Экспериментальные исследования и математическое моделирование каталитической конверсии биодизельного топлива в синтез-газ

Исследованы паровая конверсия и автотермический риформинг метилолеата (модельное соединение биодизельного топлива) в синтез-газ на структурированном Rh-содержащем катализаторе. Показано, что превращение метилолеата протекает через стадию термического крекинга с последующей конверсией образованных органических соединений с более коротким углеродным скелетом. На основе экспериментальных результатов была разработана математическая модель, учитывающая радиальный градиент температуры и представляющая собой эффективный инструмент для количественного описания и оптимизации процесса конверсии биодизельного топлива.

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