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Oligomerization of pent-1-ene over zeolite catalysts
https://doi.org/10.18412/1816-0387-2019-4-307-315
Abstract
Oligomerization of pent-1-ene is an effective process for synthesis of high-quality environmentally friendly fuel components. Catalytic properties of H-zeolites FAU, OFF, MOR, ВЕА, MTW and MFI were studied for synthesis of pentene oligomers in an autoclave at 110–200 °C. The wide-pore structure of H-Y and H-Beta (18) zeolites and the high concentration of acid sites were established to cause the high oligomerization activity to obtain 97–100 % yields of oligomers. Oligomers obtained over these catalysts comprised, depending on the reaction conditions, 30–73 % dimers, 25–50 % trimers and 2–14 % oligomers with more than three monomer units (n > 3). Fine-pore zeolites (H-ZSM-5) and zeolites with one-dimensional channel systems (H-OFF, H-MOR, H-ZSM-12) were less active to oligomerization of pent-1-ene, decenes being the main reaction products.
About the Authors
N. G. Grigoryeva
Institute of Petrochemistry and Catalysis, Ufa
Russian Federation
Russian Federation
D. V. Serebrennikov
Institute of Petrochemistry and Catalysis, Ufa
Russian Federation
Russian Federation
S. V. Bubennov
Institute of Petrochemistry and Catalysis, Ufa
Russian Federation
Russian Federation
B. I. Kutepov
Institute of Petrochemistry and Catalysis, Ufa
Russian Federation
Russian Federation
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Review
For citations:
Grigoryeva N.G., Serebrennikov D.V., Bubennov S.V., Kutepov B.I. Oligomerization of pent-1-ene over zeolite catalysts. Kataliz v promyshlennosti. 2019;19(4):307-315. (In Russ.) https://doi.org/10.18412/1816-0387-2019-4-307-315
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