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Acid activation as a method to control the catalytic properties of montmorillonite in the synthesis of solketal from glycerol and acetone
https://doi.org/10.18412/1816-0387-2022-1-57-66
Abstract
The effect of acid activation using 0.125–0.5 mol/l Н2SO4, HCl and HNO3 on the physicochemical and catalytic properties of natural clay (95 % montmorillonite, Mukhartalinsk deposit) was investigated. The rate and selectivity of the solketal (2,2-dimethyl-4-hydroxymethyl-1,3-dioxolane) synthesis from glycerol and acetone were shown to depend on the concentration and type of the acid. The reaction rate and the yield of solketal increase with increasing concentration of the acid, which is consistent with the growth in the amount of Broensted sites. As the surface acidity increases, the efficiency of the system increases in the series MM/HCl > MM/HNO3 > MM/H2SO4.
About the Authors
O. N. Kovalenko
Boreskov Institute of Catalysis SB RAS, Novosibirsk
Russian Federation
Russian Federation
I. I. Simentsova
Boreskov Institute of Catalysis SB RAS, Novosibirsk
Russian Federation
Russian Federation
V. N. Panchenko
Boreskov Institute of Catalysis SB RAS, Novosibirsk; Novosibirsk State Technical University
Russian Federation
Russian Federation
M. N. Timofeeva
Boreskov Institute of Catalysis SB RAS, Novosibirsk; Novosibirsk State Technical University
Russian Federation
Russian Federation
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Review
For citations:
Kovalenko O.N., Simentsova I.I., Panchenko V.N., Timofeeva M.N. Acid activation as a method to control the catalytic properties of montmorillonite in the synthesis of solketal from glycerol and acetone. Kataliz v promyshlennosti. 2022;22(1):57-66. (In Russ.) https://doi.org/10.18412/1816-0387-2022-1-57-66
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