Transformations of ethylene and propylene on molybdenum oxide catalysts deposited on γ-alumina and silica gel

The physicochemical properties, the state of the active component, the activity and selectivity of deposited molybdenum-containing catalysts in the processes of ethylene to propylene conversion and propylene metathesis are considered. It is shown that the activity of molybdenum-containing catalysts in the transformations of ethylene and propylene increases with an increase in the number of medium-strength and strong acid centers on their surface. The alumina-based catalyst is active at temperatures of 100-250 °C. At the same time, a silica gel-based catalyst requires temperatures up to 500 °C. The higher activity of the MoO3/γ-Al2O3 catalyst in metathesis reactions is associated with the formation of highly dispersed molybdenum compounds and Brensted acid centers.

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