: Vegetable oils processing and modification techniques. College Station, Texas: Texas A&M Univ. 2000.
22. Toshtay K., Auyezov A.B., Bizhanov Zh.A., Yeraliyeva A.T., Toktasinov S.K., Kudaibergen B., Nurakyshev A. // Eurasian Chem. Tech. J. 2015. V. 17. № 1. P. 33-39. http://dx.doi.org/10.18321/ectj192
23. ГОСТ Р 52677—2006. Масла растительные, жиры животные и продукты их переработки. Методы определения массовой доли трансизомеров жирных кислот.
24. ГОСТ 31665—2012. Масла растительные и жиры животные. Получение метиловых эфиров жирных кислот.
25. ГОСТ Р ИСО 3961—2010. Жиры и масла животные и растительные: определение йодного числа.
26. ГОСТ Р 51445—99. Жиры и масла животные. Метод определения показателя преломления.
27. ГОСТ Р 52179—2003. Маргарины, жиры для кулинарии, кондитерской, хлебопекарной и молочной промышленности. Правила приемки и методы контроля.
28. ГОСТ Р 53158—2008. Масла растительные, жиры животные и продукты их переработки. Определение содержания твердого жира методом ядерно-магнитного резонанса.
29. Condon J.B. Surface area and porosity determinations by physisorption: measurements and theory. Elsevier, 2006.
30. Coenen J.W.E. // Ind. Eng. Chem. Fundam. 1986. V. 25. № 1. P. 43-52. DOI: 10.1021/i100021a006
31. Abdullina R.M., Voropaev I.N., Romanenko A.V., Chumachenko V.A., Noskov A.S., Mashnin A.S. // Russ. J. Appl. Chem. 2012. V. 85. № 8. P. 1204-1211. https://doi.org/10.1134/S1070427212080125
32. Coenen J.W.E. // J. Am. Oil Chem.’ Soc. 1976. V. 53. № 6. P. 382-389. https://doi.org/10.1007/BF02605727
33. Veldsink J.W., Bouma M.J., Schöön N.H., Beenackers A.A. // Cat. Rev. 1997. V. 39. № 3. P. 253-318. https://doi.org/10.1080/01614949709353778
34. Mondal K., Lalvani S.B. // J. Am. Oil Chem.’ Soc. 2003. V. 80. № 11. P. 1135—1141. https://doi.org/10.1007/s11746-003-0832-8
35. Drozdowski B., Szukalska E. // Eur. J. Lipid Sci. Technol. 2000. V. 102. № 10. P. 642—645. https://doi.org/10.1002/1438-9312(200010)102:10<642::AID-EJLT642>3.0.CO;2-I
Review
For citations:
Toshtay K., Auezov A.B. Hydrogenation of plant oil over a palladium catalyst supported on activated diatomite. Kataliz v promyshlennosti. 2019;19(4):265-274. (In Russ.) https://doi.org/10.18412/1816-0387-2019-4-265-274
Views:
1436
Email this article 