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The effect of water-soluble polymers on the dynamics of carbon dioxide sorption by lime sorbents
https://doi.org/10.18412/1816-0387-2023-2-6-14
Abstract
The effect of water-soluble polymers with different structure on the sorption properties of nonregenerable lime sorbents of carbon dioxide was studied. It was found that the introduction of water-soluble polymers into the sorbents could either decrease or increase the protective power time of the sorbents. To explain the revealed regularities, pore structure of the sorbents was investigated, molecular-dynamic modeling of the carbon dioxide transport was performed, and CO2 diffusion coefficients in water-polymer solutions were calculated. The results of the modeling correlate with the sorption experiment data: a high dynamic sorption capacity of the sorbent is reached after adding a water-polymer medium with a high CO2 diffusion coefficient. The results obtained can be used both to optimize the systems for the recovery of carbon dioxide from gas mixtures and to intensify mass transfer in the systems intended for photo- and electrocatalytic conversion of CO2 to useful products.
About the Authors
V. S. Derevschikov
Boreskov Institute of Catalysis SB RAS, Novosibirsk
Russian Federation
Russian Federation
O. Yu. Selyutina
Voevodsky Institute of Chemical Kinetics and Combustion, Novosibirsk
Russian Federation
Russian Federation
References
1. Udara Willhelm Abeydeera L.H., Wadu Mesthrige J., Samarasinghalage T.I. // Sustainability. 2019. V. 11. № 14. P. 3972.
2. Ameyaw B., Yao L., Oppong A., Agyeman J.K. // Energy Policy. 2019. V. 130. P. 7–21.
3. Gao J., Hou H., Zhai Y., Woodward A., Vardoulakis S., Kovats S., Wilkinson P., Li L., Song X., Xu L., Meng B., Liu X., Wang J., Zhao J., Liu Q. // Environ. Pollut. 2018. V. 240. P. 683–698.
4. Fasihi M., Efimova O., Breyer C. // Journal of Cleaner Production. 2019. V. 224. P. 957–980.
5. Vega F., Baena-Moreno F.M., Gallego Fernández L.M., Portillo E., Navarrete B., Zhang Z. //Applied Energy. 2020. V. 260. P.114313.
6. Varghese A.M., Karanikolos G.N. // International Journal of Greenhouse Gas Control. 2020. V. 96. P.103005.
7. Lee J.Y., Park C.Y., Moon S.Y., Choi J.H., Chang B.J., Kim J.H. // J. Membr. Sci. 2019. V. 589. P. 117214.
8. Salih H.A., Pokhrel J., Reinalda D., AlNashf I., Khaleel M., Vega L.F., Karanikolos G.N., Abu Zahra M. // International Journal of Greenhouse Gas Control. 2021. V.110. P. 103415.
9. Yu W., Wang T., Park A.A., Fang M. // Nanoscale. 2019. V. 11. № 37. P. 17137–17156.
10. Devendiran D.K., Amirtham V.A. // Renewable Sustainable Energy Rev. 2016. V.60. P. 21–40.
11. Kuehnel, M. F., Orchard, Katherine L., Dalle K. E., Reisner E. // J. Am. Chem. Soc. 2017. V. 139. № 21. P. 7217–7223.
12. Resasco J, Bell A.T. // Trends in Chemistry. 2020. V. 2. № 9. P. 825-836.
13. Olmeda B., Villén L., Cruz A., Orellana G., Perez-Gil J. // Biochimica et Biophysica Acta (BBA) – Biomembranes. 2010. V. 1798. № 6. P. 1281–1284.
14. Derevschikov V.S., Kazakova E.D., Yatsenko D.A., Veselovskaya J.V. // Separation Science and Technology. 2021. V.56. P. 485–497.
15. Деревщиков В.С., Казакова Е.Д. // Катализ в промышленности. 2019. Т. 19. С. 258–264.
16. Гладышев Н.Ф., Гладышева Т.В., Путин Б.В., Путин С.Б. Известковые поглотители нового поколения. М.: Изд. дом «Спектр», 2012. 136 с.
17. Гладышева Т.В., Гладышев Н.Ф., Дворецкий С.И., Суворова Ю.А. Известковые хемосорбенты. Получение. Свойства. Применение. М.: Изд. дом «Спектр», 2015. 184 с.
18. Юркевич А.А., Ивахнюк Г.К., Федоров Н.Ф. Технологические основы производства химических компонентов систем жизнеобеспечения. СПб.: Менделеев, 2014. 368 с.
19. Ивахнюк Г.К., Кожина Т.Г., Самонин В.В., Федоров Н.Ф., Слесарева М.О. // Журнал прикладной химии. 1991. Т. 64. С. 578–582.
20. Самонин В.В., Кругликова И.В., Федоров Н.Ф. // Журнал прикладной химии. 1994. Т. 67. С. 300–302.
21. Корешонкова М.О., Ивахнюк Г.К., Крылов В.К., Малинин В.Р. // Журнал прикладной химии. 1997. Т. 70. С. 1743–1744.
22. Murray J.M., Renfrew C.W., Bedi A., McCrystal C.B., Jones D.S., Fee J.P. // Anesthesiology. 1999. V. 91. № 5. P. 1342–1348.
23. Деревщиков В.С., Казакова Е.Д., Веселовская Ж.В., Яценко Д.А., Козлов Д.В. // Журнал физической химии. 2021. Т. 95. № 7. С. 1095–1100.
24. Lowell S., Shields J.E., Thomas M.A., Thommes M. Characterization of Porous Solids and Powders: Surface Area, Pore Size and Density. New York: Springer, 2004. 363 p.
25. Oostenbrink C., Villa A., Mark A.E., Van Gunsteren W.F. // Journal of Computational Chemistry. 2004. Vol. 25. № 13. P. 1656- 1676.
26. Essmann U., Perera L., Berkowitz M.L., Darden T., Lee H., Pedersen L.G. // J. Chem. Phys. 1995. V. 103. № 19. P. 8577–8593.
27. Parrinello M., Rahman A. // J. Appl. Phys. 1998. V. 52. P. 7182.
28. Hoover W.G. // Phys. Rev. A. 1985. V. 31. P. 1695.
29. ALOthman Z.A. // Materials. 2012. V. 5. P. 2874–2902. doi:10.3390/ma5122874.
30. Rouquerol J., Avnir D., Fairbridge C.W., Everett D.H., Haynes J.H., Penicone N., Ramsay J.D.F., Sing K.S.W., Unger K.K. // Pure Appl. Chem. 1994. V. 66. № 8. P. 1739–1758.
31. Ланге К.Р. Поверхностно-активные вещества: синтез, свойства, анализ, применение. СПб.: Профессия, 2007. 240 c.
32. Данквертс П.В. Газожидкостные реакции. М.: Химия, 1973. 296 с.
Review
For citations:
Derevschikov V.S., Selyutina O.Yu. The effect of water-soluble polymers on the dynamics of carbon dioxide sorption by lime sorbents. Kataliz v promyshlennosti. 2023;23(2):6-14. (In Russ.) https://doi.org/10.18412/1816-0387-2023-2-6-14
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