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Synthesis of Co and Ni Sulfides for Destruction of Heavy Oil Components
https://doi.org/10.18412/1816-0387-2026-3-78-85
Abstract
In this work, the effect of synthesized (ex situ) Ni3S2 and Со9S8 catalysts on the composition and structure of heavy oil cracking products was investigated in comparison with catalysts obtained in situ using nickel and cobalt-containing precursors. The temperature range of nickel sulfide formation during heavy oil cracking was established. It was demonstrated that the use of ex situ nickel catalysts promotes the production of liquid products enriched in light fractions by more than 60 wt.%. The use of ex situ cobalt catalysts accelerates cracking reactions, which leads to the formation of more than 20 wt.% by-products, mainly gaseous. X-ray diffraction revealed NiS and CoS phases in the solid residues of cracking products, which indicates sulfidation of the initial sulfide compounds Ni3S2 and Со9S8 during the process.
Supporting agencies: The work was carried out within the framework of the state assignment of the Institute of Chemical Sciences of the Siberian Branch of the Russian Academy of Sciences, funded by the Ministry of Science and Higher Education of the Russian Federation (FWRN-2021-0005).
About the Authors
Kh. Kh. Urazov
Institute of Petroleum Chemistry SB RAS, Tomsk
Russian Federation
Russian Federation
N. N. Sviridenko
Institute of Petroleum Chemistry SB RAS, Tomsk
Russian Federation
Russian Federation
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Review
For citations:
Urazov Kh.Kh., Sviridenko N.N. Synthesis of Co and Ni Sulfides for Destruction of Heavy Oil Components. Kataliz v promyshlennosti. 2026;26(3):78-85. (In Russ.) https://doi.org/10.18412/1816-0387-2026-3-78-85
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