|Generate QR code
Open Access
Subscription or Fee Access
Improvement of catalysts for upgrading naphtha fractions
Abstract
The authors proposed a method of modifying a catalyst based on high-silica zeolite ZSM-5 type by nanosized Ni-powder to improve catalysts for straightrun gasoline fractions upgrading. The proposed method of solid-phase mechanical mixture with Ni-nanopowder more environmentally friendly than traditional impregnation or ion exchange, and developed Ni-containing zeolite catalysts can reduce low-octane gasoline fractions upgrade process temperature on 20–40 °C, increase the desired product yield with high content of high-octane components - isoalkanes. We have studied the acidic and catalytic properties of high silica zeolite containing different amounts of nano-sized Ni-powder. The activity of catalytic systems is investigated in the conversion of virgin petrol fractions of oil. There is determining the optimal composition of the catalyst and process conditions for obtaining maximum yield of target product - high-octane gasoline.
About the Authors
E. V. Urzhumova
Institute of Petroleum Chemistry SB RAS, Tomsk
Russian Federation
Russian Federation
L. M. Velichkina
Institute of Petroleum Chemistry SB RAS, Tomsk
Russian Federation
Russian Federation
A. V. Vosmerikov
Institute of Petroleum Chemistry SB RAS, Tomsk
Russian Federation
Russian Federation
A. E. Ermakov
Institute of Metal Physics, Ural Branch of the Russian Academy of Sciences, Yekaterinburg
Russian Federation
Russian Federation
References
1. Гусев А.И. Нанокристаллические материалы: методы получения и свойства. Екатеринбург: УрО РАН, 1998.
2. Восмерикова Л.Н., Величкина Л.М., Коробицына Л.Л. и др. // Журнал прикладной химии. 2000. Т. 73, № 9. С. 1477.
3. Бухтияров В.И., Слинько М.Г. // Успехи химии. 2001. Т. 70, № 2. С. 167.
4. Восмериков А.В., Ермаков А.Е., Восмерикова Л.Н. и др. // Кинетика и катализ. 2004. Т. 45, № 2. С. 232.
5. Величкина Л.М., Пестряков А.Н., Восмериков А.В. и др. // Нефтехимия. 2008. Т. 48, № 3. С. 201.
6. Восмериков А.В. // Нанотехника. 2008. № 1(13). С. 27.
7. Степанов В.Г., Ионе К.Г. // Химическая промышленность. 1996. № 3. С. 59.
8. Пат. 2024585 (РФ). Способ получения высокооктанового бензина / В.Г. Степанов, В.И. Небыков, К.Г. Ионе. 1994.
9. Ечевский Г.В., Климов О.В., Кихтянин О.В. и др. // Катализ в промышленности. 2003. № 2. С. 60.
10. Фалькевич Г.С., Ростанин Н.Н., Виленский Л.М. и др. // Катализ в промышленности. 2002. № 3. С. 12.
11. Ясьян Ю.П., Колесников А.Г., Крахмалева И.С. и др. // Химия и технология топлив и масел. 2001. № 5. С. 37.
12. Pat. 1471440 (GB). A method of preparing a crystalline aluminosilicate zeolite / Mobil oil corporation. 1979.
13. Pat. 1588614 (GB). Synthesis of a new ZSM-5 type zeolite / Mobil oil corporation. 1981.
Review
For citations:
Urzhumova E.V., Velichkina L.M., Vosmerikov A.V., Ermakov A.E. Improvement of catalysts for upgrading naphtha fractions. Kataliz v promyshlennosti. 2011;(2):28-32. (In Russ.)
Views:
123
Email this article 