SYNTHESIS OF METAL INTERCALATED CLAY CATALYSTS FOR SELECTIVE HYDROGENATION REACTIONS
Abstract
Interlamellar space of the smectite clay minerals have been found as an excellent nano phase reactor due to their easy swelling property and the adsorption capacity. In this work size quantized nano particles of catalytically active noble metals have been generated within the interlamellar space of the smectite type clay minerals. Platinum and ruthenium intercalated/impregnated montmorillonite and hectorite catalysts were synthesised and characterized by various instrumental techniques. Catalytic activity of the synthesised catalysts was evaluated towards hydrogenation of cinnamaldehyde in liquid phase. The effect of various reaction parameters such as temperature, hydrogen pressure, solvents, and amount of catalyst and time on stream on conversion and selectivity were studied and the results are discussed. The studies revealed that noble metal intercalated/impregnated clay catalysts were very effective in hydrogenation reactions as they showed significant conversion and selectivity. Comparison of catalytic activity made with the impregnated catalysts showed that the intercalated catalysts were better than impregnated catalysts in terms of conversion and selectivity.
About the Authors
G. D. Manikandan
Advanced Ceramics and Nanotechnology Laboratory, Department of Materials Engineering, Faculty of Engineering, University of Concepcion, Concepcion, Chile
Catalysis Laboratory, Department of Chemical Engineering, A.C. College of Technology, Anna University, Chennai – 600 025, India
Russian Federation
Russian Federation
Ph.D., Post Doctorate Researcher, Advanced Ceramics and Nanotechnology Laboratory, Department of Materials Engineering, Faculty of Engineering, University of Concepcion, Concepcion, Chile. Catalysis Laboratory, Department of Chemical Engineering, A.C. College of Technology, Anna University, Chennai – 600 025, India. Phone: 0056-41-2203664
R. V. Mangalaraja
Advanced Ceramics and Nanotechnology Laboratory, Department of Materials Engineering, Faculty of Engineering, University of Concepcion, Concepcion, Chile
Russian Federation
Russian Federation
Ph.D., Associate Professor, Advanced Ceramics and Nanotechnology Laboratory, Department of Materials Engineering, Faculty of Engineering, University of Concepcion, Concepcion, Chile. Phone: 0056-41-2207389
S. Ananthakumar
Materials and Minerals Division, National Institute for Interdisciplinary Science and Technology (NIIST), CSIR, Trivandrum, India
Russian Federation
Russian Federation
Ph.D., Scientist, Materials and Minerals Division, National Institute for Interdisciplinary Science and Technology (NIIST), CSIR, Trivandrum, India. Phone: 0091-471-2515289
T. Sivakumar
Catalysis Laboratory, Department of Chemical Engineering, A.C. College of Technology, Anna University, Chennai – 600 025, India
Russian Federation
Russian Federation
Ph.D., Assistant Professor, Catalysis Laboratory, Department of Chemical Engineering, A.C. College of Technology, Anna University, Chennai – 600 025, India. Phone: 0091-44-44159636
References
1. C.M.P. Cientifica, Nano Catalysis and the Energy markets. 2002. Madrid, Spain.
2. Liu Z., Wang C., Liu Z., Lu J. // Appl. Catal. A: Gen. 344 (2008) 114.
3. Ying B., Jiajian P., Yingqian H., Jiayun L., Huayu Q., Guoqiao L. // Chinese Journal of Chemical Engineering, 17(6) (2009) 1038.
4. Li H., Zhu Z., Li H., Li P., Zhou X. // Journal of Colloid and Interface Science 349 (2010) 613.
5. Ribeiro Nielson F.P., Mendes Fabiana M.T., Perez Carlos A.C., Souza Mariana M.V.M., Martin S. // Appl. Catal. A: Gen. 347 (2008) 62.
6. Navarro R., Pawelec B., Fierro J.L.G., Vasudevan P.T., Cambra J.F., Guemez M.B., Arias P.L. // Fuel Processing Technology 61 (1999) 73.
7. Shu Y., Ichikawa M. // Catal. Today 71 (2001) 55.
8. Chmielarz L., Kusґtrowski P., Michalik M., Dudek B., Piwowarska Z., Dziembaj R. // Catal. Today 137 (2008) 242.
9. Kalpesh B.S., Hasmukh A.P., Parimal A.P., Bahadur P., Bajaj H.C., Jasra R.V. // Applied Clay Science 42 (2009) 386.
10. Maki-Arvela P., Hajek J., Salmi T., Yu M.D. // Appl. Catal. A. 292 (2005) 1.
11. Singh U.K., Vannice M.A. // Appl. Catal. A. 213 (2001) 1.
12. Rolison D.R. Nanomaterials: Synthesis, properties and application. Edelstein A.S., Cammarata R.C. (Eds.). Institute of Physics Publishing, Bristol (1996).
13. Malyala R.V., Rode C.V., Arai M., Hegde S.G., Chaudhari R.V. // Appl. Catal. A, 193, 1–2 (2000) 71.
14. Melendrez R., A. Alarcon Angel G.D., R. Gomez React. Kinet. // Catal. Lett. 2000, 70, 1, 113.
15. Hajek J., Kumar N., Maki-Arvela P., Salmi T., Murzin D.Y., Paseka I., Heikkila T., Laine E., Laukkanen P., Vayrynen J. // Appl. Catal. A, 251, 2 (2003) 385.
16. Lashdaf M., Tiitta M., Venalainen T., Sterholm H.O., Krause A.O.I. // Catal. Lett. 94, 1—2, (2004) 7.
17. Chatterjee M., Iwasaki T., Onodera Y., Nagase T. // Catal. Lett. 61, 3—4 (1999) 199.
18. Chatterjee M., Ikushima Y., Zhao F.Y. // Catal. Lett., 82, 1—2, (2002) 141.
19. Chatterjee M., Iwasaki T., Onodera Y., Hayashi H., Ikushima Y., Nasage T., Ebina T. // Appl. Clay Sci., 25, 3—4 (2004) 195.
20. Szollosi G., Torok B., Baranyi L., Bartok M. // J. Catal. 179, 2 (1998) 619.
21. Reyes P., Rojas H., Pecchi G., Fierro J.L.G. // J. Mol. Catal. A: Chem. 179, 1—2 (2002) 293.
22. Sivakumar T., Mori T., Kubo J., Morikawa Y. // Chem. Lett. 30, 9 (2001) 860.
23. Sivakumar T., Krithiga T., Shanthi K., Mori T., Kubo J., Morikawa Y. // J. Mol. Catal. A., 223, 1—2 (2004) 185.
24. Bachiller-Baeza B., Rodrіguez I., Guerrero-Ruiz A. // Appl. Catal. A, 205, 1—2 (2001) 227.
25. Consonni M., Jokic D., Murzin D.Y., Touroude R.J. // J. Catal. 188, 1 (1999) 165.
26. Milone C., Tropeano M.L., Gulino G., Neri G., Ingoglia R., Galvagno S. // Chem. Commun. 8 (2002) 868.
27. Okumura M., Akita T., Haruta M. // Catal. Today, 74, 3—4 (2002) 265.
28. Silva A.M., Santos O.A.A., Mendes M.J., Jordao E., Fraga M.A. // Appl. Catal. A 241, 1—2 (2003) 155.
29. Kijenski J., Winiarek P., Paryjczak T., Lewicki A., Mikołajska A. // Appl. Catal. A, 233, 1—2 (2002) 171.
30. Recchia S., Rossi C., Poli N., Fusi A., Sordelli L., Psaro R. //J. Catal. 184, 1, (1999) 1.
31. Klabunde K.J., Mulukutta R.S. Nanoscale materials in chemistry. 2001. Ed. By Klabunde K.J., John Wiley & Sons, Inc., New York, p. 223.
32. Mohr C., Claus P. // Sci. Progress, 84, 4 (2001) 311.
33. Bauer K., Garbe D. Common fragrance and flavour materials. 1985. VCH, Weinheim.
34. Gallezot P., Fendler G., Richard D. // Catalysis of organic reactions. 1991. Pascoe W. (Ed.,), Marcel Dekker, New York, p. 1.
35. Bartok M., Molnar A. The chemistry of double bonded functional groups, Supplement A3, 1997, Patai S., Ed., Wiley, New York, p. 843.
36. Coq B., Figueras F. // Coord. Chem. Rev., 178—180, 2 (1998) 1753.
37. Smith G.V., Notheisz F. Heterogeneous catalysis in organic chemistry. 1999. Academic Press, London, p. 58.
38. Lashdaf M., Krause A.O.I., Lindblad M., Tiitta M., Venalainen T. // Appl. Catal. A, 241, 1—2 (2003) 65.
39. Ryndin Y.A., Santini C.C., Prat D., Basset J.M. // J. Catal. 190, 1—2 (2000) 364.
40. Toshima N., Takahashi T. // Bulletin Chemical Society of Japan, 65 (1992) 400.
41. Kiraly Z., Veisz B., Mastalir A., Razga Z., Dekany I. // Chem. Commun. (1999) 1925.
42. Kiraly Z., Veisz B., Mastalir A., Kofarago G. Langmuir, 17 (2001) 5381.
43. Duff D.G., Edwards P.P., Johnson B.F.G. // Journal Physical Chemistry, 99, 43, (1995) 15934.
44. Hahakura S., Isoda S., Ogawa T., Moriguchi S., Kobayashi T.J. // Cryst. Growth, 237–239, 3 (2002) 1942.
45. Abid M.R., Touroude R. // Catal. Lett. 69, 3—4 (2000) 139.
46. Englisch M., Jentys A., Lercher J.A. // J. Catal. 166 (1997) 25.
47. Giroir-Fendler A., Richard D., Gallezot P. // Studies in Surface Science and catalysis, 41 (1988) 171.
48. Satagopan V., Chandalia S.B. // J. Chem. Technol. Biotechnol. 60, 1 (1994) 17.
49. Zhang L., Winterbottom J.M., Boyes A.P., Raymahasay S. // J. Chem. Technol. Biotechnol. 72, 3 (1998) 264.
50. Von Arx M., Mallat T., Baiker A.J. // J. Mol. Catal. A: Chem. 148, 1–2 (1999) 275.
51. Singh U.K., Vannice M.A. // J. Catal. 199 (2001) 73.
52. Hajek J., Kumar N., Maki-Arvela P., Salmi T., Murzin D.Y. // J. Mol. Catal. A: Chem. 217 (2004) 145.
Review
For citations:
Manikandan G.D., Mangalaraja R.V., Ananthakumar S., Sivakumar T. SYNTHESIS OF METAL INTERCALATED CLAY CATALYSTS FOR SELECTIVE HYDROGENATION REACTIONS. Kataliz v promyshlennosti. 2012;(1):11-26. (In Russ.)
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