Guaiacol hydrodeoxygenation in the presence of Ni-containing catalysts
Abstract
The testing of series of Ni-containing catalysts were investigated in the reaction of guaiacol hydrodeoxygenation. Guaiacol is a model compound products of fast biomass pyrolysis. The reaction was carried out in an autoclave at temperature 320 °C and hydrogen pressure 17 MPa. The main products of guaiacol hydrodeoxygenation were cyclohexane, 1- methylcyclohexanediol-1,2 and cyclohexanone (products of aromatic ring reduction). Scheme of transformations of guaiacol, which explains the formation of the main products, is offered. The most active are Ni-containing catalysts on SiO2 and SiO2–ZrO2, prepared by the sol-gel method. According to XRD and EM, high activity of these catalysts is due to high content of active component (nickel) in the dispersed form of restored films on the surface of silicate structures. There is assumption about the prospects of the proposed catalysts in the upgrading of biomass fast pyrolysis products for fuel hydrocarbon production.
About the Authors
M. V. Bykova
Boreskov Institute of Catalysis SB RAS, Novosibirsk
Russian Federation
Russian Federation
O. A. Bulavchenko
Boreskov Institute of Catalysis SB RAS, Novosibirsk
Russian Federation
Russian Federation
D. Yu. Ermakov
Boreskov Institute of Catalysis SB RAS, Novosibirsk
Russian Federation
Russian Federation
M. Yu. Lebedev
Boreskov Institute of Catalysis SB RAS, Novosibirsk
Russian Federation
Russian Federation
V. A. Yakovlev
Boreskov Institute of Catalysis SB RAS, Novosibirsk
Russian Federation
Russian Federation
V. N. Parmon
Boreskov Institute of Catalysis SB RAS, Novosibirsk
Russian Federation
Russian Federation
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Review
For citations:
Bykova M.V., Bulavchenko O.A., Ermakov D.Yu., Lebedev M.Yu., Yakovlev V.A., Parmon V.N. Guaiacol hydrodeoxygenation in the presence of Ni-containing catalysts. Kataliz v promyshlennosti. 2010;(5):45-52. (In Russ.)
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