Membrane systems for recovery of gaseous energy utilities from biomass treatment products
Abstract
One of the prospective technologies of the production of energy carriers from renewable raw material is biological conversion of organic wastes. The products of this conversion are gaseous (biogas, biohydrogen) or liquid mixtures containing methane and hydrogen or lover alcohols respectively. Traditional membrane systems are considered and original gas-liquid membrane contactors (MCs) are proposed as prospective systems for energy carriers recovery (methane, hydrogen) from gas mixtures. MCs do not demand preliminary compression of initial gas mixture. Technical degree methane (> 95 %) can be obtained after the separation stage of biogas. Low energy consumable membrane system is created on the basis of developments of TIPS RAS in cooperation with experts-microbiologists and specialists in mechanical engineering. Developed MCs are based on non-porous high permeable asymmetric polyvinyltrimethylsilane (PVTMS) membrane which shows the permeance level of CO2 more than 1500 L/(m2·h·atm) that completely satisfy requirements of high permeable and sterile barrier. Composite membranes based on glassy polymer with high free volume – polytrimethylsililpropyne (PTMSP) which are already produced in laboratory scale are considered as prospective membranes for MCs. Application of such membrane methods as pervaporation and membrane recovery of organic component from vapour phase is also perspective for recovery of liquid energy carriers (bioalcohols) from diluted water-organic solutions (range of organic substances concentrations is 1–7 %) obtained by biofermentation. It is shown that organophillic PTMSP membranes can be successfully applied for processes of continuous recovery of liquid energy carriers from products of biomass treatment.
About the Authors
V. V. Tepliakov
Institute of Petrochemical Synthesis. A.V. Topchieva RAS, Moscow
Russian Federation
Russian Federation
V. S. Khotimskiy
Institute of Petrochemical Synthesis. A.V. Topchieva RAS, Moscow
Russian Federation
Russian Federation
A. V. Yakovlev
Institute of Petrochemical Synthesis. A.V. Topchieva RAS, Moscow
Russian Federation
Russian Federation
M. G. Shalygin
Institute of Petrochemical Synthesis. A.V. Topchieva RAS, Moscow
Russian Federation
Russian Federation
L. G. Gasanоva
Institute of Petrochemical Synthesis. A.V. Topchieva RAS, Moscow
Russian Federation
Russian Federation
V. B. Zenkevich
NPC Biotest, Kirishi
Russian Federation
Russian Federation
A. I. Netrusov
Department of Microbiology, Faculty of Biology, Moscow State University. M.V. Lomonosova, Moscow
Russian Federation
Russian Federation
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Review
For citations:
Tepliakov V.V., Khotimskiy V.S., Yakovlev A.V., Shalygin M.G., Gasanоva L.G., Zenkevich V.B., Netrusov A.I. Membrane systems for recovery of gaseous energy utilities from biomass treatment products. Kataliz v promyshlennosti. 2010;(5):95-103. (In Russ.)
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