Influence of process conditions on the product ratio of liquidphase oxidation of normal hydrocarbons C10–C13 hydrogen peroxide on titanium-containing catalyst (TS-1)
https://doi.org/10.18412/1816-0387-2010-3-
Abstract
Strict economic and environmental require to create a new technologies for producing fatty alcohols, which would replace the existing processes, leading to the formation of large quantities of waste, and eliminate or significantly reduce their disadvantages. The most interest in this area are methods based on the using of environmentally friendly oxidant – hydrogen peroxide. The influence of process conditions (initial molar ratio of reactants and temperature) on the ratio of products (alcohols and ketones) liquid-phase oxidation of normal hydrocarbons С10–С13 aqueous solutions of H2O2 on heterogeneous catalyst silikalite titanium (TS-1) is studied. The main reaction products are alcohols and ketones, and the ratio of alcohol in the reaction mass decreases with increasing temperature and decreasing the molar ratio of hydrocarbon/hydrogen peroxide.
About the Authors
S. M. Danov
Dzerzhinsky Polytechnic Institute of the Nizhny Novgorod State Technical University named after R.E. Alekseev
Russian Federation
Russian Federation
A. E. Fedosov
Dzerzhinsky Polytechnic Institute of the Nizhny Novgorod State Technical University named after R.E. Alekseev
Russian Federation
Russian Federation
A. V. Lunin
Dzerzhinsky Polytechnic Institute of the Nizhny Novgorod State Technical University named after R.E. Alekseev
Russian Federation
Russian Federation
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Review
For citations:
Danov S.M., Fedosov A.E., Lunin A.V. Influence of process conditions on the product ratio of liquidphase oxidation of normal hydrocarbons C10–C13 hydrogen peroxide on titanium-containing catalyst (TS-1). Kataliz v promyshlennosti. 2010;(3). (In Russ.) https://doi.org/10.18412/1816-0387-2010-3-
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