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The effect of treatment with sodium carbonate and hydrogen on the activity and selectivity of polymeric Pd-containing catalysts for hydrogenation of acetylene compounds
https://doi.org/10.18412/1816-0387-2021-1-2-86-96
Abstract
Catalytic hydrogenation of the triple carbon-carbon bond of acetylene compounds is an important industrial process. High selectivity to the olefin compound should be provided in the process. This study considers the effect exerted by sodium carbonate treatment of the palladium catalysts containing super-cross-linked polystyrene (SPS) on their activity and selectivity in the hydrogenation of 2-methyl- 3-butin-2-ol and phenylacetylene. The effect of such treatment was shown to depend on the chosen palladium precursor and the type of polymeric support (non-functionalized SPS or that containing ternary amino groups). At atmospheric pressure of hydrogen and a temperature of 90 °C in a toluene medium, the 1%-Pd/SPS catalysts treated with Na2CO3 provided a 98 % selectivity in the hydrogenation of 2-methyl-3-butin-2-ol (at a 95 % conversion of the substrate), while selectivity in the hydrogenation of phenylacetylene reached 99.5 %.
About the Authors
A. A. Bertova
Tver State Technical University
Russian Federation
Russian Federation
A. A. Korshakova
Tver State Technical University
Russian Federation
Russian Federation
A. V. Bykov
Tver State Technical University
Russian Federation
Russian Federation
M. G. Sulman
Tver State Technical University
Russian Federation
Russian Federation
L. Zh. Nikoshvili
Tver State Technical University
Russian Federation
Russian Federation
L. Kiwi-Minsker
Tver State University
Russian Federation
Russian Federation
References
1. Tungler A., Tarnai T., Hegediis L., Fodor K., Máthé T. // Platinum Metals Rev.1998. Vol. 42. P. 108.
2. Coq B., Figueras F. // J. Mol. Catal. A. 2001. Vol. 173. P. 117.
3. Bogdan V.I.,Koklin A.E.,Kalenchuk A.N., Kustov L.M. // Mendeleev Commun. 2020. Vol. 30. P. 462.
4. Chai Y., Wu G., Liu X., Ren Y., Dai W., Wang C., Xie Z., Guan N., Li L. // J. Am. Chem. Soc.2019. Vol. 141. P. 9920.
5. Tschan R., Schubert M.M., Baiker A., Bonrath W., Lansink-Rotgerink H. // Catal. Lett. 2001. Vol. 75. P. 31.
6. Anderson J.A., Mellor J., Wells R.P.K. // J. Catal. 2009. Vol. 261. P. 208.
7. Nikolaev S.A., Zanaveskin L.N., Smirnov V.V., Averyanov V.A., Zanaveskin K.L. // Russ. Chem. Rev. 2009. Vol. 78. P. 231.
8. Iwasa N., Yoshikawa M., Arai M. // Chem. Phys. Chem. 2002. Vol. 4. P. 5414.
9. Semagina N., Grasemann M., Xanthopoulos N., Renken A., Kiwi-Minsker L. // J. Catal. 2007. Vol. 251. P. 213.
10. Yarulin A., Yuranov I., Cárdenas-Lizana F., Alexander D.T.L., Kiwi-Minsker L. // Appl. Catal. A. 2014. Vol. 478. P. 186.
11. Kim S.K., Lee J.H., Ahn I.Y., Kim W.J., Moon S.H. //Appl. Catal. A. 2011. Vol. 401. P.12.
12. Kim W.J., Kang J.H., Ahn I.Y., Moon S.H. // Appl. Catal. A. 2004. Vol. 268. P. 77.
13. Cho H.-B., Hong B.-E., Park J.-H., Ahn S.-H., Park Y.-H. // Bull. Korean Chem. Soc. 2008. Vol. 29. P. 2434.
14. Cho H.-B., Lee B.U., Ryu C.-H., Nakayama T., Park Y.-H. // Korean J. Chem. Eng. 2013. Vol. 30. P. 306.
15. Pellegrini R.,Leofanti G., Agostini G., Bertinetti L., Bertarione S., Groppo E., Zecchina A., Lamberti C. // J. Catal. 2009. Vol. 267. P. 40.
16. Jia L., Bulushev D.A., Beloshapkin S., Ross J.R.H.// Appl. Catal. B. 2014. Vol. 160. P. 35.
17. Aramendía M.A., Burch R., Garcia I.M., Marinas A., Marinas J.M., Southward B.W.L., Urbano F.J. // Appl. Catal. B. 2001. Vol. 31. P. 163.
18. Aramendia M.A., Borau V., Garcia I.M., Jiménez C, Lafont F., Marinas A., Marinas J.M., Urbano F.J. // J. Mol. Catal. A. 2002. Vol. 184. P. 237.
19. Moreno J.M., Aramendia M.A., Marinas A., Marinas J.M., Urbano F.J. // Appl. Catal. B. 2005. Vol. 59. P. 275.
20. Nikoshvili L.Zh., Bykov A.V., Khudyakova T.E., LaGrange T., Héroguel F., Luterbacher J.S., Matveeva V.G., Sulman E.M., Dyson P.J., Kiwi-Minsker L. // Ind. Eng. Chem. Res. 2017. Vol. 56. P. 13219.
21. Nemygina N.A., Nikoshvili L.Zh., Matveeva V.G., Sulman M.G., Sulman E.M., Kiwi-Minsker L. // Top. Catal. 2016. Vol. 59. P. 1185.
22. Sulman E.M., Nikoshvili L., Matveeva V.G., Tyamina I., Sidorov A.I., Bykov A.V., Demidenko G.N., Stein B.D., Bronstein L.M. // Top. Catal. 2012. Vol. 55. P. 492.
23. Быков А.В., Демиденко Г.Н. // Вестник ТвГУ. Серия «Химия». 2020. № 2 (40). С. 62.
24. Быков А.В., Демиденко Г.Н., Никошвили Л.Ж. // Вестник ТвГУ. Серия «Химия». 2020. № 2 (40). С. 73.
25. Bykov A.V., Alekseeva D.V., Demidenko G.N., Vasiliev A.L., Nikoshvili L., Kiwi-Minsker L. // Catalysts. 2020. Vol. 10. P. 1362.
26. Nikoshvili L., Shimanskaya E., Bykov A., Yuranov I., Kiwi-Minsker L., Sulman E. // Catal. Today. 2015. Vol. 241. Part B. P. 179.
27. Nikoshvili L.Zh., Makarova A.S., Lyubimova N.A., Bykov A.V., Sidorov A.I., Tyamina I.Yu., Matveeva V.G., Sulman E.M. // Catal. Today. 2015. Vol. 256. P. 231.
28. Bonrath W., Eggersdorfer M., Netscher T. // Catal. Today. 2007. Vol. 121. P. 45-57.
29. Wagner C.D., Rigs W.M., Davis L.E., Moulder J.F. Handbook of X-ray photoelectron spectroscopy. Perkin-Elmer Corporation. 1979; NIST X-ray Photoelectron Spectroscopy Database, Version 4.1 (National Institute of Standards and Technology, Gaithersburg, 2012).
30. Wu T., Kaden W.E., Kunkel W.A., Anderson S.L. // Surf. Sci. 2009. Vol. 603. P. 2764-2770.
31. Chaparro S., Martinez J.J., Rojas H.A., Pineda A., Luque R. // Catal. Today. 2020. In press. https://doi.org/10.1016/j.cattod.2020.03.057
32. Shesterkina A.A., Kirichenko O.A., Kozlova L.M., Kapustin G.I., Mishin I.V., Strelkova A.A., Kustov L.M. // Mendeleev Commun. 2016. Vol. 26. P. 228-230.
Review
For citations:
Bertova A.A., Korshakova A.A., Bykov A.V., Sulman M.G., Nikoshvili L.Zh., Kiwi-Minsker L. The effect of treatment with sodium carbonate and hydrogen on the activity and selectivity of polymeric Pd-containing catalysts for hydrogenation of acetylene compounds. Kataliz v promyshlennosti. 2021;1(1-2):86-96. (In Russ.) https://doi.org/10.18412/1816-0387-2021-1-2-86-96
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