

Transformation of paraffin and olefin hydrocarbons on the modified on the zeolite-containing cracking catalyst
https://doi.org/10.18412/1816-0387-2020-1-61-66
Abstract
As a catalyst for studying the conversion of hydrocarbons contained in catalytic cracking gases, a modified Ni, Co, Cr industrial OMNIKAT-210P zeolite-containing catalyst was used. The purpose of the research is to obtain a high-octane component of gasoline. The deposition of metals was carried out on nano-sized particles of a zeolite-containing catalyst. Particle size was at the level of (5÷10)·10–9 m. The particle size allows you to evenly apply the metals Ni, Cr, Co on the surface of the nanoparticles. Then the particles are molded in the form of balls with a size of 2–3 mm and subjected to drying (120 °С) and calcining 450–500 °С. The yield of liquid products is at the level of 48.3–30.3 % of the mass.
About the Authors
A. A. KasimovAzerbaijan
Kh. B. Pirieva
Azerbaijan
S. A. Jamalova
Azerbaijan
S. M. Hajizade
Azerbaijan
Z. R. Ismailova
Azerbaijan
T. F. Agaeva
Azerbaijan
S. A. Zeynalova
Azerbaijan
Sh. A. Nuriev
Azerbaijan
References
1. Герзелиев И.М., Уодинов М.В., Хаджиев С.Н. // Нефтехимия. 2009. Т. 49. № 1. С .3–8.
2. Hommeltoft S.I. //Applied Catalysis A.:General. 2001. V. 221. Р. 421–428.
3. Солодова Н.Л., Абдиллин Н.И., Емельянычева Е.А. // Вестник Казанского технологич. ун-та. 2013. Т. 16. № 18. С. 253–258.
4. Солодова Н.Л., Хасанов И.Р. // Вестник технологич. ун-та. 2015. Т. 18. № 7. С. 119–123.
5. Цадкин М.А., Бадикова А.Д. // Прикладная химия и биотехнология. 2016. Т. 6. № 2. С. 71–75.
6. Huang C.P., Liu Z.C., Xu C.M. et al. // Applied Catalysis A.: General. 2004. V. 277. № 1-2. Р. 41–43.
7. Aschaner S., Schilder L., Korth W. et al. // Catalysis Letters. 2011. № 141. Р. 1405–1419.
8. Liu Y., Hu R., Xu C., Su H. // Applied Catalysis A-General. 2008. V. 346. № 1. Р. 189–193.
9. Zhao D., Wu M., Kon Y., Min E. // Catalysis today. 2002. V. 74. Р. 157–189.
10. Yoo K., Namboodiri V.V., Varma R.S. Panagiotis G.S. // Journal of catalysis. 2004.V. 223. Р. 511–519.
11. Xiao X., Tier-ney J.W., Wender I.I. et. al. //Applied catalysis A.: General. 1999. V. 183. № 1. Р. 278–282.
12. Крылов О.В. Новое в алкилировании // Катализ в промышленности. 2005. № 4. С. 9–13.
Review
For citations:
Kasimov A.A., Pirieva Kh.B., Jamalova S.A., Hajizade S.M., Ismailova Z.R., Agaeva T.F., Zeynalova S.A., Nuriev Sh.A. Transformation of paraffin and olefin hydrocarbons on the modified on the zeolite-containing cracking catalyst. Kataliz v promyshlennosti. 2020;20(1):61-66. (In Russ.) https://doi.org/10.18412/1816-0387-2020-1-61-66