Solid-Phase Synthesis of Nickel-Molybdenum Catalysts for Metathesis of Propylene under Mechanical Action

The solid-phase synthesis of model aluminum-molybdenum (Al-Mo) and aluminum-nickel-molybdenum (Al-Ni-Mo) compositions constituting the catalysts for metathesis of propylene was carried out under mechanical action. The structure of model Al-Mo and Al-Ni-Mo compositions was studied using X-ray diffraction analysis, high-resolution transmission electron microscopy, infrared spectroscopy, and diffuse reflectance electron spectroscopy (UV-vis DRS). The latter method revealed the presence of isolated monomeric and oligomeric molybdate compounds in the model Al-Ni-Mo compositions. Granulated catalysts for metathesis were obtained by molding the model Al-Mo and Al-Ni-Mo compositions with aluminum hydroxide followed by calcination. Most active in the metathesis of propylene was the aluminum-molybdenum catalyst containing 2.6 wt.% Ni, 13.0 wt.% Mo and 32.7 wt.% Al. At the process temperature of 200 °С, pressure 0.1 MPa, and weight space velocity of propylene 1 h^–1, the conversion of propylene on this catalyst reached 33.7 %, which makes the catalyst promising for practical application. Therewith, the weight fraction of ethylene in the reaction products was 17.5 %, and butenes – 71.3 %.

1. Mol J.C. // Journal of Molecular Catalysis A: Chemical. 2004. V. 213. P. 3945.

2. Кашковский В.И., Григорьев А.А. // Катализ и нефтехимия. 2006. № 14. С. 1–10.

3. Patent US 3431316, 1969.

4. Ivin K., Mol J. Metathesis and Metathesis Polymerization // Academic press, 1997.

5. Lwin S., Wachs I.E. // ACS Catal. 2014. V. 4. P. 2505–2520.

6. Fierro J.L.G., Mol J.C. Metal Oxides: Chemistry and Applications // Taylor & Francis, 2006.

7. Van Schalkwyk C., Spamer A., Moodley D.J., Dube T., Reynhardt J., Botha J.M. // Applied Catalysis A: General. 2003. V. 255. P. 121–131.

8. Liu H., Huang S., Zhang L., Liu S., Xin W., Xu L. // Catalysis Communications. 2009. V. 10. P. 544–548.

9. Debecker D., Stoyanova M., Rodemerck U., Su B., Gaigneaux E., Leonard A. // Catalysis today. 2011. V. 169. P. 60–68.

10. Debecker D.P., Bouchmella K., Poleunis C., Eloy P., Bertrand P., Gaigneaux E.M., Mutin P.H. // Chem. Mater. 2009. V. 21. P. 2817–2824.

11. Topka P., Balcar H., Rathousky J., Zilkova, N., Verpoort, F., Cejka, J. // Microporous Mesoporous Mater. 2006. V. 96. P. 44–54.

12. Handzlik J. // Surf. Sci. 2007. V. 601. P. 2054–2065.

13. Aritani H., Fukuda O., Miyaji A., Hasegawa S. // Appl. Surf. Sci. 2001. V. 180. P. 261–269.

14. Zavoianu R., Soares Dias A.P.V., Pavel O.D., Angelescu E., Portela M.F. // Catalysis Communications. 2005. V. 6. P. 321–327.

15. Budukva S.V., Klimov O.V., Chesalov Y.A., Prosvirin I.P., Larina T.V., Noskov A.S. // Catalysis Letters. 2018. V. 148. P. 1525–1534.

16. Grunert W., Stakheev A.Yu., Feldhaus R., Anders K., Shpiro E.S., Minachev K.M. // Journal of Catalysis. 1992. V. 135. P. 287–299.

17. Samain L., der Jaworski A., Edén M., Ladd D.M., Seo D.-K., Garcia-Garcia F.J., Häussermann U. // Journal of Solid State Chemistry. 2014. V. 217. P. 1–8.

18. Masakuni Ozawa, Mareo Kimura, Akio Isogai. // Journal of the Less Common Metals. 1990. V. 162. P. 297–308.

19. Buelna G., Lin Y.S., Liu L.X., Litster J.D. // Ind. Eng. Chem. Res. 2003. V. 42. P. 442–447.

20. Bergwerff J.A., Visser T., Leliveld B.R.G., Rossenaar B.D., de Jong K.P., Weckhuysen B.M. // J. Am. Chem. Soc. 2004. V. 126. P. 14548–14556.

21. Oyerinde O.F., Weeks C.L., Anbar A.D., Spiro T.G. // Inorganica Chimica Acta. 2008. V. 361. P. 1000–1007.

22. Borg S., Liu W., Etschmann B., Tian Y., Brugger J. // Geochimicaet Cosmochimica Acta. 92 (2012) 292–307.

23. Lwin S., Wachs I.E. ACS Catal. 2014. V. 4. P. 2505−2520.

24. Debecker D.P., Stoyanova M., Rodemerck U., Eloy P., Léonard A., Su B.-L., Gaigneaux E.M. // J. Phys. Chem. C. 2010. V. 114. P. 6584–6590.

25. Drake T.L., Stair P.C. // Topics in Catalysis. 2017. V. 60. P. 1618-1630.

26. Braun S., Appel L.G., Camorim V.L., Schmal M. // J. Phys. Chem. B. 2000. V. 104. P. 6584–6590.

27. Debecker D.P., Stoyanova M., Rodemerck U., Gaigneaux E.M. // Studies in Surface Science and Catalysis. 2010. V. 175. P. 581–585.

28. Balcar H., Mishra D., Marceau E., Carrier X., Zilkova N., Bastl Z. // Applied Catalysis A: General. 2009. V. 359. P. 129–135.

29. Avvakumov G.V., Senna M., Kosova N.V. Soft Mechanochemical Synthesis: A Basis for New Chemical Technologies. Kluwer Academic Publishers, 2002.

30. Afonasenko T.N., Knyazheva O.A., Baklanova O.N., Gulyaeva T.I., Trenikhin M.V., Tsyrul'nikov P.G., Bulavchenko O.A., Tsybulya S.V. // Kinetics and Catalysis. 2014. V. 56. P. 359–368.

31. Duplyakin V.K., Baklanova O.N., Chirkova O.A., Antonicheva N.V., Arbuzov A.B., Voitenko N.N., Drozdov V.A., Likholobov V.A. Kinetics and Catalysis. 2010. V. 51. P. 126–130.

32. Knyazheva O.A., Baklanova O.N., Lavrenov A.V.,.Drozdov V.A., Leont'eva N.N., Trenikhin M.V., Arbuzov A.B., Likholobov V.A. // Kinetics and Catalysis. 2011. V. 52. P. 886–895.

33. Knyazheva O.A., Baklanova O.N., Lavrenov A.V., Drozdov V.A., Leont'eva N.N., Vasilevich A.V., Shilova A.V., Likholobov V.A. // Kinetics and Catalysis. 2014. V. 55. P. 121–129.

34. Paramzin S.M., Zolotovskii B.P., Buyanov R.A., Plyasova L.M., Novgorodova O.N. // Kinetics and Catalysis. 1991. V. 32. P. 452-455.

35. Yurchenko E.N., Detusheva L.G. // Journal of structural chemistry. 1982. V. 23. P. 706–713.

36. Tian H., Roberts C.A., Wachs I.E. // J. Phys. Chem. C. 2010. V. 114. P. 14110–14120.