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Influence of the Fe/Cr ratio on the catalytic activity of FeCr/C catalysts in the process of oxidative dehydrogenation of ethane
https://doi.org/10.18412/1816-0387-2024-4-60-64
Abstract
The influence of the ratio of active components (Fe and Cr) on the catalytic activity of FeCr/C catalysts in the oxidative dehydrogenation of ethane with CO2 was analyzed. The best results were achieved on the 2Fe3.7Cr/C catalyst, in which the Fe:Cr ratio corresponds to the stoichiometry of iron (II) chromite – FeCr2O4. The physicochemical characteristics of the prepared catalysts were obtained and analyzed (XRF, XPS, magnetometric method). From the totality of the data obtained, we can assume the presence of an iron (II) chromite phase.
About the Authors
I. I. Mishanin
N.D. Zelinsky Institute of Organic Chemistry RAS, Moscow
Russian Federation
Russian Federation
T. V. Bogdan
Moscow State University. M.V. Lomonosov, Faculty of Chemistry RAS, Moscow
Russian Federation
Russian Federation
T. V. Fedoseev
N.D. Zelinsky Institute of Organic Chemistry RAS, Moscow
Russian Federation
Russian Federation
M. A. Skiba
Higher Chemical College of the RAS (VCC RAS), Moscow
Russian Federation
Russian Federation
P. A. Chernavsky
Moscow State University. M.V. Lomonosov, Faculty of Chemistry RAS, Moscow
Russian Federation
Russian Federation
A. E. Koklin
N.D. Zelinsky Institute of Organic Chemistry RAS, Moscow
Russian Federation
Russian Federation
K. I. Maslakov
Moscow State University. M.V. Lomonosov, Faculty of Chemistry RAS, Moscow
Russian Federation
Russian Federation
V. I. Bogdan
N.D. Zelinsky Institute of Organic Chemistry RAS, Moscow
Russian Federation
Russian Federation
References
1. M.A. Artsiusheuski, R. Verel, J.A. Bokhoven, V.L. Sushkevich // Angew. Chem.Int. Ed. 2023. V.62. e2023091.
2. https://doi.org/10.1002/anie.202309180
3. M.A. Tedeeva, A.L. Kustov, P.V. Pribytkov, G.I. Kapustin, A.V. Leonov, O.P. Tkachenko, O.B. Tursunov, N.D. Evdokimenko, L.M. Kustov // Fuel. 2022. V. 313. P. 122698.
4. https://doi.org/10.1016/j.fuel.2021.122698
5. S. A. Chernyak, M. Corda, J. P. Dath, V. V. Ordomsky, A.Y. Khodakov // Chem. Soc. Rev. 2022. V.51. P. 7994-8044.
6. https://doi.org/10.1039/D1CS01036K
7. Igonina M., Tedeeva M., Kalmykov K., Kapustin G., Nissenbaum V., Mishin I., Pribytkov P., Dunaev S., Kustov L., Kustov A. // Catalysts. 2023. V.13. P.1-15.
8. https://doi.org/10.3390/catal13050906
9. Mashkin M.Y., Tedeeva M.A., Fedorova A.A., Fatula E.R., Egorov A.V., Dvoryak S.V., Maslakov K.I., Knotko A.V., Baranchikov A.E., Kapustin G.I., Petukhov D.I., Shatalova T.B., Morozov I.V., Kustov L.M., Kustov A.L. // J. Chem. Technol. Biotechnol. 2023. V. 98. P.1247-1259.
10. https://doi.org/10.1002/jctb.7339
11. Y Cao, X Luo, H Yu, F Peng, H Wang, G Ning // Catal. Sci. Technol. 2013. V. 3. P. 2654-2660
12. https://doi.org/10.1039/C3CY00256J
13. Guang Xiong, Jiannan Sang // J. Mol. Catal. A. 2014. V. 392. P. 315-320.
14. https://doi.org/10.1016/j.molcata.2014.05.037.
15. Zhu J., Holmen A., Chen D. // ChemCatChem. 2013. V. 5. P. 378.
16. https://doi.org/10.1002/cctc.201200471
17. Chernyak S.A., Kustov A.L., Stolbov D.N., Tedeeva M.A., Isaikina O.Ya, Maslakov K.I., Usoltseva N.V., Savilov S.V. // Appl. Surf. Sci. 2022. V. 578. 152099.
18. https://doi.org/10.1016/j.apsusc.2021.152099
19. I. I. Mishanin, T.V. Bogdan, A.E. Koklin, V.I. Bogdan // Chem. Eng. J. 2022. V. 446. P. 137184.
20. https://doi.org/10.1016/j.cej.2022.137184
21. I.I. Mishanin, T.V. Bogdan, A.V. Smirnov, P.A. Chernavskii, N.N. Kuznetsova, V.I. Bogdan // Mendeleev Commun. 2023. V. 33. P. 422-424.
22. https://doi.org/10.1016/j.mencom.2023.04.039
23. Kim O.A., Bogdan T.V., Koklin A.E., Bogdan V.I. // Rus. J. Phys.Chem. B. 2022. V. 16(7), P. 1218–1220.
24. https://doi.org/10.1134/S1990793122070107
25. Lei Liu, Qing-Fang Deng, Bao Agula, Tie-Zhen Ren, Yu-Ping Liu, Bao Zhaorigetu, Zhong-Yong Yuan // Catal. Today. 2012. V. 186. P.35-41.
26. https://doi.org/10.1016/j.cattod.2011.08.022
27. Adnan Hayel Ali, Eduardo H. Wanderlind, Gizelle I. Almerindo // Renew. Energ. 2024. V.220.119656.
28. https://doi.org/10.1016/j.renene.2023.119656
29. Liu, L., Deng, Q.-F., Liu, Y.-P., Ren, T.-Z., & Yuan, Z.-Y. // Catal. Commun. 2011. V. 16. P. 81–85.
30. https://doi.org/10.1016/j.catcom.2011.09.005
31. Hu, Z.-P., Zhao, H., Chen, C., & Yuan, Z.-Y. // Catal. Today. 2018. V. 316. P. 214-222.
32. https://doi.org/10.1016/j.cattod.2018.01.010
33. I.I. Mishanin, V.I. Bogdan // Mendeleev Commun. 2020. V. 30. P. 359.
34. https://doi.org/10.1016/j.mencom.2020.05.033
35. Lokteva E.S., Shishova V.V., Maslakov K.I., Golubina E.V., Kharlanov A.N., Rodin I.A., Vokuev M.F., Filimonov D.S., Tolkachev N.N. // Applied Surface Science. 2023 V. 613 P. 156022. https://doi.org/10.1016/j.apsusc.2022.156022
36. Максимочкин В.И., Губайдуллин Р.Р., Гареева М. Я. // Вестник Московского университета. Серия 3. Физика. Астрономия. 2013. №3. C. 64-70.
37. URL:https://cyberleninka.ru/article/n/magnitnye-svoystva-i-struktura-hromitov-sostava-fe2-xmgxcro4 (дата обращения: 30.11.2023).
Review
For citations:
Mishanin I.I., Bogdan T.V., Fedoseev T.V., Skiba M.A., Chernavsky P.A., Koklin A.E., Maslakov K.I., Bogdan V.I. Influence of the Fe/Cr ratio on the catalytic activity of FeCr/C catalysts in the process of oxidative dehydrogenation of ethane. Kataliz v promyshlennosti. 2024;24(4):60-64. (In Russ.) https://doi.org/10.18412/1816-0387-2024-4-60-64
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