|Generate QR code
Open Access
Subscription or Fee Access
Oligomerization of α-octene in the presence of zeolite catalysts
Abstract
Oligomerization of octene-1 in the presence of different structural types zeolites – Y, Beta, ZSM-12, ZSM-5 is investigated. It is shown that extensively porous zeolite catalysts Y, Beta, ZSM-12 exhibit a high catalytic activity at 150–200 °C. In their presence octane conversion reaches 96 %, the oligomers yield is 88–100 wt.%. Zeolite ZSM-5 has a low active at 150–180 °C and catalyzes mainly the octene-1 isomerization. If the temperature is raised up to 250 °C the main reaction products are low molecular weight oligomers of cracking products. The activity and selectivity of zeolite catalysts in the octene-1 oligomerization are due to their acidic properties and structural characteristics, as well as reaction conditions. It’s found that octene dimers with alkyl naphthenic structure is dominated among oligomers, the content of unsaturated hydrocarbons with tri-and tetrasubstituted double bonds slightly 2,2–3,2 %. Octene oligomers that synthesized in the presence of zeolite Beta, possess physicochemical properties similar to those of hydrogenated poly-α-olefin oligomerization which was carried out on complexes of AlCl3.
About the Authors
N. G. Grigorieva
Institute of Petrochemistry and Catalysis RAS, Ufa
Russian Federation
Russian Federation
S. V. Bubennov
Institute of Petrochemistry and Catalysis RAS, Ufa
Russian Federation
Russian Federation
B. I. Kutepov
Institute of Petrochemistry and Catalysis RAS, Ufa
Russian Federation
Russian Federation
References
1. Global Information Inc. Market Research Report. Synthetic lubricant: Potential Applications and Markets in Western Europe, North America, and Asia-Pacific. Technical Insights, New York: John Wiley & Sons, 1999.
2. Мамедьяров М.А. Химия синтетических масел. Л.: Химия, 1989.
3. Матковский П.Е., Старцева Г.П., Чур В.Я. и др. Научные основы и технологическое оформление процесса получения синтетических олигодеценовых масел для автомобильного транспорта // Химия в интересах развития. 2005. Т. 13, № 6. С. 787—791.
4. Цветков О.Н. Поли-α-олефиновые масла: химия, технология и применение. М.: Техника, ТУМА ГРУПП, 2006.
5. Котов С.В., Моисеев И.К., Шабанова А.В. Олигомеры олефинов: способы получения и применение в качестве полимеров топлив и масел (обзор) // Нефтехимия. 2003. Т. 43, № 5. С. 323—333.
6. Pat. № 7268268 (USA). Dimerization of olefins // F. Al-Soufi, B. Sami Al, B. Yajnavalskya Subrai, H. Altaf. 2007.
7. Pat. 5064794 (USA). Catalyst supports, catalyst systems, and olefin dimerization // C. A. Drake. 1991.
8. Pat. 5461181 (USA). Lightly branched higher olefin oligomerization with surface modified zeolite catalyst // J.C. Cheng, Sal Miseo, S. L. Soled, J. S. Buchanan, J.S. Feeley. 1995.
9. Pat. 5120891 (USA). Process for oligomerizing olefins using a super-dealuminated Y-zeolite // J. R. Sanderson, Pei S. E. Dai, J. F. Knifton, 1992.
10. Pat. 4912280 (USA). Olefin dimerization method // M.G. Clerici. 1990.
11. Pat. 2072484 (EurP). Olefin oligomerization process // S. Brown, M.Georges, J. Godsmark. 2005.
12. Knifton J.F., Sanderson J.R. // Catalysis Letters. 1994. № 28. P. 223—230.
13. Arno de Clerk Oligomerization of 1-hexene and 1-octene over solid acid catalysts // Ind. Eng. Chem. Res. 2005. № 44. P. 2887—3893.
14. Пат. 2151739 (РФ). Способ получения высокомодульных цеолитов типа Y. // М.Л. Павлов, М.И. Левинбук, Е.М. Савин, В.К. Смирнов и др., 1997.
15. Рыбак Б.М. Анализ нефти и нефтепродуктов. М.: ГНТИ, 1962.
16. Григорьева Н.Г, Паукщтис Е.А., Кутепов Б.И. и др. Цеолиты типа Y в реакции димеризации α-метилстирола // Нефтехимия. 2005. Т. 45, № 6. C. 453—459.
17. Григорьева Н.Г, Галяутдинова Р.Р., Паукштис Е.А. и др. Димеризация α-метилстирола на высококремнистых цеолитах // Нефтехимия. 2006. Т. 46, № 5. С. 1—6.
18. Ganapati D. Yadav, Nirav S. Doshi Development of a green process for poly-α-olefin based lubricants // Green chemistry. 2002. № 4. P. 528—540.
Review
For citations:
Grigorieva N.G., Bubennov S.V., Kutepov B.I. Oligomerization of α-octene in the presence of zeolite catalysts. Kataliz v promyshlennosti. 2011;(6):14-21. (In Russ.)
Views:
24
Email this article 