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Features of Deactivation and Regeneration of the Zeolite-Containing Cobalt Catalyst in a Fischer – Tropsch Synthesis Reactor
https://doi.org/10.18412/1816-0387-2022-6-16-29
Abstract
Endurance tests of the zeolite-containing cobalt catalyst for the Fischer – Tropsch synthesis were carried out in reactor tubes of the size comparable with those used in industrial reactors. During the tests (3000 h), the catalyst activity decreased by 13 %. Deactivation of the zeolite-containing cobalt catalyst was shown to occur due to agglomeration of cobalt clusters and formation of amorphous carbon on their surface. A method of decreasing the catalyst deactivation rate and two methods of the catalyst regeneration were proposed. The method of redox regeneration of zeolite-containing cobalt catalysts allows restoring 98 % of their initial activity.
About the Authors
A. S. Gorshkov
INFRA Ltd, Moscow
Russian Federation
Russian Federation
L. V. Sineva
INFRA Ltd, Moscow; Technological Institute for Superhard and Novel Carbon Materials (TISNCM), Moscow
Russian Federation
Russian Federation
K. O. Gryaznov
Technological Institute for Superhard and Novel Carbon Materials (TISNCM), Moscow
Russian Federation
Russian Federation
E. Yu. Asalieva
INFRA Ltd, Moscow; Technological Institute for Superhard and Novel Carbon Materials (TISNCM), Moscow
Russian Federation
Russian Federation
V. Z. Mordkovich
INFRA Ltd, Moscow; Technological Institute for Superhard and Novel Carbon Materials (TISNCM), Moscow
Russian Federation
Russian Federation
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Review
For citations:
Gorshkov A.S., Sineva L.V., Gryaznov K.O., Asalieva E.Yu., Mordkovich V.Z. Features of Deactivation and Regeneration of the Zeolite-Containing Cobalt Catalyst in a Fischer – Tropsch Synthesis Reactor. Kataliz v promyshlennosti. 2022;22(6):16-29. (In Russ.) https://doi.org/10.18412/1816-0387-2022-6-16-29
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