

System of dewaxing and hydrotreating catalysts for EURO diesel production
Abstract
«Angarsk plant catalysts and organic synthesis» offers modern catalysts for hydrotreating and dewaxing, which represent a single integrated catalyst system for diesel fuel productions. Optimization of technology for CVM zeolite synthesis conducted to improve the efficiency c dewaxing catalyst. Stage of hydrothermal treatment of silica is introduced, resulting in an increase of reactivity of silica, a reduce the duration of crystallization, and zeolite crystallite sizes decrease. Comparative testing of dewaxing catalysts – own developed (DEP) and industrial (SGK-1) was conducted. It has been established that the zeolite promotion (Zn2+ or La3+) leed to increasing the activity of the dewaxing catalyst and allows to obtain high yields of diesel fraction at a lower temperature than when using an industrial SGK-1. The results of the pilot tests on real feed have shown that the usege of an integrated system of catalysts AGKD-400/DEP provides diesel fuel filterability limit temperature minus 38 °C and 35 ppm sulfur content for at least 720 hours. The proposed catalytic system can be implemented in many refineries to produce EURO diesel.
About the Authors
T. P. KiselevaRussian Federation
O. M. Posokhova
Russian Federation
M. I. Tselyutina
Russian Federation
I. D. Reznichenko
Russian Federation
R. R. Aliev
Russian Federation
S. A. Skornikova
Russian Federation
References
1. Коновальчиков О.Д., Поезд Д.Ф., Красильникова Л.А., Зеленцов Ю.Н., Порублев М.А., Бабиков А.Ф., Яс-
2. кин В.П. Катализаторы и процессы гидродепарафинизации нефтяных фракций. Тематический обзор.
3. ЦНИИТЭнефтехим, 1994.
4. Скорникова С.А., Латышева Л.Е., Ченец В.В., Дисс И.Ю., Эппель С.А. // Кинетика и катализ. 1992. Т. 33. № 1. С. 245—249.
5. Раt. RU 2500473C2. Catalyst of hydroisomerisation, method of its obtaining, method of liquid petroleum product deparaffinisation and method of obtaining basic lubricating oil / KhAJaSAKA Kadzuaki (JP), OKADZAKI Motoja (JP), JOKOI Majumi (JP). 2009.
6. Раt. RU 2465959C2. Hydroisomerisation catalyst, method of producing said catalyst, method for dewaxing hydrocarbon oil and method of producing lubricant base oil / KhAJaSAKA Kadzuaki (JP). 2009.
7. Пат. 2362797 РФ. Способ получения деароматизированного дизельного топлива с ультранизким содержанием серы / А.Н. Логинова, М.В. Китова, В.В. Фадеев, С.В. Лысенко, А.В. Иванов. 2008.
8. Лобза Г.В., Афонина Г.Г., Коломейчук В.Н.,Скорникова С.А., Латышева Л.Е. // Журнал физической химии. 1989. Т. 63. № 1. С. 239—241.
9. PDF / Powder Diffraction File. Hanawaet Search Manual. Inorganic Phases. Sets 1—42. 1992.
10. Пат. 2457179 РФ. Способ приготовления высококремнеземного цеолита / И.Д. Резниченко, М.И. Целютина, О.М. Посохова, Р.Р. Алиев, С.А. Скорникова, А.Ф. Гизетдинова, Т.П. Киселёва. 2010.
Review
For citations:
Kiseleva T.P., Posokhova O.M., Tselyutina M.I., Reznichenko I.D., Aliev R.R., Skornikova S.A. System of dewaxing and hydrotreating catalysts for EURO diesel production. Kataliz v promyshlennosti. 2014;(2):45-50. (In Russ.)