

Catalytic conversion of flame gas on Rh catalysts with subsequent direct monetization
https://doi.org/10.18412/1816-0387-2022-4-51-57
Abstract
The paper considers technical feasibility of the direct monetization of casing-head gas, which is being flared now. The proposed approach is based on the technology of low-temperature steam conversion of hydrocarbons, which makes it possible to enhance the quality of flame gases to comply with the requirements on a fuel for gas-piston and gas-turbine power stations. The synthesis and performance of advanced rhodium catalysts for the low-temperature steam conversion of flame gas are discussed. For such catalysts, mixed cerium-zirconium oxides are most promising as the supports. The indicated catalysts have some advantages over the well-studied nickel catalysts in the low-temperature steam conversion of hydrocarbons.
About the Authors
A. S. UrlukovRussian Federation
S. I. Uskov
Russian Federation
D. I. Potemkin
Russian Federation
P. V. Snytnikov
Russian Federation
References
1. de Vries A. // Joule. 2018. V. 2. I. 5. P. 801–805. https://doi.org/10.1016/j.joule.2018.04.016
2. Krause M.J., Tolaymat T. // Nat. Sustain. 2018. V. 1. P. 711–718 https://doi.org/10.1038/s41893-018-0152-7
3. de Vries A. // Joule. 2019. V. 3. I. 4. P. 893–898. https://doi.org/10.1016/j.joule.2019.02.007
4. Köhler S., Pizzol M. // Environ. Sci. Technol. 2019. V. 53. I. 23. P. 13598–13606. https://doi.org/10.1021/acs.est.9b05687
5. Stoll C., Klaaßen L., Gallersdörfer U. // Joule. 2019. V. 3. I. 7. P. 1647– 1661. https://doi.org/10.1016/j.joule.2019.05.012
6. http://bitcoinenergyconsumption.com
7. Снытников П.В., Потемкин Д.И, Усков С.И., Курочкин А.В., Кириллов В.А., Собянин В.А. // Катализ в промышленности. 2018. Т. 18. № 2. С. 16–32. https://doi.org/10.18412/1816-0387-2018-2-16-32
8. https://www.worldbank.org/en/news/press-release/2019/06/12/increased-shale-oil-production-and-political-conflict-contribute-to-increase-in-global-gas-flaring
9. https://minenergo.gov.ru/system/download-pdf/18288/120837
10. https://ac.gov.ru/uploads/2-Publications/TEK_annual/TEK.2019.pdf
11. http://www-wds.worldbank.org/external/default/WDSContentServer/WDSP/IB/2012/07/24/000333038_20120724022013/Rendered/PDF/713820WP0P10230C00pfc0energy0report.pdf
12. Савченко В.И., Арутюнов В.С., Фокин И.Г., Никитин А.В., Седов И.В. // Нефтехимия. 2017. Т.57. № 2. С.177–185.
13. Арутюнов В.С., Савченко В.И., Седов И.В., Никитин А.В., Магомедов Р.Н., Прошина А.Ю. // Успехи химии. 2017. № 86 (1). С. 47–74. http://dx.doi.org/10.1070/RCR4648
14. Усков С.И., Еникеева Л.В., Потемкин Д.И., Беляев В.Д., Снытников П.В., Губайдуллин И.М., Кириллов В.А., Собянин В.А. // Катализ в промышленности. 2017. Т. 17. № 1. С. 11–17. https://doi.org/10.18412/1816-0387-2017-1-11-17
15. Uskov S.I., Potemkin D.I., Shigarov A.B., Snytnikov P.V., Kirillov V.A., Sobyanin V.A. // Chem. Eng. J. 2019. V. 368. P. 533–540. https://doi.org/10.1016/j.cej.2019.02.189
16. Trimm D.L. // Cat. Today. 1997. V. 37. I. 3. P. 233–238. https://doi.org/10.1016/S0920-5861(97)00014-X
17. ГОСТ-5542–87 Газы горючие природные для промышленного и коммунально-бытового назначения. Технические условия. М.: Стандартинформ, 2015. 11 с.
Review
For citations:
Urlukov A.S., Uskov S.I., Potemkin D.I., Snytnikov P.V. Catalytic conversion of flame gas on Rh catalysts with subsequent direct monetization. Kataliz v promyshlennosti. 2022;22(4):51-57. (In Russ.) https://doi.org/10.18412/1816-0387-2022-4-51-57