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A Single-Step Hydrolysis-Reduction of Potato Starch to Sorbite in the Presence of Bifunctional Catalyst Ru/Сs3HSiW12O40
https://doi.org/10.18412/1816-0387-2022-5-70-82
Abstract
It was shown that sorbite can be obtained from potato starch by its single-step hydrolysis-reduction in the presence of bifunctional catalysts 0.3–3 wt.%Ru/Cs3HSiW12O40 (Ru/Cs-HPA). Most efficient was the catalyst containing 1 wt.%Ru; this is related to the optimal concentration ratio of Broensted and Lewis acid sites on the support surface and a high specific surface area. The reaction kinetics in the presence of 1%Ru/Сs-HPA was studied and the apparent activation energy of the starch hydrolysis-reduction to sorbite (80±8 kJ/mol) was determined. The experimental and literature data were used to propose a kinetic model of the process, which describes quite adequately the hydrolysisreduction of starch. In the presence of the catalyst with the optimal composition (1%Ru/Cs-HPA) at the optimal temperature (150 °С), the yield of sorbite achieved 88 mol.% (99 wt.%) for 3 hours of the reaction.
About the Authors
N. V. Gromov
Boreskov Institute of Catalysis SB RAS, Novosibirsk; Novosibirsk State Technical University
Russian Federation
Russian Federation
T. B. Medvedeva
Boreskov Institute of Catalysis SB RAS, Novosibirsk
Russian Federation
Russian Federation
V. N. Panchenko
Boreskov Institute of Catalysis SB RAS, Novosibirsk; Novosibirsk State Technical University
Russian Federation
Russian Federation
O. P. Taran
Boreskov Institute of Catalysis SB RAS, Novosibirsk; Institute of Chemistry and Chemical Technology SB RAS, Krasnoyarsk
Russian Federation
Russian Federation
M. N. Timofeeva
Boreskov Institute of Catalysis SB RAS, Novosibirsk; Novosibirsk State Technical University
Russian Federation
Russian Federation
V. N. Parmon
Boreskov Institute of Catalysis SB RAS, Novosibirsk
Russian Federation
Russian Federation
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For citations:
Gromov N.V., Medvedeva T.B., Panchenko V.N., Taran O.P., Timofeeva M.N., Parmon V.N. A Single-Step Hydrolysis-Reduction of Potato Starch to Sorbite in the Presence of Bifunctional Catalyst Ru/Сs3HSiW12O40. Kataliz v promyshlennosti. 2022;22(5):70-82. (In Russ.) https://doi.org/10.18412/1816-0387-2022-5-70-82
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