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The Synthesis of Glycerol Carbonate from Glycerol and Dimethyl Carbonate in the Presence of Strongly Basic Anion-Exchange Styrene-Divinylbenzene Anionites Dowex
https://doi.org/10.18412/1816-0387-2021-6-398-405
Abstract
The synthesis of glycerol carbonate from glycerol and dimethyl carbonate in the presence of strongly basic styrene-divinylbenzene anionites Dowex 1×2, Dowex 1×4 and Dowex 1×8 in the –OH form with different cross-linking degree of polystyrene matrix (the divinylbenzene content of 2, 4 and 8 wt.%) at 90–105 °C and a dimethyl carbonate/glycerol molar ratio equal to 2 was studied. The yield of glycerol carbonate was shown to decrease with an increase in the cross-linking degree of the anion-exchange resin. The maximum conversion of glycerol (95 %) and selectivity to glycerol carbonate (45.5 %) were observed in the presence of Dowex 1×2 at 105 °C after 5 h of the reaction. Advantages of the studied systems were demonstrated in comparison with the anion-exchange and cationexchange resins proposed in the literature.
About the Authors
A. V. Shvydko
Boreskov Institute of Catalysis SB RAS, Novosibirsk; Novosibirsk State Technical University
Russian Federation
Russian Federation
S. A. Prikhod’ko
Boreskov Institute of Catalysis SB RAS, Novosibirsk
Russian Federation
Russian Federation
M. N. Timofeeva
Boreskov Institute of Catalysis SB RAS, Novosibirsk; Novosibirsk State Technical University
Russian Federation
Russian Federation
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Review
For citations:
Shvydko A.V., Prikhod’ko S.A., Timofeeva M.N. The Synthesis of Glycerol Carbonate from Glycerol and Dimethyl Carbonate in the Presence of Strongly Basic Anion-Exchange Styrene-Divinylbenzene Anionites Dowex. Kataliz v promyshlennosti. 2021;21(6):398-405. (In Russ.) https://doi.org/10.18412/1816-0387-2021-6-398-405
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